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High-flow rate capacity aerobic biological dehalogenation reactor

Patent 5037551 Issued on August 6, 1991. Estimated Expiration Date: Icon_subject December 19, 2008. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Microbial degradation of DDT
Patent #: 3979283
Issued on: 09/07/1976
Inventor: Prudom

Method for producing microbial cells and use thereof to produce oxidation products
Patent #: 4266034
Issued on: 05/05/1981
Inventor: Patel ,   et al.

Biotransformations using methane-utilizing bacteria
Patent #: 4323649
Issued on: 04/06/1982
Inventor: Higgins

Procedure for purifying waste water in a floating layer reactor
Patent #: 4344848
Issued on: 08/17/1982
Inventor: Hakulinen

Production of epoxides such as propylene oxide using packed catalytic bed containing moist resting cells exhibiting oxygenase activity
Patent #: 4348476
Issued on: 09/07/1982
Inventor: Hou

Medium and process for disposing of hydrocarbon wastes
Patent #: 4385121
Issued on: 05/24/1983
Inventor: Knowlton

Method and apparatus for treating hydrocarbon and halogenated hydrocarbon contaminated ground and ground water
Patent #: 4401569
Issued on: 08/30/1983
Inventor: Jhaveri ,   et al.

Methods for decontaminating soil
Patent #: 4447541
Issued on: 05/08/1984
Inventor: Peterson

Pseudomonas compositions
Patent #: 4452894
Issued on: 06/05/1984
Inventor: Olsen ,   et al.

Microbiological oxidations
Patent #: 4455373
Issued on: 06/19/1984
Inventor: Higgins

More ...

Inventors

Assignee

Application

No. 287107 filed on 12/19/1988

US Classes:

210/603, Including collecting or storing gas (e.g., fuel, carbon monoxide, etc.)210/610, Including adding ancillary growth medium for microorganism210/617, In bed form210/747, Including geographic feature (e.g., drainage ditch, septic, pond)210/908, Organic210/928, PAPER MILL WASTE (E.G., WHITE WATER, BLACK LIQUOR, ETC.) TREATED435/250, Having five or less carbon atoms435/267Treating animal or plant material or micro-organism

Examiners

Primary: Wyse, Thomas G.

Attorney, Agent or Firm

Foreign Patent References

  • 1148488 CA. 06/13/1983
  • 3208977A1 DE. 09/13/1983
  • 239197A1 DE. 09/13/1986
  • 3715952 DE. 11/13/1988

International Class

C02F 003/34

Abstract

A method and apparatus are disclosed for dehalogenating and further biodegrading organic compounds, including halogenated organic compounds, present in an aqueous mixture, the mixture comprising the waste effluent produced in a continuous high flow rate by an industrial plant such as a bleach pulp or paper mill using chlorine and chlorine compounds. The aqueous mixture is passed through at least one combination of a first oxygen-enriched liquid zone and a second zone containing a mixed population of methylotrophic and heterotrophic microorganisms supported on a substrate bed. A first gas including oxygen is flowed through the first zone and second gas consisting substantially of a low-molecular-weight alkane is flowed through the second zone as the aqueous mixture passes through the first and second zones. The microorganisms supported by the bed dehalogenated and further biodegrade the organic compounds in the aqueous liquid flowing through the bed as they aerobically metabolize the low-molecular-weight alkane. The first zone may be hydraulically coupled to an upstream aerobic biopond for decreasing the total organic carbon and biochemical oxygen demand of the aqueous mixture before the mixture is passed through the first and second zones. A plurality of paired first and second zones may be hydraulically interconnected to achieve a higher degree of dehalogenation and further biodegradation of organic compounds in the aqueous mixture flowing therethrough and/or to accommodate higher flow rates.

