U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Safe acidic hard surface cleaner

Patent 5192460 Issued on March 9, 1993. Estimated Expiration Date: Icon_subject March 9, 2010. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3218260

3586633

Non-fluoride acid compositions for cleaning aluminum surfaces
Patent #: 4435223
Issued on: 03/06/1984
Inventor: Dollman

Acidic liquid detergent composition for cleaning ceramic tiles without eroding grout
Patent #: 4501680
Issued on: 02/26/1985
Inventor: Aszman ,   et al.

Aqueous liquid detergent composition with dicarboxylic acids and organic solvent
Patent #: 4581161
Issued on: 04/08/1986
Inventor: Nedonchelle

Aqueous liquid cleaner containing an anionic surfactant and an ethoxylated aliphatic vicinal hydroxyamine
Patent #: 4666615
Issued on: 05/19/1987
Inventor: Disch ,   et al.

Low-foaming alkaline, hypochlorite cleaner Patent #: 4878951
Issued on: 11/07/1989
Inventor: Pochard, et al.

Inventors

Application

No. 388731 filed on 07/31/1989

US Classes:

510/238, For grouted tile, bathtub, or procelain or ceramic surface (e.g., ceramic bathroom tile, etc.)134/3, Including acidic agent510/362, For removing soap scum or curd or combustion residues (e.g., carbon deposits, etc.)510/365, For removing greasy or oily contaminant from a substrate510/406, Packaged or gas-propelled composition510/417, Plural immiscible liquid phases (e.g., emulsion, oily and aqueous layers, etc.)510/425, With soap or diverse sulfur containing surfactant component510/434, Polycarboxylic acid component, or acid anhydride or salt thereof (e.g., acrylic acid polymer, maleic anhydride, sodium citrate, etc.)510/436, Organic phosphorus containing component510/469Carbon bonded directly to the phosphorus (e.g., phosphonic acid or salt or ester thereof, etc.)

Examiners

Primary: Howard, Jacqueline V.
Assistant: Silbermann, J.

Attorney, Agent or Firm

Foreign Patent References

  • 0027083 EP. 04/13/1981
  • 0040038 EP. 11/13/1981
  • 0336878 EP. 10/13/1989
  • 2106927 GB. 04/13/1983

International Classes

C11D 001/12
C11D 001/34
C11D 001/66
C11D 001/83

Abstract

An acidic aqueous cleaner, preferably in emulsion or microemulsion form, which is of a pH in the range of one to four and is useful for cleaning hard surfaced items, such as bathtubs, sinks, tiles and porcelains, and even some such items which are not acid resistant, such as those of a European enamel known as zirconium white enamel, comprises synthetic organic detergent, such as a mixture of anionic and nonionic detergents, e.g., sodium paraffin sulfonate, higher fatty alcohol ethoxylate sulfate and higher fatty alcohol or phenol ethoxylate, organic acid, e.g., mixture of succinic, glutaric and adipic acids, phosphonic acid, e.g., aminotris-(methylenephosphonic acid) and phosphoric acid in an aqueous medium.The acidic cleaner is useful to remove soap scum, lime scale and grease from surfaces of the mentioned items without adversely affecting such surfaces, and removals of the scum, scale and grease are easy, being effected by applying the microemulsion to the surface to be cleaned, followed by wiping it off. Although the cleaned surfaces may be rinsed that is often not necessary and the surfaces will be left clean and shiny after wiping, even without rinsing, or with minimal rinsing.In the described emulsions the organic acid components effectively remove soap scum and lime scale, the detergents remove greasy soils and promote effective contact between the acid and the surfaces to be treated, and the combination of phosphoric and phosphonic acids prevents acidic attack by the organic acid(s) on the European enamel surface being cleaned.

Other References

  • McCutcheon's Detergents and Emulsifiers, North American Edition 1978, p. 20
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