U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Nitration reactions with acid anhydride promoters

Patent 4921970 Issued on May 1, 1990. Estimated Expiration Date: Icon_subject May 1, 2007. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3397229

3415876

3868389

3887588

Process for making N-methyl nitrophthalimides
Patent #: 3933852
Issued on: 01/20/1976
Inventor: Cook ,   et al.

Process for making dinitrotoluene
Patent #: 3981933
Issued on: 09/21/1976
Inventor: Cook ,   et al.

Process for the production of nitro derivatives of aromatic compounds
Patent #: 4036838
Issued on: 07/19/1977
Inventor: Vogel ,   et al.

Process for the production of aromatic mononitro compounds
Patent #: 4064147
Issued on: 12/20/1977
Inventor: Thelen ,   et al.

Process for the preparation of mononitro-aromatic compounds Patent #: 4112005
Issued on: 09/05/1978
Inventor: Thiem ,   et al.

Inventor

Application

No. 012318 filed on 02/09/1987

US Classes:

548/480The ring nitrogen of the five-membered hetero ring is unsubstituted or hydrocarbyl substituted only

Examiners

Primary: Ceperley, Mary E.

Attorney, Agent or Firm

Foreign Patent References

  • 108604 EP. 05/13/1984
  • 1393312 FR. 02/13/1965

International Class

C07D 209/50

Abstract

An improved nitric acid only nitration process wherein the improvement comprises adding an effective amount of a nitration promoting acid anhydride to the reaction mixture to enhance the rate of nitration.

Other References

  • A. Murthy, "Practical Nitration and Amination Technology" Conference Paper Excerpts (Dec. 1985)
  • E. Muller, Meth. der Organischen Chemie, 1971
  • Hughes et al, "Kinetics and Mechanism of Aromatic Nitration, Part II", pp. 2400-2440 (1949)
  • K. Schofield, "Aromatic Nitration", Cambridge Univ. Press, pp. 23-43 (1980)
  • M. Astle, "Industrial Organic Nitrogen Compounds", Reinhold Publishing Corp., pp. 314-344 (1961), pp. 459 (1943)
  • C. Noller, "Chem. of Organic Compounds", Sunders Co., pp. 439-455 (1958)
  • A. Ponomarenko, "Synthesis of Monochlorophthalic Anhydrides from Mononitrophthalic Anhydrides", Zhur. Obsche: Khim (J. Gene. Chem.), pp. 20, 469-471 (1948)
  • T. Kameo et al, Chem. Abstracts 79:104832v (1973)
  • Stamicarbon N. V., Chem. Abstracts 68:95548a (1968)
  • B. Enoksson et al, Chem. Abstracts 96:201967b (1982)
  • Hoggett et al., Nitration and Aromatic Reactivity, Cambridge University Press, pp. 6-7 and 79-82 (1971)
  • Knowles et al., Journal of the Chem. Soc., Dec. 1960, 4885-4896
  • Houlen-Weyl, Methoden der Organischen Chemie, X/I, Part 1, 4th Edition, pp. 483-484 (1971) (English translation
PatentsPlus Images
Enhanced PDF formats
loading...
PatentsPlus: add to cart
PatentsPlus: add to cartSearch-enhanced full patent PDF image
$9.95more info
 
Sign InRegister
Username  
Password   
forgot password?