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AbstractThere is provided a method for preparing a pillared layered material, designated MCM-36, with a characteristic X-ray diffraction pattern. Upon calcination of the swollen, non-pillared form of this material, the layers collapse and condense upon one another in a somewhat disordered fashion to form a non-swellable material. However, when the swollen layered material is intercalated with polymeric oxide pillars, the layer separation is maintained, even after calcination. A combination of tetraethylorthosilicate and zirconium alkoxide is used as a pillaring agent for treating the swollen material. | InventorsAssigneeApplicationNo. 887811 filed on 05/04/1992US Classes:502/84, And metal, metal oxide, or metal hydroxide423/328.2, Crystalline423/329.1, X-ray diffraction pattern502/242Of Group IV (i.e., Ti, Zr, Hf, Ge, Sn or Pb)Field of Search423/328.2, Crystalline423/329.1, X-ray diffraction pattern502/80, Clay502/84, And metal, metal oxide, or metal hydroxide502/242Of Group IV (i.e., Ti, Zr, Hf, Ge, Sn or Pb)ExaminersPrimary: Breneman, R. BruceAttorney, Agent or FirmUS Patent References4439409, Crystalline aluminosilicate PSH-3 and its process of preparationIssued on: 03/27/1984 Inventor: Puppe , et al.4859648, Layered metal chalcogenides containing interspathic polymeric chalcogenides Issued on: 08/22/1989 Inventor: Landis , et al.4954325Composition of synthetic porous crystalline material, its synthesis and use Issued on: 09/04/1990 Inventor: Rubin, et al. International ClassB01J 021/06 |