Patent References T909017 1986889 2233841 2862789 3186802 3676059 3843789 Method for removing sulfur dioxide from waste gases Method of removing SO2 and/or other acid components from waste gases Process and apparatus to purify waste industrial gases InventorsAssigneeApplicationNo. 035284 filed on 03/22/1993US Classes:423/243.06, Ammonium compound reactant423/243.03, Oxygen423/545, Ammonium containing423/547Employing sulfite or bisulfite as reactantExaminersPrimary: Straub, Gary P.Attorney, Agent or FirmForeign Patent References
International ClassesC01B 017/00C01C 001/24 AbstractProcess for the removal of sulfur oxides from sulfur oxide-containing gas with simultaneous production of ammonium sulfate. The process is carried out by first passing hot sulfur oxide-containing gas through a prescrubber wherein the gas contacts saturated aqueous ammonium sulfate liquor which is recycled in the prescrubber, followed by passing the prescrubbed gas through an absorber wherein the prescrubbed gas contacts dilute aqueous ammonium sulfate liquor. The sulfur oxide in the sulfur oxide-containing gas is absorbed by the dilute aqueous ammonium sulfate liquor in the absorber, and scrubbed gas is removed from the absorber. The dilute aqueous ammonium sulfate liquor is treated with ammonia and air and the absorbed sulfur dioxide is converted to ammonium sulfate in the liquor. The dilute ammonium sulfate liquor is recycled into contact with the prescrubbed gas in the absorber. Dilute aqueous ammonium sulfate liquor is removed from the absorber and added to the saturated aqueous ammonium sulfate liquor in the prescrubber where it becomes saturated due to evaporation caused by the hot gas. Ammonium sulfate crystals form in the saturated aqueous ammonium sulfate liquor in the prescrubber are recovered as product from saturated aqueous ammonium sulfate withdrawn from the prescrubber.Other References
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