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US Patent 5278115 - Method for preparing a pillared layered oxide material

US Patent Issued on January 11, 1994
Estimated Patent Expiration Date: Icon_subject May 4, 2012Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

There is provided a method for preparing a pillared layered material, designated MCM-36, with a characteristic X-ray diffraction pattern. Upon calcination of the swollen, non-pillared form of this material, the layers collapse and condense upon one another in a somewhat disordered fashion to form a non-swellable material. However, when the swollen layered material is intercalated with polymeric oxide pillars, the layer separation is maintained, even after calcination. A combination of tetraethylorthosilicate and zirconium alkoxide is used as a pillaring agent for treating the swollen material.

Inventors

Assignee

Application

No. 887811 filed on 05/04/1992

US Classes:

502/84, And metal, metal oxide, or metal hydroxide423/328.2, Crystalline423/329.1, X-ray diffraction pattern502/242Of Group IV (i.e., Ti, Zr, Hf, Ge, Sn or Pb)

Field of Search

423/328.2, Crystalline423/329.1, X-ray diffraction pattern502/80, Clay502/84, And metal, metal oxide, or metal hydroxide502/242Of Group IV (i.e., Ti, Zr, Hf, Ge, Sn or Pb)

Examiners

Primary: Breneman, R. Bruce

Attorney, Agent or Firm

US Patent References

4439409, Crystalline aluminosilicate PSH-3 and its process of preparation
Issued on: 03/27/1984
Inventor: Puppe ,   et al.
4859648, Layered metal chalcogenides containing interspathic polymeric chalcogenides
Issued on: 08/22/1989
Inventor: Landis ,   et al.
4954325Composition of synthetic porous crystalline material, its synthesis and use
Issued on: 09/04/1990
Inventor: Rubin, et al.

International Class

B01J 021/06

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