U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Pressure-sensitive adhesive comprising hollow tacky microspheres and macromonomer-containing binder copolymer

Patent 4994322 Issued on February 19, 1991. Estimated Expiration Date: Icon_subject September 18, 2009. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3400095

3578622

3691140

3786116

3842059

3857731

Pressure sensitive hot-melt adhesive system
Patent #: 4049483
Issued on: 09/20/1977
Inventor: Loder ,   et al.

Tacky polymeric microspheres
Patent #: 4166152
Issued on: 08/28/1979
Inventor: Baker ,   et al.

Low tack microsphere glue
Patent #: 4495318
Issued on: 01/22/1985
Inventor: Howard

Acrylate copolymer pressure-sensitive adhesive composition and sheet materials coated therewith
Patent #: 4554324
Issued on: 11/19/1985
Inventor: Husman ,   et al.

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Inventors

Assignee

Application

No. 407092 filed on 09/18/1989

US Classes:

428/343, Adhesive outermost layer428/355AC, Including addition polymer from alpha-beta unsaturated carboxylic acid (e.g., acrylic acid, methacrylic acid, etc.) or derivative thereof428/355CN, Including nitrogen containing polymer (e.g., polyacrylonitrile, polymethacrylonitrile, etc.)428/402, Particulate matter (e.g., sphere, flake, etc.)521/54, Treating a cellular solid polymer by adding a solid polymer or solid polymer-forming composition521/56, Particle which is expandible, process of preparing an expandible particle, or process of expanding a particle to form a cellular product521/60, Adding expanding agent subsequent to solid polymer formation521/63, Cellular product-forming process wherein the removable material is present or is produced in situ during the solid polymer formation step521/64, Removing a liquid to form a cellular product521/134, Cellular product derived from two or more solid polymers or from at least one solid polymer and at least one polymer-forming system523/223, Process of forming a composition of a spheroidal material having physical dimension or composition containing same524/801, Process of preparing water-in-oil emulsion or dispersion, or product thereof525/205, Heterocyclic reactant is an imide or lactam525/218, Nitrogen reactant contains a carboxylic acid amide group525/221, Solid polymer derived from reactant containing a carboxylic acid group525/228At least two polymers derived from carboxylic acid ester reactants

Examiners

Primary: Foelak, Morton

Attorney, Agent or Firm

Foreign Patent References

  • 0209337 EP. 07/13/1985
  • 3544992A1 DE. 12/13/1985

International Classes

C08J 009/236
C08J 009/32

Abstract

A repositionable pressure-sensitive adhesive comprising from about 70% to about 99% hollow, polymeric, acrylate, inherently tacky, infusible, solvent-insoluble, solvent-dispersible, elastomeric microspheres comprising at least one alkyl acrylate or alkyl methacrylate ester, a majority of the microspheres having one or more interior voids having a diameter of at least about 10% of the diameter of the microsphere, and correspondingly, from about 30% to about 1% of a binder copolymer comprising an elastomeric polymeric backbone having pendant therefrom high Tg polymeric moieties.

Other References

  • Surfactant Systems: Their Chemistry, Pharmacy, & Biology, (D. Attwood and A. T. Florence, Chapman & Hall Ltd., New York, N.Y., 1983)
  • S. L. Rosen, Fundamental Principles of Polymer Materials, p. 259, Wiley-Interscience, 1982
  • D. Satas, Handbook of PSA Technology, 2nd Ed., p. 909, Van-Norstrand-Rheinhold, N.Y., 198
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