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US Patent 5215832 - Lead-free mirrors and environmentally safe manufacture thereof

US Patent Issued on June 1, 1993
Estimated Patent Expiration Date: Icon_subject October 8, 2012Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

Mirrors are formed in an environmentally compatible and substantially pollution-free manner by a sputtering process in which a transparent substrate such as glass has first sputtered upon it a primer layer and then a reflective layer of silver or other bright reflective metal. A barrier layer is provided over the reflective layer to protect the latter from corrosive environments. If the transmittance of the reflective layer is greater than zero percent, the barrier layer includes a different bright reflective metal sufficient to reduce the transmittance of the combined reflective and barrier layers to zero percent. The mirror includes a lead free polymeric protective layer spaced further from the transparent substrate than the barrier layer. The inclusion of zinc pigment in the polymeric coating provides sulfiding protection, and the use of an outer sputtered on film of zinc or zinc oxide provides substantial adhesion thereto of the polymeric coating.

Other References

  • McGraw-Hill Encyclopedia of Science and Technology, vol. II, Sixth Ed. p. 272
  • Eagle Zinc Company advertising brochure
  • Advertising materials of Heocotech Ltd., entitled "HEUCOPHOS--White, non toxic, anti-corrosive pigments

Inventors

Assignee

Application

No. 958593 filed on 10/08/1992

US Classes:

428/623, Adjacent to each other204/192.27, Reflective428/622, More than one such component428/626, Synthetic resin428/627, Boride, carbide or nitride component428/630, Noncrystalline silica or noncrystalline plural-oxide component (e.g., glass, etc.)428/632, Oxide-containing component428/687Surface feature (e.g., rough, mirror)

Field of Search

428/687, Surface feature (e.g., rough, mirror)428/621, With additional, spatially distinct nonmetal component428/622, More than one such component428/623, Adjacent to each other428/624, Organic component428/626, Synthetic resin428/631, Film (e.g., glaze, etc.)428/632, Oxide-containing component428/633, Plural oxides428/673, Ag-base component428/457, Of metal428/469, Next to metal salt or oxide428/627, Boride, carbide or nitride component428/630, Noncrystalline silica or noncrystalline plural-oxide component (e.g., glass, etc.)359/884, With selective absorption or transparent overcoating359/883, Laminated or layered mirror support359/838, MIRROR359/871, With support204/192.27Reflective

Examiners

Primary: Zimmerman, John J.

Attorney, Agent or Firm

US Patent References

1977639, 2123049, 4009947, Reflecting mirror
Issued on: 03/01/1977
Inventor: Nishida ,   et al.
4340646, Multi-layer reflectors
Issued on: 07/20/1982
Inventor: Ohno ,   et al.
4563400, Primer for metal films on nonmetallic substrates
Issued on: 01/07/1986
Inventor: Criss ,   et al.
4666263, Radiant energy reflector and method for construction thereof
Issued on: 05/19/1987
Inventor: Petcavich
4690871, Protective overcoat of titanium nitride films
Issued on: 09/01/1987
Inventor: Gordon
4692389, Stainless steel overcoat for sputtered films
Issued on: 09/08/1987
Inventor: Gillery ,   et al.
4707405, Cyanamide salts of non-lead metals as corrosion inhibitive pigments in mirror back coatings
Issued on: 11/17/1987
Inventor: Evans ,   et al.
4780372, Silicon nitride protective coatings for silvered glass mirrors
Issued on: 10/25/1988
Inventor: Tracy ,   et al.
4880668, Mirror protective composition comprising 2-mercaptothiazoline
Issued on: 11/14/1989
Inventor: Hayes, et al.
4883721, Multi-layer low emissivity thin film coating
Issued on: 11/28/1989
Inventor: Nalepka, et al.
4898789, Low emissivity film for automotive heat load reduction
Issued on: 02/06/1990
Inventor: Finley
4898790, Low emissivity film for high temperature processing
Issued on: 02/06/1990
Inventor: Finley
4902580, Neutral reflecting coated articles with sputtered multilayer films of metal oxides
Issued on: 02/20/1990
Inventor: Gillery
4948677High transmittance, low emissivity article and method of preparation
Issued on: 08/14/1990
Inventor: Gillery

Foreign Patent References

  • 1258659 FR. 03/21/1991
  • 58-149002 JP 09/21/1983

International Classes

B32B 017/06
C23C 014/08
C23C 014/18
G02B 005/08

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