U.S. patents available from 1976 to present.
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IGCC process with combined methanol synthesis/water gas shift for methanol and electrical power production

Patent 4946477 Issued on August 7, 1990. Estimated Expiration Date: Icon_subject April 7, 2008. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2665289

Process for the synthesis of aliphatic alcohol-containing mixtures Patent #: 4477594
Issued on: 10/16/1984
Inventor: Greene ,   et al.

Inventors

Assignee

Application

No. 178955 filed on 04/07/1988

US Classes:

48/197R, PROCESSES518/700, LIQUID PHASE FISCHER-TROPSCH REACTION518/708, Water utilized518/711WATER UTILIZED DURING THE FISCHER-TROPSCH STEP OF THE PROCESS

Examiners

Primary: Woodard, Joye L.

Attorney, Agent or Firm

Foreign Patent References

  • 59-207827 JP 11/13/1984

International Class

C07C 031/04

Abstract

The present invention relates to an improvement to a process for the production of methanol from synthesis gas containing carbon monoxide and hydrogen utilizing a three phase or liquid-phase reaction technology. The improvement to the process is the addition of relatively small amounts of water to the liquid-phase reactor thereby allowing for the use of a CO-rich synthesis gas for the production of methanol by effectuating in the same reactor the methanol synthesis and water-gas shift reactions. A portion of the unreacted synthesis gas stream from the liquid-phase reactor is separated into a hydrogen-rich component and a carbon monoxide-rich component. The hydrogen-rich component is combined with a portion of the unreacted synthesis gas stream from the liquid-phase reactor to form a gas-phase methanol reactor feed stream for producing methanol, and the carbon monoxide-rich component is combined with the unreacted effluent from the gas-phase methanol reactor to form a feed stream for combustion in a gas turbine.

Other References

  • Sherwin et al., "Liquid-Phase Methanol", EPRI Report AF-1291, pp. 5/3-5/7, Dec. 1979
  • Vedage et al., "Water Promotion and Identification of Intermediates in Methanol Synthesis", Proceedings, 8th International Congress on Catalysis, vol. II, pp. 47-58, 198
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