Patent 4836643 Issued on June 6, 1989. Estimated Expiration Date: February 2, 2008. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
A high numerical aperture optical fibre, e.g. for use in remote spectroscopy, has a cladding of a halide glass which contains Hf and a core of a halide glass which contains Pb. Preferably both glasses contain ZrF4, BaF2, LaF3, AlF3 and NaF. In addition the cladding contains HfF4 but no PbF2 and the core contains PbF2 but no HfF4.
Other References
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Journal of Lightwave Technology, vol. LT-2, No. 5, Oct. 1984, pp. 566-586, IEEE, New York, U.S.; D.C. Tran et al.: "Heavy Metal Fluoride Glasses and Fibers: A Review", Table 1
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