Other References

  • Bailey and Ollis, Biochemical Engineering Fundamentals (2nd. ed.), McGraw-Hill, N.Y. (1986), pp. 595-600, 626-630
  • Tsien, H-C et al., "Biodegradation of Trichloroethylene by Methylosinus trichosporium OB3b," Appl. Environ. Microbiol. 55:3155-3161 (1989)
  • Oldenhuis, R. et al., "Degradation of Chlorinated Aliphatic Hydrocarbons by Methylosinus trichosporium OB3b Expressing Soluble Methane Monooxygenase," Appl. Environ. Microbiol. 55:2819-2826 (1989)
  • Strandberg, G. W. et al., "Degradation of Trichloroethylene and trans-1,2-Dichloroethylene by a Methanotrophic Consortium in a Fixed-Film, Packed-Bed Bioreactor," Environ. Sci. Technol. 23:1422-1425 (1989)
  • Uchiyama, H. et al., "Aerobic Degradation of Trichloroethylene at High Concentration by a Methane-Utilizing Mixed Culture," Agric. Biol. Chem. 53:1019-1024 (1989a)
  • Henson, H. et al., "Metabolism of Chlorinated Methanes, Ethanes, and Ethylenes by a Mixed Bacterial Culture Growing on Methane," J. Ind. Microbiol. 4:29-35 (1989)
  • Uchiyama, H. et al., "Aerobic Degradation of Trichloroethylene by a New Type II Methane-Utilizing Bacterium, Strain M," Agric. Biol. Chem. 53:2903-2907 (1989b)
  • Hanson, R. S. et al., "Development of Methanotrophs for the Biodegradation of Trichloroethylene and Other Chlorinated Olefins," Abstr. Pap. Am. Chem. Soc., 1989 Meeting (1989)
  • Mayer, K. P. et al., "Degradation of Trichloroethylene by Methanotrophic Bacteria in a Laboratory Column of Saturated Aquifer Material," Water Sci. Tech. 20:175-178 (1988)
  • Thomas, J. M. and Ward, C. H., "In situ Biorestoration of Organic Contaminants in the Subsurface," Environ. Sci. Technol. 23:760-766 (1989)
  • Dooley-Danna, M. et al., "The Sequential Anaerobic/Aerobic Biodegradation of Chlorinated Ethenes in an Aquifier Simulator," Abstr. Annu. Meet. Am. Soc. Microbiol., 1989 Meeting (1989)
  • Eng, W. and Palumbo, A. V., "Trichloroethylene and Trans-1,2-Dichloroethylene Degradation by Pure Methanotrophic Cultures and Mixed Methane-Utilizing Consortia," Abstr. Annu. Meet. Am. Soc. Microbiol., 1989 Meeting (1989)
  • Henry, S. M. et al., "Effects of Mineral Medium on Trichloroethylene Oxidation and Involvement of a Particulate Methane Monooxygenase," Abstr. Annu. Meet. Am. Soc. Microbiol., 1989 Meeting (1989)
  • Moore, A. T. et al., "Biodegradation of Trans-1,2-Dichloroethylene by Methane-Utilizing Bacteria in an Aquifer Simulator," Environ. Sci. Technol. 23:403-406 (1989)
  • Janssen, D. B. et al., "Degradation of Trans-1,2-Dichloroethene by Mixed and Pure Cultures of Methanotrophic Bacteria," Appl. Microbiol. Biotechnol. 29:392-399 (1988)
  • Nelson, M. J. K. et al., "Preliminary Development of a Bench-Scale Treatment System for Aerobic Degradation of Trichloroethylene," Basic Life Sci. 45:203-209 (1988)
  • Meyer, P. and Bartha, R., "Effects of Analog Substrates, Methanogens and Methanotrophs on the Persistence of 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (TCDD)," Abstr. Annu. Meet. Am. Soc. Microbiol., 1988 Meeting (1988)
  • Roberts, P. V. et al., In-Situ Aquifer Restoration of Chlorinated Aliphatics by Methanotrophic Bacteria, Report No. EPA/600/2-89/033 (1989)
  • Donaldson, T. L. et al., Biotreatment of TCE (Trichloroethylene) Contaminated Groundwater, Report No. CONF-890430-3 (1989)
  • Semprini, L. et al., "In Situ Biodegradation for Aquifer Restoration," Environ. Waste Mgt. Mag.. (Apr. 1990); pp. 22-23
  • Leisinger, T., "Microbial Degradation of Chlorinated Alkanes and Alkenes," Eur. Conf. Biotechnol. (1988); pp. 150-154
