U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Method for the manufacture and recovery of methyl tertiary butyl ether

Patent 5243091 Issued on September 7, 1993. Estimated Expiration Date: Icon_subject November 19, 2012. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Recovery of ethers Patent #: 4144138
Issued on: 03/13/1979
Inventor: Rao ,   et al.

Inventors

Assignee

Application

No. 978570 filed on 11/19/1992

US Classes:

568/697, Preparing by reacting an olefin and an organic hydroxy containing compound (H of -OH may be replaced by a Group IA or IIA light metal)568/698, Preparing by dehydration of an organic hydroxy containing compound (H of -OH may be replaced by a Group IA or IIA light metal)568/699, Purification or recovery568/922Heavy metal or aluminum containing compound utilized

Examiners

Primary: Mars, Howard T.

Attorney, Agent or Firm

International Class

C07C 041/09

Abstract

A method for the preparation of methyl tertiary butyl ether is provided wherein a mixture of methanol and substantially peroxides-free tertiary butyl alcohol are catalytically reacted to form a reaction product that is separated into a first lighter distillation fraction comprising isobutylene, methanol and methyl tertiary butyl ether and a second heavier distillation fraction comprising methanol, tertiary butyl alcohol and water, wherein the first distillation fraction and a first recycle isobutylene fraction are reacted to form an isobutylene conversion product that is charged, together with recycle isobutylene to a methanol extraction zone and countercurrently contacted with water to provide an overhead extract comprising aqueous isobutylene, and wherein the isobutylene is recovered and recycled.

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