U.S. patents available from 1976 to present.
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Lead-free mirrors and environmentally safe manufacture thereof

Patent 5215832 Issued on June 1, 1993. Estimated Expiration Date: Icon_subject October 8, 2012. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

1977639

2123049

Reflecting mirror
Patent #: 4009947
Issued on: 03/01/1977
Inventor: Nishida ,   et al.

Multi-layer reflectors
Patent #: 4340646
Issued on: 07/20/1982
Inventor: Ohno ,   et al.

Primer for metal films on nonmetallic substrates
Patent #: 4563400
Issued on: 01/07/1986
Inventor: Criss ,   et al.

Radiant energy reflector and method for construction thereof
Patent #: 4666263
Issued on: 05/19/1987
Inventor: Petcavich

Protective overcoat of titanium nitride films
Patent #: 4690871
Issued on: 09/01/1987
Inventor: Gordon

Stainless steel overcoat for sputtered films
Patent #: 4692389
Issued on: 09/08/1987
Inventor: Gillery ,   et al.

Cyanamide salts of non-lead metals as corrosion inhibitive pigments in mirror back coatings
Patent #: 4707405
Issued on: 11/17/1987
Inventor: Evans ,   et al.

Silicon nitride protective coatings for silvered glass mirrors
Patent #: 4780372
Issued on: 10/25/1988
Inventor: Tracy ,   et al.

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Inventors

Assignee

Application

No. 958593 filed on 10/08/1992

US Classes:

428/623, Adjacent to each other204/192.27, Reflective428/622, More than one such component428/626, Synthetic resin428/627, Boride, carbide or nitride component428/630, Noncrystalline silica or noncrystalline plural-oxide component (e.g., glass, etc.)428/632, Oxide-containing component428/687Surface feature (e.g., rough, mirror)

Examiners

Primary: Zimmerman, John J.

Attorney, Agent or Firm

Foreign Patent References

  • 1258659 FR. 03/12/1991
  • 58-149002 JP 09/12/1983

International Classes

B32B 017/06
C23C 014/08
C23C 014/18
G02B 005/08

Abstract

Mirrors are formed in an environmentally compatible and substantially pollution-free manner by a sputtering process in which a transparent substrate such as glass has first sputtered upon it a primer layer and then a reflective layer of silver or other bright reflective metal. A barrier layer is provided over the reflective layer to protect the latter from corrosive environments. If the transmittance of the reflective layer is greater than zero percent, the barrier layer includes a different bright reflective metal sufficient to reduce the transmittance of the combined reflective and barrier layers to zero percent. The mirror includes a lead free polymeric protective layer spaced further from the transparent substrate than the barrier layer. The inclusion of zinc pigment in the polymeric coating provides sulfiding protection, and the use of an outer sputtered on film of zinc or zinc oxide provides substantial adhesion thereto of the polymeric coating.

Other References

  • McGraw-Hill Encyclopedia of Science and Technology, vol. II, Sixth Ed. p. 272
  • Eagle Zinc Company advertising brochure
  • Advertising materials of Heocotech Ltd., entitled "HEUCOPHOS--White, non toxic, anti-corrosive pigments
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