U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Dual-wavelength absorption detector adapted for continuous-flow detection

Patent 5408326 Issued on April 18, 1995. Estimated Expiration Date: Icon_subject April 28, 2013. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2980512

3327584

3592607

3666941

3807875

3910701

Method and apparatus for investigating the conformation of optically active molecules by measuring parameters associated with their luminescence
Patent #: 3967902
Issued on: 07/06/1976
Inventor: Steinberg

Adsorption process
Patent #: 4000990
Issued on: 01/04/1977
Inventor: Bingham

Photometer with concave mirrors and field optics
Patent #: 4188126
Issued on: 02/12/1980
Inventor: Boisde ,   et al.

Novel photometric system
Patent #: 4276475
Issued on: 06/30/1981
Inventor: Nelson

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Inventor

Assignee

Application

No. 053784 filed on 04/28/1993

US Classes:

356/410, Of flowing liquids250/576, Sample holder or supply396/213, EXPOSURE CONTROL CIRCUIT396/570Photocell controlled

Examiners

Primary: McGraw, Vincent P.
Assistant: Wolfe, Russell C.

Attorney, Agent or Firm

International Class

G01N 021/85

Abstract

A dual-wavelength absorption detector is provided. The detector includes an electronics section, a three branched optical guide and a detector-cell. Each branch of the optical guide has a plurality of fibers, and at one end the branches are separated and connected to different portions of the electronics section. Two of the three branches are terminated next to LEDs having different wavelengths, a measuring wavelength and a reference wavelength. The third branch is terminated next to a photodetector. At the opposite end of the optical guide the three branches are combined to form a common end which is terminated within the detector-cell. The detector-cell includes a continuous-flow sample cell connected to a sample line. Within the detector-cell, the common end's fiber ends are held at a fixed location on one side of the sample cell with a concave mirror being located on the opposite side. Sequential pulses of light from the LEDs are guided through their respective branches to the common end where they cross the sample cell to be absorbed by sample material flowing through the cell. Portions of each pulse are reflected by the concave mirror back across the sample cell to the common end and strike the photodetector branch fiber ends. At the photodetector, signals proportional to the illumination intensity of the pulses striking the fiber ends are produced. The signals are then compared to provide an output signal which represents the absorption of the sampled material.

Other References

  • P. K. Dasgupta et al "Light Emitting Diode Based Flow Through Optical Absorption Detectors." Shell Oil Co., Nov. 15, 1991, Talanta, vol. 40 pp. 53-74 (1993)
  • J. Huang et al "A Dual Wavelength Light Emitting Diode Based Detector for Flow Injection Analyzers" Talanta, vol. 39 No. 6 pp. 589-592 (1992)
  • P. K. Dasgupta et al., "Light Emitting Diode Based Flow-Through Optical Absorption Detectors." Shell Oil Company received the enclosed pre-publication copy on Nov. 15, 1991. The article was subsequently accepted for publication and published in Talanta, vol. 40, pp. 53-74 (1993)
  • Process Instruments And Controls Handbook, Douglas M. Considine, Editor-in-Chief, McGraw-Hill Book Company, Third Edition (1985), pp. 6.63-6.73, 6.89-6.91, and 6.169-6.187
  • J. Ruzicka et al., "Flow Injection Analyses, Part I. A New Concept of Continuous Flow Analysis," Analytica Chimica Acta., 78, pp. 145-157 (1975) Elsevier Scientific Publishing Co., Amsterdam
  • D. Betteridge et al., "A Highly Sensitive Flow-Through Phototransducer for Unsegmented Continuous-Flow Analysis Demonstrating High-Speed Spectrophotometry at the Parts Per 109 Level and a New Method of Refractometric Determinations," The Analyst, vol. 103, No. 1230, pp. 897-907 (Sep. 1978)
  • J. Huang et al., "A Dual-Wavelength Light-Emitting Diode Based Detector for Flow-Injectin Analysis Proess Analysers," Talanta, vol. 39, No. 6, pp. 589-592 (1992)
  • E. A. G. Zagatto et al., "Compensation of the Schlieren Effect in Flow-Injection Analysis by Using Dual-Wavelength Spetrophotometry," Analytica Chimica Acta., 234, pp. 153-160 (1990)
  • V. Kuban et al., "Nitroprusside and Methylene Blue Methods for Silicone Membrane Differentiated Flow Injection Determination of Sulfide in Water and Wastewater," Anal. Chem., 64, pp. 36-43 (1992)
  • Series 6000 Process Diode Array [brochure], Ametek Process & Analytical Instruments Division, Ametek, Inc. Newark, Delaware (1991)
  • Model 400 Photometric Analyzers, Bulletin P-400, Ametek Process & Analytical Instruments Division, Ameteck, Inc., Newark, Delaware (1992)
  • Alfa-Laval/Bran+Luebbe Market Information [brochure], Bran+Luebbe Analyzing Technologies, Elmsford, N.Y. (1992
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