U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate

Patent 5362458 Issued on November 8, 1994. Estimated Expiration Date: Icon_subject March 22, 2013. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

T909017

1986889

2233841

2862789

3186802

3676059

3843789

Method for removing sulfur dioxide from waste gases
Patent #: 3983217
Issued on: 09/28/1976
Inventor: Muraki ,   et al.

Method of removing SO2 and/or other acid components from waste gases
Patent #: 4039304
Issued on: 08/02/1977
Inventor: Bechthold ,   et al.

Process and apparatus to purify waste industrial gases
Patent #: 4213945
Issued on: 07/22/1980
Inventor: Haese ,   et al.

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Inventors

Assignee

Application

No. 035284 filed on 03/22/1993

US Classes:

423/243.06, Ammonium compound reactant423/243.03, Oxygen423/545, Ammonium containing423/547Employing sulfite or bisulfite as reactant

Examiners

Primary: Straub, Gary P.

Attorney, Agent or Firm

Foreign Patent References

  • 52-7870 JP 01/12/1977
  • 57-121387 JP. 07/12/1982

International Classes

C01B 017/00
C01C 001/24

Abstract

Process for the removal of sulfur oxides from sulfur oxide-containing gas with simultaneous production of ammonium sulfate. The process is carried out by first passing hot sulfur oxide-containing gas through a prescrubber wherein the gas contacts saturated aqueous ammonium sulfate liquor which is recycled in the prescrubber, followed by passing the prescrubbed gas through an absorber wherein the prescrubbed gas contacts dilute aqueous ammonium sulfate liquor. The sulfur oxide in the sulfur oxide-containing gas is absorbed by the dilute aqueous ammonium sulfate liquor in the absorber, and scrubbed gas is removed from the absorber. The dilute aqueous ammonium sulfate liquor is treated with ammonia and air and the absorbed sulfur dioxide is converted to ammonium sulfate in the liquor. The dilute ammonium sulfate liquor is recycled into contact with the prescrubbed gas in the absorber. Dilute aqueous ammonium sulfate liquor is removed from the absorber and added to the saturated aqueous ammonium sulfate liquor in the prescrubber where it becomes saturated due to evaporation caused by the hot gas. Ammonium sulfate crystals form in the saturated aqueous ammonium sulfate liquor in the prescrubber are recovered as product from saturated aqueous ammonium sulfate withdrawn from the prescrubber.

Other References

  • Huvel, The Ammonia Wet Scrubbing Desulphurizaton Process Combined With A Denox-Stage, International Symposium on Improved Technology For Fossil Power Generation, Washington, D.C. (EPRI), Mar. 1-3, 199
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