U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Elastic substantially linear olefin polymers

Patent 5272236 Issued on December 21, 1993. Estimated Expiration Date: Icon_subject October 15, 2011. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3491073

3645992

Ethylene copolymers
Patent #: 4205021
Issued on: 05/27/1980
Inventor: Morita ,   et al.

Ethylene copolymer
Patent #: 4405774
Issued on: 09/20/1983
Inventor: Miwa ,   et al.

Ethylene-alpha-olefin-polyene random copolymer rubber
Patent #: 4510303
Issued on: 04/09/1985
Inventor: Oda ,   et al.

Process and catalyst for producing polyethylene having a broad molecular weight distribution
Patent #: 4530914
Issued on: 07/23/1985
Inventor: Ewen ,   et al.

Linear ethylene copolymer
Patent #: 4668752
Issued on: 05/26/1987
Inventor: Tominari ,   et al.

Process and catalyst for producing polyethylene having a broad molecular weight distribution
Patent #: 4935474
Issued on: 06/19/1990
Inventor: Ewen, et al.

Process and catalyst for producing reactor blend polyolefins
Patent #: 4937299
Issued on: 06/26/1990
Inventor: Ewen, et al.

Copolymerization of ethylene and an alpha-olefin having six carbon atoms comprising hexene-1 or 4-methyl-pentene-1 in a fluidized bed
Patent #: 4987212
Issued on: 01/22/1991
Inventor: Morterol, et al.

More ...

Inventors

Application

No. 776130 filed on 10/15/1991

US Classes:

526/348.5, N-hexene502/152, Organic compound including carbon-metal bond526/127, Contains non-transition free metal, hydride thereof, or carbon to non-transition metal atom bond526/160, Transition metal bonded to carbon atom526/170, Transition metal bonded to carbon atom526/348.2, At least six carbon atoms526/348.4, Six carbon atoms only526/348.6, At least four carbon atoms526/943POLYMERIZATION WITH METALLOCENE CATALYSTS

Examiners

Primary: Schofer, Joseph L.
Assistant: Wu, David W.

Attorney, Agent or Firm

Foreign Patent References

  • 0416815A2 EP. 03/13/1991
  • 9003414 WO. 04/13/1990

International Classes

C08F 210/08
C08F 210/14

Abstract

Substantially linear olefin polymers having a melt flow ratio, I10 /I2, ࣙ5.63, a molecular weight distribution, Mw /Mn, defined by the equation: Mw /Mn ࣘ(I10 /I2)-4.63, and a critical shear stress at onset of gross melt fracture of greater than about 4×106 dyne/cm2 and their method of manufacture are disclosed. The substantially linear olefin polymers preferably have at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5. The new polymers have improved processability over conventional olefin polymers and are useful in producing fabricated articles such as fibers, films, and molded parts.

