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US Patent 5254296 - Method to double the piezo-and pyroelectric of polyvinylidine fluoride (PVDF) films

US Patent Issued on October 19, 1993
Estimated Patent Expiration Date: Icon_subject November 13, 2011Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

Polyvinylidene fluoride (PVDF) films and co-polymers thereof possess the highest values of piezoelectric and pyroelectric constants of any known polymer. These films, up to present, have been first subjected to stretching and then to a high electric field (or corona charge) at an elevated temperature to provide a maximum piezoelectric constants (d31) of about 30-35 pC/N and a maximum pyroelectric constants (p) of about 3.5 nC/cm2 K. It has now been found that the piezoelectric constant d31 and pyroelectric constant p of these films can be increased up to about 60 pC/N and 6 nC/cm2 K respectively when they are subjected to simultaneously stretching and corona poling with a poling field Ep =0.55MV/cm, a stretching ratio S.R.=4.5X and a poling temperature Tp =80° C.

Inventor

Assignee

Application

No. 791275 filed on 11/13/1991

US Classes:

264/435, Molecular aligning or molecular orientating (e.g., poling, etc.)264/288.4, Stretching by applying tension264/483, Plasma (e.g., corona, glow discharge, etc.)425/174.8EElectro-static

Field of Search

264/288.4, Stretching by applying tension425/174.8EElectro-static

Examiners

Primary: Thurlow, Jeffery

Attorney, Agent or Firm

US Patent References

4265841, Method for production of composite piezoelectric material
Issued on: 05/05/1981
Inventor: Fujimori ,   et al.
4308370, Piezoelectric and pyroelectric polymer film and process for preparing same
Issued on: 12/29/1981
Inventor: Fukada ,   et al.
4345359, Process for manufacturing a piezoelectric transducer made from a polymer material
Issued on: 08/24/1982
Inventor: Micheron
4403382, Process for manufacturing electromechanical transducers using at least one polymer film
Issued on: 09/13/1983
Inventor: Facoetti ,   et al.
4427609, Process for producing piezoelectric polymer films
Issued on: 01/24/1984
Inventor: Broussoux ,   et al.
4481158, Extrusion of films of vinylidene fluoride polymers
Issued on: 11/06/1984
Inventor: Georlette ,   et al.
4557880, Piezoelectric and pyroelectric film
Issued on: 12/10/1985
Inventor: Pantelis
4668449, Articles comprising stabilized piezoelectric vinylidene fluoride polymers
Issued on: 05/26/1987
Inventor: Soni ,   et al.
4800048Die drawing process and apparatus for piezoelectric polymer films and tubes
Issued on: 01/24/1989
Inventor: Bloomfield ,   et al.

Foreign Patent References

  • 734901 SU 05/22/1980

International Class

B29C 035/00

Foreign Application Priority Data

1990-12-11 CA

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