U.S. patents available from 1976 to present.
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Photovoltaic cell and method

Patent 5261968 Issued on November 16, 1993. Estimated Expiration Date: Icon_subject January 13, 2012. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Methods for improving solar cell open circuit voltage
Patent #: 4178395
Issued on: 12/11/1979
Inventor: Jordan ,   et al.

Thin film photovoltaic cells having blocking layers
Patent #: 4251286
Issued on: 02/17/1981
Inventor: Barnett

Polycrystalline photovoltaic cell
Patent #: 4362896
Issued on: 12/07/1982
Inventor: Singh

Photovoltaic cell including doped cadmium telluride, a dislocation preventing agent and improved ohmic contacts
Patent #: 4568792
Issued on: 02/04/1986
Inventor: Mooney ,   et al.

Barrier layer for photovoltaic devices
Patent #: 4598306
Issued on: 07/01/1986
Inventor: Nath ,   et al.

CuInSe2 thin film solar cell with thin CdS and transparent window layer
Patent #: 4611091
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Inventor: Choudary ,   et al.

Thin film cadmium telluride solar cell
Patent #: 4650921
Issued on: 03/17/1987
Inventor: Mitchell

Solar cell module
Patent #: 4705911
Issued on: 11/10/1987
Inventor: Nakano ,   et al.

Method for forming a polycrystalline monolayer
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Issued on: 04/05/1988
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Solar cells incorporating transparent electrodes comprising hazy zinc oxide
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Issued on: 01/07/1992
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Inventor

Assignee

Application

No. 819281 filed on 01/13/1992

US Classes:

136/244, Panel or array136/256, Contact, coating, or surface geometry136/258, Polycrystalline or amorphous semiconductor136/260, Cadmium containing136/264, Selenium or tellurium containing257/184, Light responsive structure257/E27.124, In a repetitive configuration, e.g. planar multi-junction solar cells (EPO)257/E31.017, Characterized by doping material (EPO)257/E31.126, Transparent conductive layer (e.g., transparent conductive oxide (TCO), indium tin oxide (ITO) layer) (EPO)438/85, Having metal oxide or copper sulfide compound semiconductive component438/94, Heterojunction438/95, Chalcogen (i.e., oxygen (O), sulfur (S), selenium (Se), tellurium (Te)) containing438/97Polycrystalline semiconductor

Examiners

Primary: Weisstuch, Aaron

Attorney, Agent or Firm

International Classes

H01L 031/042
H01L 031/18
H01L 031/072
H01L 031/036.8

Abstract

An improved photovoltaic panel and method of forming a photovoltaic panel are disclosed for producing a high efficiency CdS/CdTe photovoltaic cell. The photovoltaic panel of the present invention is initially formed with a substantially thick CdS layer, and the effective thickness of the CdS layer is substantially reduced during regrowth to both form large diameter CdTe crystals and substantially reduce the effective thickness of the CdS layer by diffusion into the CdTe layer such that a majority of sunlight having a wavelength less than 520 nm passes through the CdS layer to the photovoltaic junction. Shorting of individual cells is substantially minimized by providing a conductive layer which is formed from two tin oxide layers, each having substantially dissimilar electrical conductivity, such that an electrically-conductive tin oxide layer interconnects the plurality of photovoltaic cells, while the comparatively high resistivity tin oxide layer prevents shorting of a cell. The electron density of the high resistivity tin oxide layer may be adjusted to be within a magnitude of approximately three orders of the presumed electron density of the CdTe layer, such that a energy-producing junction is formed in any area of flaws in the CdS layer by the CdTe layer and tin oxide layer. The photovoltaic panel of the present invention has a low material and manufacturing cost, yet produces a surprisingly high efficiency to produce a low cost per output watt photovoltaic panel.

Other References

  • K. W. Mitchell et al., Conference Record, 18th IEEE Photovoltaic Specialists Conference, (1985), pp. 1359-1364
  • "Properties of Screen-Printed and Sintered CdTe Film Formed on a CdS Sintered Film", Technical Digest of the International PVSEC-3, 1987, by Matsumoto et al., pp. 695-698
  • "Effect of Resistivity of CdS Sintered Film on Photovoltaic Properties of Screen-Printed CdS/CdTe Solar Cell", Japanese Journal of Applied Physics, vol. 22, Dec. 1983, by Uda et al., pp. 1832-1836
  • "Preparation of Low Resistance Contact Electrode in Screen Printed CdS/CdTe Solar Cell", Japanese Journal of Applied Physics, vol. 22, Dec. 1983, by Kuribayashi et al., pp. 1828-1831
  • "Screen Printed Thin Film CdS/CdTe Solar Cell", Japanese Journal of Applied Physics, vol. 19, Apr. 1980, by Nakayama et al., pp. 703-712
  • "All Screen Printed CdS/CdTe Solar Cell", IEEE Photovoltaic Specialists Conf., (1982), by Uda et al., pp. 801-804
  • "Optical Energy Gap of the Mixed Crystal CdSTe", Japan. J. Appl. Phys., vol. 12, 1973, by Ohata et al., pp. 1641-1642
  • "Stability of Screen Printed CdS/CdTe Solar Cells", Japanese Journal of Applied Physics, vol. 22, Dec. 1983, by Uda et al., pp. 1822-1827
  • "CdS/CdTe Solar Cells by the Screen-Printing-Sintering Technique", IEEE Photovoltaic Specialists Conference, 1990, by Suyama et al., pp. 498-503
  • "Preparation and Photoconductive Properties of Sintered Films of CdS-CdTe Mixed Crystals", Phys. Stat. Soc. A., vol. 39, 1977, by Saraie et al., pp. 331-336
  • "Electrical and Microstructural Properties of Screenprinted CdS Layers for CdS-CdTe Solar Cells", IEEE Photovoltaic Specialists Conference, 1988, by Clemminck et al., pp. 1585-1589
  • "Progress Towards High Efficiency, Thin Film CdTe Solar Cells", IEEE Photovoltaic Specialists Conference, 1985, by Mitchell et al., pp. 1359-1364
  • S. Ikegami, Solar Cells, vol. 23, pp. 89-105 (1988
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