U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for preparing arylamines

Patent 4764625 Issued on August 16, 1988. Estimated Expiration Date: Icon_subject August 16, 2005. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2476170

2924620

3065269

3251881

3313854

3314788

Inventors

Assignee

Application

No. 06/639032 filed on 08/09/1984

US Classes:

548/442, One of the benzene rings and an additional carbocyclic ring bonded directly to the same acyclic nitrogen564/309, Benzidines564/405Which also contains benzene ring

Examiners

Primary: Higel, Floyd D.
Assistant: Greason, Carolyn S.

Attorney, Agent or Firm

International Classes

C07D 209/00 (20060101)
C07D 209/88 (20060101)

Abstract

The process of preparing a tertiary amine by the condensation of a mono- or di-tertiary amine and a mono- or di-iodoaryl compound. Conducting the condensation reaction in the presence of potassium hydroxide, and a copper catalyst, either in the absence of a solvent or with an inert saturated hydrocarbon solvent, in an inert atmosphere, at a temperature between from about 120° C. to about 190° C. for a period of time sufficient to at least substantially complete the reaction.

Other References

  • Creason et al, Jour. Org. Chem., vol. 37, No. 26, pp. 4440-4446, 1972
  • F. Ullmann: Ueber eine neue Bildungsweise von Diphenylaminderivaten (Chem. Ber. 36, 2382, 1903)
  • Chemical Abstracts, vol. 70, No. 11, 1969, Columbus, OH, U.S.A., I. E. Moisak et al., "Tertiary Aromatic Amines," p. 289, Abstract 47064j, Izobiet., Prom. Obraztsy, