Patent 5272236 Issued on December 21, 1993. Estimated Expiration Date: October 15, 2011. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
526/348.5, N-hexene502/152, Organic compound including carbon-metal bond526/127, Contains non-transition free metal, hydride thereof, or carbon to non-transition metal atom bond526/160, Transition metal bonded to carbon atom526/170, Transition metal bonded to carbon atom526/348.2, At least six carbon atoms526/348.4, Six carbon atoms only526/348.6, At least four carbon atoms526/943POLYMERIZATION WITH METALLOCENE CATALYSTS
Substantially linear olefin polymers having a melt flow ratio, I10 /I2, ࣙ5.63, a molecular weight distribution, Mw /Mn, defined by the equation: Mw /Mn ࣘ(I10 /I2)-4.63, and a critical shear stress at onset of gross melt fracture of greater than about 4×106 dyne/cm2 and their method of manufacture are disclosed. The substantially linear olefin polymers preferably have at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5. The new polymers have improved processability over conventional olefin polymers and are useful in producing fabricated articles such as fibers, films, and molded parts.
Other References
Journal of Polymer Science, Part A, vol. 1, (pp. 2869-2880 (1993)), "Long-Chain Branching Frequency in Polyethylene" by J. E. Guillet
Polymer Preprints, Amer. Chem. Society, vol. 12, No. 1, pp. 277-281, (Mar. 1971), "Evidence of Long-Chain Branching in High Density Polyethylene" by E. E. Drott and R. A. Mendelson
Journal of the American Chemical Society, 98:7, pp. 1729-1742, (Mar. 31, 1976), "Structure and Chemistry of Bis(cyclopentadienyl)-MLn Complexes" by Joseph W. Lauher and Roald Hoffman
Polymer Engineering and Science, vol. 16, No. 12, pp. 811-816, (Dec. 1976), "Influence of Long-Chain Branching on the Viscoelastic Properties of Low-Density Polyethylenes" by L. Wild, R. Ranganath, and D. Knobeloch
Angew. Chem. Int. Ed. Engl., pp. 630-632, (1976), vol. 15, No. 10, "Halogen-Free Soluble Ziegler Catalysts for the Polymerization of Ethylene. Control of Molecular Weight by Choice of Temperature" by Arne Andresen et al
Advances in Organometallic Chemistry, pp. 99-148, vol. 18, (1980), "Ziegler-Natta Catalysis" by Hansjorg Sinn and Walter Kaminsky
Angew. Chem. Int. Ed. Engl., pp. 390-393, vol. 19, No. 5, (1980), "`Living Polymers` on Polymerization with Extremely Productive Ziegler Catalysis" by Hansjorg Sinn, Walter Kaminsky, Hans-Jurgen Vollmer, and Rudiger Woldt
Polymer Bulletin, 9, pp. 464-469, (1983), "Halogen Free Soluble Ziegler Catalysts with Methylalumoxan as Catalyst" by Jens Herwig and Walter Kaminsky
Makromol. Chem., Rapid Commun., 4, pp. 417-421, (1983), "Bis(cyclopentadienyl)zirkon-Verbingungen und Aluminoxanals Ziegler-Katalysatoren fur die Polymerisation und Copolymerisation von Olefinen" by Walter Kaminsky et al
ANTEC Proceedings, pp. 306-309, (1983), "Analysis of Long Chain Branching in High Denisty Polyethylene" by J. K. Hughes
Makromol. Chem., Rapid Commun., (5), pp. 225-228, (1984), "Influence of Hydrogen on the Polymerization of Ethylene with the Homogeneous Ziegler System Bis(cyclopentadienyl)Zirconiumdicholoride/Aluminoxiane" by Walter Kaminsky et al
Journal of Polymer Science, Polymer Chemistry Edition, pp. 2117-2133, (1985), vol. 23, "Homogeneous Ziegler-Natta Catalysis. II. Ethylene Polymerization by IVB Transaction Metal Complexes/Methyl Aluminoxane Catalyst Systems" by E. Giannetti and R. Mazzocchi
