U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Monomer recovery from polymeric materials

Patent 5326919 Issued on July 5, 1994. Estimated Expiration Date: Icon_subject February 8, 2013. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3901951

Method for thermal decomposition of plastic scraps and apparatus for disposal of plastic scraps
Patent #: 4584421
Issued on: 04/22/1986
Inventor: Saito ,   et al.

Monomeric recovery from polymeric materials Patent #: 5136117
Issued on: 08/04/1992
Inventor: Paisley, et al.

Inventors

Assignee

Application

No. 014833 filed on 02/08/1993

US Classes:

585/241, From synthetic resin or rubber585/648By C content reduction, e.g., cracking, etc.

Examiners

Primary: Pal, Asok
Assistant: Achutamurthy, P.

Attorney, Agent or Firm

Foreign Patent References

  • 982078 CA. 02/12/2012
  • 9105976 EP. 02/12/2012
  • 2234755 DE. 02/12/2012
  • 1398858 GB. 02/12/2012

International Class

C07C 004/22

Abstract

A method is described for the recovery of high yields of monomers from waste and scrape polymeric materials with minimal amounts of char and tar. The process involves heating the polymer at a heating rate of at least 500° C./sec in a flow-through reactor. Heating is accomplished by contacting the polymer with a heat transfer material such as hot incandescent sand. A flow-through reactor is used to provide the high heating rates and short reactor residence times for the monomer product. The flow through reactor may be a circulating fluidized bed reactor, an entrainment reactor, a cyclonic reactor or a gravity reactor.

Other References

  • R. G. Graham et al., Fast Pyrolysis (ultrapyrolysis) of Biomass Using Solid Heat Carriers in Fundamentals of Thermochemical Biomass Conversion edited by Overend et al. p. 397
  • D. C. Scott et al., Fast Pyrolysis of Waste Plastics, Energy From Biomass and Wastes XIV; Lake Buena Vista, Fla. Jan. 29, 1990
  • W. Kaminsky, Thermal Recycling of Polymers, Journal of Analytical and Applied Pyrolysis, 1985, vol. 8, pp. 439-448
  • Sinn et al., Processing of Plastic Waste and Scrap Tires into Raw Materials, Especially by Pyrolysis, Angew. Chem. Int. Ed. Engl., 1976, vol. 15, No. 11, pp. 660-672
  • T. Sawaguchi et al., Studies on the Thermal Degradation of Synthetic Polymers--Thermal Gasification of Polyolefins, Bulletin of the Japan Petroleum Institute, 1977, No. 2, pp. 124-230
  • T. Kuroki et al., Pyrolysis of Polystyrene--Prediction of Product Yields, Nippon Kagaku Kaishi, 1976, No. 11, pp. 1766-1772, Translation Provided
  • T. Kuroki et al., Thermal Gasification of Polypropylene, Nippon Kagaku Kaishi, 1976, No. 2, pp. 322-327
  • T. Sawaguchi et al., Thermal Gasification of Polyethylene-Prediciton of Product Yield, Nippon Kagaku Kaishi, 1977, No. 4, pp. 565-569
  • R. B. Seymour, Polymer Chemistry and Technology, American Chemical Society, 1981, p. 11
  • R. J. Gendreau et al., "An Independent Assessment of Operating Circulating Fluidized Bed Boiler Installations", 1985 Pulping Conference, pp. 331-340 especially section titled CFB Process Description starting on p. 332
  • B. Schweiger, "Fluidized-Bed Boilers Achieve Commerical Status Worldwide" Power, Feb. 1985, p. S-
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