U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Removal of bitterness from citrus juices using a post-crosslinked adsorbent resin

Patent 4965083 Issued on October 23, 1990. Estimated Expiration Date: Icon_subject March 20, 2009. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Polymeric adsorbents from vinylbenzyl chloride copolymer beads
Patent #: 4191813
Issued on: 03/04/1980
Inventor: Reed ,   et al.

Uniform polymer beads and ion exchange resins therefrom prepared by post-crosslinking of lightly crosslinked beads
Patent #: 4192920
Issued on: 03/11/1980
Inventor: Amick

Polymeric adsorbents from macroreticular polymer beads
Patent #: 4263407
Issued on: 04/21/1981
Inventor: Reed, Jr.

Preparation of citrus juices, concentrates and dried powders which are reduced in bitterness
Patent #: 4439458
Issued on: 03/27/1984
Inventor: Puri

Removal of bitter naringin and limonin from citrus juices containing the same
Patent #: 4514427
Issued on: 04/30/1985
Inventor: Mitchell ,   et al.

Upflow ion exchange treatment of natural edible juices containing high acidity and suspended solids
Patent #: 4522836
Issued on: 06/11/1985
Inventor: Dechow ,   et al.

Porous polymers Patent #: 4668709
Issued on: 05/26/1987
Inventor: Jones ,   et al.

Inventors

Application

No. 326186 filed on 03/20/1989

US Classes:

426/422, Treatment of liquid with nongaseous material other than water per se426/271, INVOLVING ION EXCHANGE, SEQUESTERING OR CHELATING MATERIAL426/330.5, Fruit and vegetable juice426/333, Citrus fruit426/590, Beverage or beverage concentrate521/31, Solid polymer derived from ethylenically unsaturated reactant only521/33Treated with sulfur-containing material

Examiners

Primary: Czaja, Donald E.
Assistant: Workman, D.

Foreign Patent References

  • 58-56663 JP 04/12/1983

International Classes

A23L 002/30
A23L 002/36

Abstract

Bitter components, such as limonin, may be effectively removed from citrus juices, particularly navel orange juices, by contacting the juices with an adsorbent resin. The adsorbent resin is derived from a copolymer of a monoethylenically unsaturated monomer and a crosslinking monomer, where the copolymer has been post-crosslinked in the swollen state in the presence of a Friedel-Crafts catalyst and functionalized with hydrophilic groups. Preferably, the copolymers are styrene and divinylbenzene.

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