Other References

  • Journal of Polymer Science, Part A, vol. 1, (pp. 2869-2880 (1993)), "Long-Chain Branching Frequency in Polyethylene" by J. E. Guillet
  • Polymer Preprints, Amer. Chem. Society, vol. 12, No. 1, pp. 277-281, (Mar. 1971), "Evidence of Long-Chain Branching in High Density Polyethylene" by E. E. Drott and R. A. Mendelson
  • Journal of the American Chemical Society, 98:7, pp. 1729-1742, (Mar. 31, 1976), "Structure and Chemistry of Bis(cyclopentadienyl)-MLn Complexes" by Joseph W. Lauher and Roald Hoffman
  • Polymer Engineering and Science, vol. 16, No. 12, pp. 811-816, (Dec. 1976), "Influence of Long-Chain Branching on the Viscoelastic Properties of Low-Density Polyethylenes" by L. Wild, R. Ranganath, and D. Knobeloch
  • Angew. Chem. Int. Ed. Engl., pp. 630-632, (1976), vol. 15, No. 10, "Halogen-Free Soluble Ziegler Catalysts for the Polymerization of Ethylene. Control of Molecular Weight by Choice of Temperature" by Arne Andresen et al
  • Advances in Organometallic Chemistry, pp. 99-148, vol. 18, (1980), "Ziegler-Natta Catalysis" by Hansjorg Sinn and Walter Kaminsky
  • Angew. Chem. Int. Ed. Engl., pp. 390-393, vol. 19, No. 5, (1980), "`Living Polymers` on Polymerization with Extremely Productive Ziegler Catalysis" by Hansjorg Sinn, Walter Kaminsky, Hans-Jurgen Vollmer, and Rudiger Woldt
  • Polymer Bulletin, 9, pp. 464-469, (1983), "Halogen Free Soluble Ziegler Catalysts with Methylalumoxan as Catalyst" by Jens Herwig and Walter Kaminsky
  • Makromol. Chem., Rapid Commun., 4, pp. 417-421, (1983), "Bis(cyclopentadienyl)zirkon-Verbingungen und Aluminoxanals Ziegler-Katalysatoren fur die Polymerisation und Copolymerisation von Olefinen" by Walter Kaminsky et al
  • ANTEC Proceedings, pp. 306-309, (1983), "Analysis of Long Chain Branching in High Denisty Polyethylene" by J. K. Hughes
  • Makromol. Chem., Rapid Commun., (5), pp. 225-228, (1984), "Influence of Hydrogen on the Polymerization of Ethylene with the Homogeneous Ziegler System Bis(cyclopentadienyl)Zirconiumdicholoride/Aluminoxiane" by Walter Kaminsky et al
  • Journal of Polymer Science, Polymer Chemistry Edition, pp. 2117-2133, (1985), vol. 23, "Homogeneous Ziegler-Natta Catalysis. II. Ethylene Polymerization by IVB Transaction Metal Complexes/Methyl Aluminoxane Catalyst Systems" by E. Giannetti and R. Mazzocchi
  • Journal of Applied Polymer Science, pp. 3751-3765, (1985), vol. 30, "On the Effects of Very Low Levels of Long Chain Branching on Rheological Behavior in Polyethylene" by B. H. Bersted
  • Journal of Polymer Science: Polymer Chemistry Edition, pp. 2151-2164, (1985), vol. 23, "Ethylene Propylene Diene Terpolymers Produced with a Homogeneous and Highly Active Zirconium Catalyst" by Walter Kaminsky et al
  • The Society of Rheology, pp. 337-357, (1986), vol. 30, "Wall Slip in Viscous Fluids and Influence of Materials of Construction" by A. V. Ramamurthy
  • Makromol. Chem., Macromol. Symp., 4, pp. 103-118, (1986), "Elastomers by Atactic Linkage of ଱-Olefins Using Soluble Ziegler Catalysts" by W. Kaminsky and M. Schlobohm
  • Journal of Rheology, 31(8), pp. 815-834, (1987), "Wall Slip and Extrudate Distortion in Linear Low-Density Polyethylene" by D. Kalika and M. Denn
  • Makromol. Chem., 190, pp. 515-526, (1989), "Copolymerization of Cycloalkenes with Ethylene In Presence of Chiral Zirconocene Catalysts" by W. Kaminsky and R. Spiehl
  • Journal of Macromolecular Science: Reviews in Macromolecular Chemistry and Physics, C29(2&3), pp. 201-303, (1989), "A Review of High Resolution Liquid 13 Carbon Nuclear Magnetic Resonance Characterizations of Ethylene-Based Polymers"
  • Journal of Non-Newtonian Fluid Mechanics, 36, pp. 255-263, (1990), "Additional Observations on The Surface Melt Fracture Behavior of Linear Low-Density Polyethylene" by R. Moynihan, D. Baird, and R. Ramanathan
  • Makromol. Chem. Commun., pp. 89-94, (1990), "Terpolymers of Ethylene, Propene and 1,5-Hexadiene Synthesized with Zicronocene/Methylaluminoxane" by W. Kaminsky and H. Drogemuller
  • Journal of Rheology, 35(4), 3, (May, 1991), pp. 497-552, "Wall Slip of Molten High Density Polyethylene. I. Sliding Plate Rhoemeter Studies" by S. G. Hatzikiriakos and J. M. Dealy
  • Proceedings of the 1991 IEEE Power Engineering Society, pp. 184-190, (Sep. 22-27, 1991), "New Specialty Linear Polymers (SLP) For Power Cables" by Monica Hendewerk and Lawrence Spenadel
  • Society of Plastic Engineers Proceedings, Polyolefins VII International Conference, Feb. 24-27, 1991, "Structure/Property Relationships in Exxpol™ Polymers", (pp. 45-66), by C. Speed, B. Trudell, A. Mehta, and F. Stehling
  • 1991 Specialty Polyolefins Conference Proceedings, "The Marketing Challenge Created by Single Site Catalysts in Polyolefins", Sep. 24, 1991, (pp. 41-45), by Michael P. Jeffries
  • High Polymers, vol. XX, "Crystalline Olefin Polymers", Part I, pp. 495-501
  • 1991 Polymers, Laminations & Coatings Conference, TAPPI Proceedings, presented in Feb. 1991, pp. 289-296, "A New Family of Linear Ethylene Polymers with Enhanced Sealing Performance" by D. Van der Sanden and R. W. Halle
  • Society of Plastic Engineers 1991 Specialty Polyolefins Conference Proceedings, pp. 41-55, "The Marketing Challenge Created by Single Site Catalysts in Polyolefins" by M. Jefferies, (Sep. 24, 1991)
  • Advances In Polyolefins, by R. B. Seymour and T. Cheng, (1987), pp. 373-380, "Crystallinity and Morphology of Ethylene ଱-Olefin Copolymers" by P. Schouterden, G. Groeninckx, and H. Reynaers
  • Advances In Polyolefins, by R. B. Seymour and T. Cheng, (1987), "New Catalysis and Process for Ethylene Polymerization", pp. 337-354, by F. Karol, B. Wagner, I. Levine, G. Goeke, and A. Noshay
  • Advances In Polyolefins, by R. B. Seymour and T. Cheng, (1987), "Polymerization of Olefins with a Homogeneous Zirconium/Alumoxane Catalysts", pp. 361-371 by W. Kaminsky and H. Hahnsen
  • Derwent 90-239017/3
PatentsPlus Images
Enhanced PDF formats
loading...
PatentsPlus: add to cart
PatentsPlus: add to cartSearch-enhanced full patent PDF image
$9.95more info
 
Sign InRegister
Username  
Password   
forgot password?