U.S. patents available from 1976 to present.
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Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons

Patent 4973453 Issued on November 27, 1990. Estimated Expiration Date: Icon_subject February 27, 2009. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2552737

2683121

2697655

Installation for chemical conversion of a gas mixture containing hydrogen and hydrocarbons Patent #: 4746495
Issued on: 05/24/1988
Inventor: Mingaud ,   et al.

Inventor

Assignee

Application

No. 316015 filed on 02/27/1989

US Classes:

422/190, Plural solid, extended surface, fluid contact reaction stages each containing; e.g., inert Raschig rings, particulate sorbent, particulate or monolithic catalyst, etc.48/127.9, APPARATUS FOR CONVERTING OR TREATING HYDROCARBON GAS48/198.7, Employing catalytic particles252/373, Carbon-oxide and hydrogen containing252/374, Nitrogen and hydrogen containing422/187, Combined422/198, Including heat exchanger for reaction chamber or reactants located therein518/703, Gaseous oxygen utilized in the preliminary reaction518/704Water utilized in the preliminary reaction

Examiners

Primary: Warden, Robert J.
Assistant: Johnston, Jill

Attorney, Agent or Firm

International Classes

B01J 008/04
B01J 012/00
C01B 003/26

Abstract

An apparatus for the production of heavier hydrocarbons from one or more gaseous light hydrocarbons is provided. The process of using the apparatus comprises reacting the gaseous light hydrocarbons by autothermal reforming with air in the presence of recycled carbon dioxide and steam to produce a synthesis gas stream containing hydrogen and carbon monoxide. The synthesis gas stream is reacted in the presence of a hydrocarbon synthesis catalyst containing cobalt to form heavier hydrocarbons and water from the hydrogen and carbon monoxide. The heavier hydrocarbons and water are separated, and the resulting residue gas stream is subjected to catalytic combustion with additional air to form a product stream comprising carbon dioxide and nitrogen. The carbon dioxide is separated from the nitrogen to produce a nitrogen product stream, and at least a portion of the separated carbon dioxide is recycled to the autothermal reforming step.

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