Patent References 2552308 2683121 2686195 3549335 3888043 Partial oxidation process Integrated process for the production of methanol and ammonia Process for the preparation of hydrocarbons Process for the preparation of hydrocarbons Process comprising reforming, synthesis, and hydrocracking InventorAssigneeApplicationNo. 07/152878 filed on 02/05/1988US Classes:518/703, Gaseous oxygen utilized in the preliminary reaction252/373, Carbon-oxide and hydrogen containing252/374, Nitrogen and hydrogen containing518/704Water utilized in the preliminary reactionExaminersPrimary: Mars, Howard T.Attorney, Agent or FirmInternational ClassesC07C 1/00 (20060101)C07C 1/04 (20060101) AbstractA process and apparatus for the production of heavier hydrocarbons from one or more gaseous light hydrocarbons is provided. The process comprises reacting the gaseous light hydrocarbons by autothermal reforming with air in the presence of recycled carbon dioxide and steam to produce a synthesis gas stream containing hydrogen and carbon monoxide. The synthesis gas stream is reacted in the presence of a hydrocarbon synthesis catalyst containing cobalt to form heavier hydrocarbons and water from the hydrogen and carbon monoxide. The heavier hydrocarbons and water are separated, and the resulting residue gas stream is subjected to catalytic combustion with additional air to form a product stream comprising carbon dioxide and nitrogen. The carbon dioxide is separated from the nitrogen to produce a nitrogen product stream, and at least a portion of the separated carbon dioxide is recycled to the autothermal reforming step. |
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