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Layered metal chalcogenides containing interspathic polymeric chalcogenides

Patent 4859648 Issued on August 22, 1989. Estimated Expiration Date: Icon_subject August 22, 2006. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

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Inventors

Assignee

Application

No. 06/879787 filed on 06/27/1986

US Classes:

502/242, Of Group IV (i.e., Ti, Zr, Hf, Ge, Sn or Pb)502/202, Boron or compound containing same502/350, Of titanium502/84And metal, metal oxide, or metal hydroxide

Examiners

Primary: Dees, Carl F.

Attorney, Agent or Firm

International Classes

C01B 13/14 (20060101)
C01B 17/00 (20060101)
C01B 17/20 (20060101)
C01B 17/42 (20060101)
C01B 19/00 (20060101)
C07C 2/08 (20060101)
C07C 2/00 (20060101)
C01G 23/00 (20060101)
C10G 45/02 (20060101)
C10G 45/04 (20060101)
B01J 29/00 (20060101)
B01J 29/04 (20060101)
C07C 2/10 (20060101)

Abstract

Layered chalcogenide materials of high thermal stability and surface area which contain interspathic polymeric chalcogenides such as polymeric silica are prepared by ion exchanging a layered metal oxide, such as layered titanium oxide, with organic cation, to spread the layers apart. A compound such as tetraethylorthosilicate, capable of forming a polymeric oxide, is thereafter introduced between the layers. The resulting product is treated to form polymeric oxide, e.g. by hydrolysis, to produce the layered oxide material. The resulting product may be employed as catalyst material in the conversion of organic compounds.

Other References

  • Weiss et al., Angew. Chem./72 Jahrg' 1960/Nr/2, pp. 413-415
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