U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Joint, a laminate, and a method of preparing a nickel-titanium alloy member surface for bonding to another layer of metal

Patent 5242759 Issued on September 7, 1993. Estimated Expiration Date: Icon_subject May 21, 2011. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2858600

2882593

2906008

3002265

3037880

3923609

Apparatus containing silicon metal joints
Patent #: 3956098
Issued on: 05/11/1976
Inventor: Welch ,   et al.

Method of applying a firmly adherent metallic coating to titanium and titanium alloy
Patent #: 4024303
Issued on: 05/17/1977
Inventor: Hahn

Sealing cover for an hermetically sealed container
Patent #: 4331258
Issued on: 05/25/1982
Inventor: Geschwind

Ti-base material for eyeglass-frames and a method for producing same
Patent #: 4427746
Issued on: 01/24/1984
Inventor: Takamura

More ...

Inventor

Assignee

Application

No. 703493 filed on 05/21/1991

US Classes:

428/610, Having composition, density, or hardness gradient228/207, Applying flux228/262.72, Brazing or soldering427/309, Inorganic base427/310, Fluxing428/660Refractory (Group IVB, VB, or VIB) metal-base component

Examiners

Primary: Zimmerman, John J.

Attorney, Agent or Firm

Foreign Patent References

  • 56-81665 JP 07/13/1981
  • 58-167073 JP 10/13/1983
  • 59-116342 JP 07/13/1984
  • 746648 GB 03/13/2012

International Classes

B32B 005/14
B32B 015/00
B23K 035/363

Abstract

A joint and a laminate including a nickel-titanium alloy such as nitinol and a method for preparing the surface of a nickel-titanium alloy member for bonding solder material and, electively, another similar or dissimilar member thereto. The method includes applying an aluminum paste flux to the titanium oxide coated surface of a nickel-titanium alloy member and heating the flux to its activation temperature. The flux removes and suspends the titanium oxide therein along with leaching titanium from the base alloy member surface to form a nickel-rich interface surface. The activated flux also coats the nickel-rich interface layer for protection from further oxidation. A bonding material such as a tin-silver solder is flowed onto the nickel-rich interface surface to displace the activated flux. Electively, another member is applied to the molten solder to form a joint between the two members. The residual flux is cleaned from the joint to prevent further deterioration of the base metal. The solder joint includes the base nickel-titanium alloy metal, the nickel-rich interface surface, and the solder material. Electively, any other member may be applied to this joint in the molten state to form a metallic bond therebetween.

Other References

  • Manko, H. H., "Solders and Soldering", McGraw Hill Book Co., 1964, pp. 8-11, 14-15, 112-113, 174-183
  • Buehler, W. J. et al., "Summary of Recent Research on the Nitinol Alloys . . . ", Pergamon Press, Oxford, Ocean Engng. vol. 1, pp. 105-120 (1968)
  • Buehler, W. J. et al., "55-Nitinol-Unique Alloy Wire", preprint of Wire Journal article, pp. 1-15, no date
  • Abstract of Japanese Patent Application Serial No. 90JP-286448, JP 04162982-A, Jun. 8, 1992
  • Chan, C. M., et al., "Oxidation of an NiTi Alloy", Surface and Interface Analysis, vol. 15, pp. 349-354 (1990
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