U.S. patents available from 1976 to present.
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Methods of making pn CdTe/CdS thin film solar cells

Patent 5304499 Issued on April 19, 1994. Estimated Expiration Date: Icon_subject September 28, 2012. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Polycrystalline thin film CdS/CdTe photovoltaic cell
Patent #: 4207119
Issued on: 06/10/1980
Inventor: Tyan

Photoelectric element, picture-reading device including the same, and process for production thereof
Patent #: 4375644
Issued on: 03/01/1983
Inventor: Mori ,   et al.

Thin film cadmium telluride solar cell Patent #: 4650921
Issued on: 03/17/1987
Inventor: Mitchell

Inventors

Assignee

Application

No. 929514 filed on 09/28/1992

US Classes:

438/94, Heterojunction136/260, Cadmium containing136/264, Selenium or tellurium containing427/76, Coating is selenium, tellurium, or compound thereof438/967SEMICONDUCTOR ON SPECIFIED INSULATOR

Examiners

Primary: Weisstuch, Aaron

Attorney, Agent or Firm

Foreign Patent References

  • 0006025 EP 12/13/1979

International Classes

H01L 031/18
H01L 031/072

Foreign Application Priority Data

1991-10-03 DE

Abstract

A method of making pn CdTe/CdS thin film solar cells, in which a transparent TCO layer is deposited as a front contact on a transparent substrate in the form of inexpensive soda-lime glass, and is preferably provided with an ultra-thin indium layer, which is in turn coated with the CdS layer, wherein the thus coated substrate is brought to the CdTe coating at a temperature between 480° C. and 520° C., which is maintained during the ensuing rapid CdTe deposition using the close-spaced sublimation method with a preferred rate of deposition of 5 to 15 μm/min in an inert atmosphere. The indium layer dissolves during this deposition and effects the necessary n-doping of the CdS layer, without an additional method step. Solar cells can be made in this way with high efficiency in an inexpensive method, suitable for mass production.

Other References

  • K. Mitchell et al, J. Vac. Sci. Technol., vol. 12, No. 4, Jul./Aug. 1975, pp. 909-911
  • Y-S Tyan et al, Conference Record, 16th IEEE Photovoltaic Specialist Conf., Sep. 1982, pp. 794-800
  • V. Sosa et al, J. Vac. Sci. Technol., vol. A8, Mar./Apr. 1990, pp. 979-983
  • T. L. Chu et al, Solar Cells, vol. 21, pp. 73-80 (1987)
  • Y-S. Tyan, Solar Cells, vol. 23, pp. 19-29 (1988)
  • H. Uda et al, Jap. J. Appl. Phys., vol. 29, Oct. 1990, pp. 2003-2007
  • D. Bonnet et al, Conf. Record, 22nd IEEE Photovoltaic Specialists Conf. (Oct. 1991), pp. 1165-1168
  • T. L. Chu, "Thin Film Cadmium Telluride Solar Cells by Two Chemical Vapor Deposition Techinques", Solar Cells, 23 (1988), pp. 31-48
  • "Thin Film Solar cells", Katsuri Lal Chopr, Suhit Ranjan Das, Plenum Press, New York (1983), pp. 288-290; 295-304; 408-40
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