  • Strandberg, G. W. et al., Degradation of Trichloroethylene and Trans-1,2-Dichloroethylene by a Methanotrophic Consortia in a Trickle-Type Bioreactor, Report No. CONF.-881054-23 (1988)
  • Barrio-Lage et al., "Sequential Dehalogenation of Chlorinated Ethenes," Environ. Sci. Technol. 20:96-99 (1986)
  • Barrio-Lage et al., "Kinetics of the Depletion of Trichloroethene," Environ. Sci. Technol. 21:366-370 (1987)
  • Kloepfer et al., "Anaerobic Degradation of Trichloroethylene in Soil," Environ. Sci. Technol. 19:277-280 (1985)
  • Khare and Dondero, "Fractionation and Concentration from Water of Volatiles and Organics on High Vacuum System: Examination of Sanitary Landfill Leachate," Environ. Sci. Technol. 11:814-819 (1977)
  • Parsons et al., "Transformations of Tetrachloroethene and Trichloroethene in Microcosms and Groundwater," Jour. A.W.A.A., Feb., 1984:56-59
  • Parsons and Lage, "Chlorinated Organics in Simulated Groundwater Environments," Jour. A.W.W.A., May, 1985:52-59
  • Petura, "Trichloroethylene and Methyl Chloroform in Groundwater: A Problem Assessment," Jour. A.W.W.A., Apr., 1981:200-205
  • Tabak et al., "Biodegradability Studies With Organic Priority Pollutant Compounds," Jour. W.P.C.F. 53:1503-1518 (1981)
  • Wilson et al., "Biotransformations of Selected Alkylbenzenes and Halogenated Aliphatic Hydrocarbons in Methanogenic Aquifer Material: A Microcosm Study," Environ. Sci. Technol. 20:997-1002 (1986)
  • Trussell et al., "Precise Analysis of Trihalomethanes," Jour. A.W.W.A., Jul., 1979:385-396
  • Brunner et al., "Bacterial Degradation of Dichloromethane," Appl. Environ. Microbiol. 40:950-958 (1980)
  • Brown et al., "Pentachlorophenol Degradation: A Pure Bacterial Culture and an Epilithic Microbial Consortium," Appl. Environ. Microbiol. 52:92-97 (1986)
  • Boyd et al., "Anaerobic Biodegradation of Phenolic Compounds in Digested Sludge," Appl. Environ. Microbiol. 46:50-54 (1983)
  • Deeley et al., "Biodegradation of [14C]Phenol in Secondary Sewage and Landfill Leachate Measured by Double-Vial Radiorespirometry," Appl. Environ. Microbiol. 49:867-869 (1985)
  • Petrasek et al., "Fate of Toxic Organic Compounds in Wastewater Treatment Plants," Jour. W.P.C.F. 55:1286-1296 (1983)
  • Young and Rivera, "Methanogenic Degradation of Four Phenolic Compounds," Water Res. 19:1325-1332 (1985)
  • Grbic-Galic and Vogel, "Transformation of Toluene and Benzene by Mixed Methanogenic Cultures," Appl. Environ. Microbiol. 53:254-260 (1987)
  • Healy and Young, "Anaerobic Biodegradation of Eleven Aromatic Compounds to Methane," Appl. Environ. Microbiol. 38:84-89 (1979)
  • Boethling and Alexander, "Effect of Concentration of Organic Chemicals on Their Biodegradation by Natural Microbial Communities", Appl. Environ. Microbiol. 37:1211-1216 (1979)
  • Suflita et al., "Kinetics of Microbial Dehalogenation of Haloaromatic Substrates in Methanogenic Environments", Appl. Environ. Microbiol. 45:1466-1473 (1983)
  • Brown, "Household Hazardous Waste: The Unresolved Water Quality Dilemma," Jour. W.P.C.F. 59:120-124 (1987)
  • DeWalle and Chian, "Detection of Trace Organics in Well Water Near a Solid Waste Landfill," Jour. A.W.W.A., Apr., 1981: 206-211
  • Vogel and Grbic-Galic, "Incorporation of Oxygen From Water Into Toluene and Benzene During Anaerobic Fermentative Transformation," Appl. Environ. Microbiol. 52:200-202 (1986)
  • Geraghty and Miller, "Status of Groundwater Contamination in the U.S.," Jour. A.W.W.A., Mar., 1978:162-167
