U.S. patents available from 1976 to present.
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Phenol preparation process and propylene recovery therefrom

Patent 5017729 Issued on May 21, 1991. Estimated Expiration Date: Icon_subject September 5, 2009. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Alcohol dehydration employing a zinc aluminate catalyst
Patent #: 4260845
Issued on: 04/07/1981
Inventor: Shioyama

Process for the production of phenol and acetone
Patent #: 4310712
Issued on: 01/12/1982
Inventor: Langley

Process for preparing a methyl phenol
Patent #: 4431849
Issued on: 02/14/1984
Inventor: Colvin

Method for production of phenol/acetone from cumene hydroperoxide
Patent #: 4876397
Issued on: 10/24/1989
Inventor: Knifton, et al.

Method of oxidizing secondary alkyl substituted naphtalenes and a process of producing isopropylnaphthols Patent #: 4906790
Issued on: 03/06/1990
Inventor: Ishiguro, et al.

Inventors

Assignee

Application

No. 402528 filed on 09/05/1989

US Classes:

568/798, Preparing by cleavage of hydroperoxide or other peroxide568/385, Peroxy containing reactant568/565, Preparing by oxidation utilizing gaseous oxygen568/569, Preparing by oxidation utilizing gaseous oxygen568/577, Preparing by oxidation utilizing gaseous oxygen568/741, Preparing from peroxide or preparing by oxidation568/768, Preparing by cleavage of hydroperoxide or other peroxide568/799, Preparing by reduction or dehydrogenation (e.g., by hydrogenation, etc.)568/840, Acyclic585/422, By condensation of entire cyclic molecules or entire hydrocarbyl moieties thereof, e.g., polymerization, etc.585/446By condensation of entire molecules or entire hydrocarbyl moieties thereof, e.g., alkylation, etc.

Examiners

Primary: Lone, Werren B.

Attorney, Agent or Firm

Foreign Patent References

  • 25653 JP 03/21/1970
  • 62-12729 JP 06/21/1987
  • 62-77338 JP 09/21/1987
  • 8702910 WO. 05/21/1987
  • 1207133 GB 09/21/1970

International Classes

C07C 037/08
C07C 045/53

Foreign Application Priority Data

1988-09-30 JP

Abstract

Phenol is produced in a recycle manner by (a) reacting benzene with propylene to synthesize cumene, (b) oxidizing the cumene of step (a) into cumene hydroperoxide, (c) acid cleaving cumene hydroperoxide into phenol and acetone, (d) hydrogenating the acetone of step (c) into isopropanol, (e) dehydrating the isopropanol of step (d) into propylene, and (f) recycling the propylene of step (e) to step (a). It is also possible to take propylene from step (e). The acetone by-product produced upon preparation of phenol is converted into propylene which is useful by itself for any other uses or recycled to the phenol producing process.

Other References

  • Gasior et al., Chemical Abstracts 38862z, vol. 101, No. 6 of Aug. 6, 198
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