Journal of Applied Polymer Science, pp. 3751-3765, (1985), vol. 30, "On the Effects of Very Low Levels of Long Chain Branching on Rheological Behavior in Polyethylene" by B. H. Bersted
Journal of Polymer Science: Polymer Chemistry Edition, pp. 2151-2164, (1985), vol. 23, "Ethylene Propylene Diene Terpolymers Produced with a Homogeneous and Highly Active Zirconium Catalyst" by Walter Kaminsky et al
The Society of Rheology, pp. 337-357, (1986), vol. 30, "Wall Slip in Viscous Fluids and Influence of Materials of Construction" by A. V. Ramamurthy
Makromol. Chem., Macromol. Symp., 4, pp. 103-118, (1986), "Elastomers by Atactic Linkage of -Olefins Using Soluble Ziegler Catalysts" by W. Kaminsky and M. Schlobohm
Journal of Rheology, 31(8), pp. 815-834, (1987), "Wall Slip and Extrudate Distortion in Linear Low-Density Polyethylene" by D. Kalika and M. Denn
Makromol. Chem., 190, pp. 515-526, (1989), "Copolymerization of Cycloalkenes with Ethylene In Presence of Chiral Zirconocene Catalysts" by W. Kaminsky and R. Spiehl
Journal of Macromolecular Science: Reviews in Macromolecular Chemistry and Physics, C29(2&3), pp. 201-303, (1989), "A Review of High Resolution Liquid 13 Carbon Nuclear Magnetic Resonance Characterizations of Ethylene-Based Polymers"
Journal of Non-Newtonian Fluid Mechanics, 36, pp. 255-263, (1990), "Additional Observations on The Surface Melt Fracture Behavior of Linear Low-Density Polyethylene" by R. Moynihan, D. Baird, and R. Ramanathan
Makromol. Chem. Commun., pp. 89-94, (1990), "Terpolymers of Ethylene, Propene and 1,5-Hexadiene Synthesized with Zicronocene/Methylaluminoxane" by W. Kaminsky and H. Drogemuller
Journal of Rheology, 35(4), 3, (May, 1991), pp. 497-552, "Wall Slip of Molten High Density Polyethylene. I. Sliding Plate Rhoemeter Studies" by S. G. Hatzikiriakos and J. M. Dealy
Proceedings of the 1991 IEEE Power Engineering Society, pp. 184-190, (Sep. 22-27, 1991), "New Specialty Linear Polymers (SLP) For Power Cables" by Monica Hendewerk and Lawrence Spenadel
Society of Plastic Engineers Proceedings, Polyolefins VII International Conference, Feb. 24-27, 1991, "Structure/Property Relationships in Exxpol™ Polymers", (pp. 45-66), by C. Speed, B. Trudell, A. Mehta, and F. Stehling
1991 Specialty Polyolefins Conference Proceedings, "The Marketing Challenge Created by Single Site Catalysts in Polyolefins", Sep. 24, 1991, (pp. 41-45), by Michael P. Jeffries
High Polymers, vol. XX, "Crystalline Olefin Polymers", Part I, pp. 495-501
1991 Polymers, Laminations & Coatings Conference, TAPPI Proceedings, presented in Feb. 1991, pp. 289-296, "A New Family of Linear Ethylene Polymers with Enhanced Sealing Performance" by D. Van der Sanden and R. W. Halle
Society of Plastic Engineers 1991 Specialty Polyolefins Conference Proceedings, pp. 41-55, "The Marketing Challenge Created by Single Site Catalysts in Polyolefins" by M. Jefferies, (Sep. 24, 1991)
Advances In Polyolefins, by R. B. Seymour and T. Cheng, (1987), pp. 373-380, "Crystallinity and Morphology of Ethylene -Olefin Copolymers" by P. Schouterden, G. Groeninckx, and H. Reynaers
Advances In Polyolefins, by R. B. Seymour and T. Cheng, (1987), "New Catalysis and Process for Ethylene Polymerization", pp. 337-354, by F. Karol, B. Wagner, I. Levine, G. Goeke, and A. Noshay
Advances In Polyolefins, by R. B. Seymour and T. Cheng, (1987), "Polymerization of Olefins with a Homogeneous Zirconium/Alumoxane Catalysts", pp. 361-371 by W. Kaminsky and H. Hahnsen