  • Harmsen, "Identification of Organic Compounds in Leachate From A Waste Tip," Water Res. 17:699-705 (1983)
  • Keith and Telliard, "Priority Pollutants I-A Perspective View," Environ. Sci. Technol. 13:416-423 (1979)
  • Kim and Maier, "Acclimation and Biodegradation of Chlorinated Organic Compounds in the Presence of Alternate Substrates," Jour. W.P.C.F. 58:157-164 (1986)
  • Kobayashi and Rittman, "Microbial Removal of Hazardous Organic Compounds," Environ. Sci. Technol. 16:170A-183A (1982)
  • Morgan, "Floating Chains and Fine Bubbles Improve Lagoon Aeration Methods," Pulp & Paper, Apr., 1987:87-88
  • Tittlebaum, "Organic Carbon Content Stabilization Through Landfill Leachate Recirculation," Jour. W.P.C.F. 54:428-433 (1982)
  • Bouwer and McCarty, "Transformations of 1- and 2-Carbon Halogenated Aliphatic Organic Compounds Under Methanogenic Conditions," Appl. Environ. Microbiol. 45:1286-1294 (1983)
  • Alexander, "Biodegradation of Organic Chemicals," Environ. Sci. Technol. 18:106-111 (1985)
  • Patterson and Kodukala, "Biodegradation of Hazardous Organic Pollutants," CEP, Apr., 1981, pp. 48-55
  • McDougall et al., "Contaminant and Treatment of the Love Canal Landfill Leachate," Jour. W.P.C.F. 52: 2914-2924 (1980)
  • Schmidt et al., "Degradation of Chlorophenols by a Defined Mixed Microbial Community," App. Environ. Microbiol. 46:1038-1044 (1983)
  • Marinucci and Bartha, "Biodegradation of 1,2,3- and 1,2,4-Trichlorobenzene in Soil and in Liquid Enrichment Culture," App. Environ. Microbiol. 38:811-817 (1979)
  • Healy and Young, "Catechol and Phenol Degradation by a Methanogenic Population of Bacteria," App. Environ. Microbiol. 35:216-218 (1978)
  • Klecka and Maier, "Kinetics of Microbial Growth on Pentachlorophenol," App. Environ. Microbiol. 49:46-53 (1985)
  • Gibson and Suflita, "Extrapolation of Biodegradation Results to Groundwater Aquifers: Reductive Dehalogenation of Aromatic Compounds," App. Environ. Microbiol. 52:681-688 (1986)
  • Zeyer et al., "Rapid Microbial Mineralization of Toluene and 1,3-Dimethylbenzene in the Absence of Molecular Oxygen," App. Environ. Microbiol. 52:944-947 (1986)
  • Mikesell and Boyd, "Complete Reductive Dechlorination and Mineralization of Pentachlorophenol by Anaerobic Microorganisms," App. Environ. Microbiol. 52:861-865 (1986)
  • Dalton, H., and Stirling, D. I., "Co-Metabolism," Phil. Trans, R. Soc. Lond. B 297:481-496 (1982)
  • Wilson, J. T., and Wilson, B. H., "Biotransformation of Trichloroethylene in Soil," Applied and Environ. Microbiol. 49:242-243 (Jan. 1985)
  • Fogel, M. M., Taddeo; A. R., and Fogel, S., "Biodegradation of Chlorinated Ethenes by a Methane-Utilizing Mixed Culture," Applied and Environ. Microbiol. 51:720-724 (Apr. 1986)
  • Higgins, I. J., Best, D. J., and Hammond, R. C.; "New Findings in Methan-Utilizing Bacteria Highlight Their Importance in the Biosphere and Their Commercial Potential," Nature 286:561-564 (Aug. 1980)
  • Strand, S. E. and Shippert, L.; "Oxidation of Chloroform in an Aerobic Soil Exposed to Natural Gas," Applied and Environ. Microbiol. 52:203-205 (Jul. 1986)
  • Haber, C. L. et al., "Methylotrophic Bacteria: Biochemical Diversity and Genetics," Science 221:1147-1153 (Sep. 1983)
  • Best, D. J. and Higgins, I. J.; "Methane-Oxidizing Activity and Membrane Morphology in a Methanol-Grown Obligate Methanothroph, Methylosinus trichosporium OB3b," J. Gen. Microbiol. 125:73-84 (1981)
