Iron-antimony-molybdenum-containing oxide catalyst composition and process for preparing the same
Patent 5132269 Issued on July 21, 1992. Estimated Expiration Date: 
September 9, 2011. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
September 9, 2011. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.Patent ReferencesCatalyst for use in and process for preparing acrylonitrile Oxidation/ammoxidation catalyst Process for producing unsaturated aldehydes, and unsaturated fatty acids Sb-containing catalysts by Sb-oxide impregnation Catalyst compositions and their use for the preparation of methacrolein Process for preparing iron-antimony-phosphorus-containing catalyst for fluidized bed process Patent #: 4981830 InventorsAssigneeApplicationNo. 756708 filed on 09/09/1991US Classes:502/205, And bismuth containing502/212, And bismuth containing502/215, Selenium or tellurium or compound containing same502/302, Of lanthanide series (i.e., atomic number 57 to 71 inclusive)502/303, Lanthanum502/304, Cerium502/306, And Group II metal containing (i.e., alkaline earth, Be, Mg, Zn, Cd or Hg)502/307, Zinc502/308, And Group IV metal containing (i.e., Ti, Zr, Hf, Ge, Sn or Pb)502/309, Titanium containing502/310, Tin containing502/311, And Group V metal containing (i.e., V, Nb, Ta, As, Sb or Bi)558/322, Tellurium containing material utilized558/323, Molybdenum containing material utilized558/324Bismuth containing material utilizedExaminersPrimary: Shine, W. J.Attorney, Agent or FirmForeign Patent References
International ClassesB01J 023/78B01J 023/84 B01J 023/88 B01J 027/057 Foreign Application Priority Data1990-09-10 JPAbstractAn iron-antimony-molybdenum-containing oxide catalyst composition for oxidation reactions, comprising a crystalline iron antimonate having a crystallite size of 100 Å or more, said catalyst being represented by the following empirical formula:Fea Sbb Moc Ld Ke Mm Nn Qq Rr Tt Oxwherein L represents at least one element selected from the group consisting of Bi and Te; M represents at least one element selected from the group consisting of Cu, Mg, Zn, La, Ce, Al, Cr, Mn, Co, Ni and Sn; N represents at least one element selected from the group consisting of Be, Ca, Sr, Ba, Y, Pr, Nd, Th, U, Ti, Zr, Hf, Nb, Ta, Re, Ru, Os, Rh, Ir, Pd, Pt, Ag, Au, Cd, Al, Ga, In, Ge and Pb; Q represents at least one element selected from the group consisting of V and W; R represents at least one element selected from the group consisting of Li, Na, Rb, Cs, and Tl; T represents at least one element selected from the group consisting of B, P, As and Se; a, b, c, d, e, m, n, q, r, t and x each is an atomic ratio, wherein when a is 10, b is 5 to 60, c is 5 to 30, d is 0.01 to 10, e is 0.01 to 5, m is 0 to 30, n is 0 to 10, q is 0 to 5, r is 0 to 3, t is 0 to 5, and x is a number of oxygen atoms as determined corresponding to the oxides formed by combining the above mentioned components.Field of SearchAnd bismuth containingAnd bismuth containing Selenium or tellurium or compound containing same Of lanthanide series (i.e., atomic number 57 to 71 inclusive) Lanthanum Cerium And Group II metal containing (i.e., alkaline earth, Be, Mg, Zn, Cd or Hg) Zinc And Group IV metal containing (i.e., Ti, Zr, Hf, Ge, Sn or Pb) Titanium containing Tin containing And Group V metal containing (i.e., V, Nb, Ta, As, Sb or Bi) Processes of attaching cyano to carbon by reaction of an inorganic cyanide with an organic compound (e.g., using HCN, cyanogen, metal cyanide, ammonium cyanide, cyanogen chloride, etc.) Molybdenum containing material utilized Bismuth containing material utilized |
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