Patent ReferencesPlasma etchant mixture Anisotropic plasma etching of tungsten Anisotropic silicon etching in fluorinated plasma Patent #: 4741799 InventorsAssigneeApplicationNo. 658254 filed on 02/20/1991US Classes:216/75, Substrate contains elemental metal, alloy thereof, or metal compound204/192.37, Silicon containing216/79, Etching silicon containing substrate252/79.1, ETCHING OR BRIGHTENING COMPOSITIONS257/E21.218, Plasma etching; reactive-ion etching (EPO)257/E21.234, Characterized by their behavior during process, e.g., soluble mask, redeposited mask (EPO)257/E21.311, Using plasma (EPO)257/E21.312, Of silicon-containing layer (EPO)257/E21.314, Using mask (EPO)438/695, Simultaneous etching and coating438/720Electrically conductive material (e.g., metal, conductive oxide, etc.)ExaminersPrimary: Powell, William A.Attorney, Agent or FirmInternational ClassesH01L 021/306B44C 001/22 C23F 001/02 C03C 015/00 AbstractThe present invention relates to the etching of a gate film, a tungsten film, a silicon film, etc. In the present invention, use is made of an etching gas comprising a mixture composed of a reductive fluoride gas, a hydrocarbon gas and a halogen gas having a larger atomic diameter than a material to be etched, or a mixture composed of a reductive fluoride gas and a Cl-containing hydrocarbon gas, and the process comprises the step of conducting anisotropic etching of a material to be etched with an etching gas (a reductive fluoride gas), the step of forming a protective film by a depositing gas (a hydrocarbon gas), and the step of removing excess deposits formed as the protective film by means of a gas reactive with the protective film (a halogen gas or a Cl-containing hydrogen gas), wherein anisotropic etching is conducted by forming a protective film on a side wall while removing excess deposits formed as the protective film, thus enabling the anisotropic etching to be conducted with good accuracy. |
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