  • Scott, D., Brannan, J. and Higgins, I. J.; "The Effect of Growth Conditions on Intracytoplasmic Membranes and Methane Mono-oxygenase Activities in Methylosinus trichosporium OB3b," J. Gen. Microbiol. 125:63-72 (1981)
  • Dostalek, M. and Molin, N., "Studies of Biomass Production of Methanol Oxidizing Bacteria," in Single-Cell Protein II (Tannenbaum, S. R. and Wang, D.C., eds.); MIT Press, pp. 385-401
  • Coty, V. F., "A Critical Review of the Utilization of Methane," Biotech and Bioeng. Symposium No. 1 (Second International Conference on Global Impacts of Applied Microbiology, Addis Ababa, Ethiopia, 1967), Interscience, 1969, pp. 105-117
  • Little, C. D. et al., "Trichloroethylene Biodegradation by a Methane-Oxidizing Bacterium," Applied and Environ. Microbiol. 54:951-956 (Apr. 1988)
  • Hanson, R. S., "Encology and Diversity of Methylotrophic Organisms," Advances in Applied Microbiology, vol. 26:3-39 (1980) Academic Press
  • Colby, J., Dalton, H. and Whittenbury, R., "Biological and Biochemical Aspects of Microbial Growth on C1 Compounds," Ann. Rev. Microbiol. 33:481-517 (1979)
  • Higgins, I. J., et al., "Methane-Oxidizing Microorganisms," Microbiol. Reviews, 45:556-590, (Dec. 1981)
  • Nichols, P. D., et al., "Detection of a Microbial Consortium, Including Type II Methanotrophs, by Use of Phospholipid Fatty Acids in an Aerobic Halogenated Hydrocarbon-Degrading Soil Column Enriched with Natural Gas," Environ. Toxicol. and Chem., 6:89-97, (1987)
  • Whittenbury, R. and Dalton, H., "The Methylotrophic Bacteria," in The Prokaryotes, vol. I, Ch. 71, pp. 894-902, (1981)
  • Leadbetter, E. R. and Foster, J. W., "Studies on Some Methane-Utilizing Bacteria," Archiv fur Mikrobiologie Bd., 30:91-118, (1958)
  • Higgins, I. J. and Quayle, J. R., "Oxygenation of Methane by Methane-Grown Pseudomonas methanica and Methanomonas methanooxidans," Biochem. J., 118:201-208, (1970)
  • Hou, C. T., et al., "Microbial Oxidation of Gaseous Hydrocarbons: Epoxidation of C2 to C4 n-Alkenes by Methylotrophic Bacteria," Applied and Environ. Microbiol., 38:127-134, (Jul. 1979)
  • Vogel, T. M. and McCarty, P. L., "Biotransformation of Tetrachloroethylene to Trichloroethylene, Dichloroethylene, Vinyl Chloride, and Carbon Dioxide under Methanogenic Conditions," Applied and Environ. Microbiol., 49:1080-1083, (May 1985)
  • Bouwer, E. J. and McCarty, P. L., "Utilization Rates of Trace Halogenated Organic Compounds in Acetate-Grown Biofilms," Biotech. and Bioeng., 27:1564-1571, (1985)
  • Steiert, J. G., Pignatello, J. J. and Crawford, R. L., "Degradation of Chlorinated Phenols by a Pentachlorophenol-Degrading Bacterium," Applied and Environ. Microbiol., 53:907-910, (May 1987)
  • Steiert, J. G. and Crawford, R. L., "Catabolism of Pentachlorophenol by a Flavobacterium Sp.," Biochem. Biophys. Res. Comm., 141:825-830, (Dec. 1986)
  • Saber, D. L. and Crawford, R. L., "Isolation and Characterization of Flavobacterium Strains that Degrade Pentachlorophenol," Applied and Environ. Microbiol., 50:1512-1518, (Dec. 1985)
  • Crawford, R. L. and Mohn, W. W., "Microbiological Removal of Pentachlorophenol from Soil Using a Flavobacterium," Enzyme Microb. Technol., 7:617-620, (Dec. 1985)
  • Apajalahti, J. H. A. and Salkinoja-Salonen, M. S., "Dechlorination and para-Hydroxylation of Polychlorinated Phenols by Rhodococcus chlorophenolicus," J. Bacteriol., 169:675-681, (Feb. 1987)
  • Apajalahti, J. H. A. and Salkinoja-Salonen, M. S., "Degradation of Polychlorinated Phenols by Rhodococcus chlorophenolicus," Applied Microbiol. Biotechnol., 25:62-67, (1986)
