U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Transition metal-spirobenzopyran complex, a production process therefor and a photochromic material comprising the complex

Patent 5288592 Issued on February 22, 1994. Estimated Expiration Date: Icon_subject November 12, 2012. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3299079

3510308

3923524

Synthesis of photochromic indolinespiropyrans
Patent #: 3950356
Issued on: 04/13/1976
Inventor: Hinnen

Photosensitive compositions for direct positive color photography
Patent #: 4725527
Issued on: 02/16/1988
Inventor: Robillard

Color image forming method and particulate developer for developing electrostatic latent image Patent #: 5045420
Issued on: 09/03/1991
Inventor: Hosono, et al.

Inventor

Assignee

Application

No. 938044 filed on 11/12/1992

US Classes:

430/345, Spiropyran dye or dye former252/586, Displaying color change430/962, RADIATION-CHROMIC COMPOUND548/402, Heavy metal or aluminum containing548/409Both rings which form the spiro are hetero rings

Examiners

Primary: Bowers, Charles L. Jr.
Assistant: McPherson, John A.

Attorney, Agent or Firm

Foreign Patent References

  • 59-202270 JP. 11/19/1984
  • 60-054388 JP. 03/19/1985
  • 63-267783 JP. 11/19/1988
  • 2-069739 JP 03/19/1990
  • 2-212585 JP 08/19/1990

International Classes

G03C 001/735
C07D 209/96

Foreign Application Priority Data

1991-03-13 JP

Abstract

The object of the invention is to provide a novel compound exhibiting stable photochromism.The invention is directed to a transition metal-spirobenzothiopyran complex of the general formula ##STR1## wherein R1 for example be C1-20 alkyl; R2, R3, R4, R5, R6, R7 and R8 independently may mean hydrogen; Y means O or S; M may for example be Cr, and a process for producing the complex.

Other References

  • "New Experimental Chemical Lecture (No. 12) Organic Metal Chemistry", Japan Chem. Soc., (Mar. 1976)
  • J. Amer. Chem. Soc. 87, 4020 (1965), Phillips et al
  • J. Chem. Soc., Chem. Commun., (1989), Tamaki et al
  • Proceedings of the 58th Spring Meeting of the Chemical Society of Japan 1874 (1989), Oda et al
  • Proceedings of the 59th Spring Meeting of the Chemcial Society of Japan 1883 (1990), Tamaki et al
  • Chemical Society of Japan (Lectures on New Experimental Chemistry) Organo Metallic Chemistry p. 114 (1979
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