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US Patent 5153081 - Lithium manganese oxide compound

US Patent Issued on October 6, 1992
Estimated Patent Expiration Date: Icon_subject July 27, 2010Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

The invention provides a novel lithium manganese oxide compound in which oxygen anions, lithium cations and manganese cations are arranged in layers, each layer of lithium cations being sandwiched between two layers of oxygen anions, each layer of manganese cations being sandwiched between two layers of oxygen anions and each layer of oxygen anions being sandwiched between a layer of lithium cations and a layer of manganese cations. The invention also provides a method of making the compound; and an electrochemical cell employing the compound as its cathode.

Other References

  • Goodenough, "Manganese Oxides as Battery Cathodes", in Proc. of the Symposium on Manganese Dioxide Electrode Theory and Practice for Electrochemical Applications Electrochemical Society, Battery Division, Proceedings, vol. 85-4 (1986), pp. 77-96
  • Rossouw, M. H., et al. "Structural Aspects of Lithium-Manganese-Oxide Electrodes for Rechargeable Lithium Batteries", Materials Research Bulletin, vol. 25 (1990), pp. 173-182
  • DeKock, A. et al. "Defect Spinels in the System Lithium Oxide . y-Manganese Dioxide (y>2.5): A Neutron-Diffraction Study and Electrochemical Characterization of Li2 Mn4 O9 ", Mat. Res. Bull, vol. 25, (1990), p. 657
  • M. Jansen, "On the Knowledge of the Sodium Chloride-Type Structure Family: New Investigations on Li2 MnO3 ", Zeitschrift fuer Anorg. Allgem. Chemie, vol. 397 (1973), pp. 279-289
  • J. C. Hunter. "Preparation of a New Crystal Form of Manganese Dioxide: λ-MnO2 ", Chemical Abstracts, vol. 95, #160312t (1981)
  • Rossouw, M., et al. "Lithium Manganese Oxides from Li2 MnO3 for Rechargeable Lithium Battery Operations", Mat. Res. Bull., vol. 26, pp. 463-473 (1991)
  • David et al., "The Crystal Structure of Li2 MNO2 ", Revue de Chimie Minerale, 20, 1983, pp. 636-642
  • Wells, A. F., Structural Inorganic Chemistry, the passage "The γ-MO.OH Structure" at pp. 527-528
  • Nohma, T., et al. "Manganese Oxides for a Lithium Secondary Battery--Composite Dimensional Manganese Oxide (CDMO)", Journal of Power Sources, 26, 389-396 (1989)
  • Hunter, James C., "Preparation of a New Crystal Form of Manganese Dioxide: λ-MnO2," Journal of Solid State Chemistry, 39, 142-147 (1981

Inventors

Assignee

Application

No. 558816 filed on 07/27/1990

US Classes:

429/333, And acyclic ether solvent423/599, Manganese (e.g., manganate, etc.)423/641, Alkali metal (Li, Na, K, Rb, or Cs)429/224, Manganese component is active material429/338, The hetero ring is a cyclic carbonate (e.g., ethylene carbonate, propylene carbonate, etc.)429/342Acyclic carbonate solvent

Field of Search

423/605, Group VIIB metal (Mn, Tc, or Re)423/599, Manganese (e.g., manganate, etc.)423/641, Alkali metal (Li, Na, K, Rb, or Cs)429/224Manganese component is active material

Examiners

Primary: Lewis, Michael
Assistant: DiMauro, Peter

Attorney, Agent or Firm

US Patent References

2562705, 4246253, MnO2 derived from LiMn2 O4
Issued on: 01/20/1981
Inventor: Hunter
4277360, Manganese dioxide
Issued on: 07/07/1981
Inventor: Mellors ,   et al.
4758484, Non-aqueous secondary cell
Issued on: 07/19/1988
Inventor: Furukawa ,   et al.
4828834, Rechargeable organic electrolyte cell
Issued on: 05/09/1989
Inventor: Nagaura ,   et al.
4959282, Cathode active materials, methods of making same and electrochemical cells incorporating the same
Issued on: 09/25/1990
Inventor: Dahn, et al.
4980251Method of synthesizing a lithium manganese oxide
Issued on: 12/25/1990
Inventor: Thackeray, et al.

Foreign Patent References

  • 009934 EP. 04/21/1980
  • 0265950 EP. 05/21/1988
  • 2221213A GB. 01/21/1990

International Classes

H01M 006/16
H01M 004/50
C01G 045/12

Foreign Application Priority Data

1989-07-28 ZA

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