  • Janssen, D. B., et al., "Degradation of Halogenated Aliphatic Compounds by Xanthobacter autotrophicus GJ10," Applied and Environ. Microbiol., 49:673-677, (Mar. 1985)
  • Nelson, M. J. K., et al., "Aerobic Metabolism of Trichloroethylene by a Bacterial Isolate," Applied and Environ. Microbiol., 52:383-384, (Aug. 1986)
  • Nelson, M. J. K., et al., "Biodegradation of Trichloroethylene and Involvement of an Aromatic Biodegradative Pathway," Applied and Environ. Microbiol., 53:949-954, (May 1987)
  • DeBont, J. A. M., et al., "Microbial Degradation of 1,3-Dichlorobenzene," Applied and Environ. Microbiol., 52:677-680, (Oct. 1986)
  • Schraa, G., et al., "Degradation of 1,4-Dichlorobenzene by Alcaligenes sp. Strain A175," Applied and Environ. Microbiol., 52:1374-1381, (Dec. 1986)
  • Kilbane, J. J., et al., "Biodegradation of 2,4,5-Trichlorophenoxyacetic Acid by a Pure Culture of Pseudomonas cepacia," Applied and Environ. Microbiol., 44:72-78, (Jul. 1982)
  • Karns, J. S., et al., "Metabolism of Halophenols by 2,4,5-Trichlorophenoxyacetic Acid-Degrading Pseudomonas cepacia," Applied and Environ. Microbiol., 46:1176-1181, (Nov. 1983)
  • Reineke, W. and Knackmuss, H.-J., "Microbial Metabolism of Haloaromatics: Isolation and Properties of a Chlorobenzene-Degrading Bacterium," Applied and Environ. Microbiol., 47:395-402, (Feb. 1984)
  • Pain, S., "Microbes `Could Break Down Dioxin`," New Scientist, p. 36, (Feb. 25, 1988)
  • Chu, J. P. and Kirsch, E. J., "Metabolism of Pentachlorophenol by an Axenic Bacterial Culture," Applied Microbiol., 23:1033-1035, (May 1972)
  • Hou, C. T., et al., "Epoxidation of Short-Chain Alkenes by Resting-Cell Suspensions of Propane-Grown Bacteria," Applied and Environ. Microbiol., 46:171-177, (Jul. 1983)
  • Colby, J., Dalton, H. and Whittenbury, R., "An Improved Assay for Bacterial Methane Mono-Oxygenase: Some Properties of the Enzyme from Methylomonas methanica," Biochem. J., 151:459-462, (1975)
  • Colby, J. and Dalton, H., "Some Properties of a Soluble Methane Mono-Oxygenase from Methylococcus capsulatus Strain Bath," Biochem. J., 157:495-497, (1976)
  • Tonge, G. M., Harrison, D. E. F. and Higgins, I. J., "Purification and Properties of the Methane Mono-Oxygenase Enzyme System from Methylosinus trichosporium OB3b," Biochem. J., 161:333-344, (1977)
  • Patel, R. N. and Savas, J. C., "Purification and Properties of the Hydroxylase Component of Methane Monooxygenase," J. Bacteriol., 169:2313-2317, (May 1987)
  • Ghosal, D., et al., "Microbial Degradation of Halogenated Compounds," Science, 228:135-142, (Apr. 1985)
  • Abelson, P. H., "Treatment of Hazardous Wastes," Science, 233:509, (Aug. 1986)
  • Abelson, P. H., Extract from a proposed manuscript, (Jan. 1987)
  • Barrio-Lage, G. A., Parsons, F. Z. and Lorenzo, P. A., "Inhibition and Stimulation of Trichloroethylene Biodegradation in Microaerophilic Microcosms," Environ. Toxicol. and Chem., 7:889-895, (1988)
  • Rintala, J. and Vuoriranta, P., "Anaerobic-Aerobic Treatment of Thermomechanical Pulping Effuents," Tappi Journal, (Sep. 1988)
  • Wilson, J. T., et al., "Transport and Fate of Selected Organic Pollutants in a Sandy Soil," J. Environ. Qual., 10:501-506, (1981)
  • Woodward, R. E., "Destroying Toxic Waste by Bioremediation: The Process Works", (unknown origin and date)
  • Dean-Ross, D., "Biodegradation of Toxic Wastes in Soil," ASM News, 53:490-492, (1987
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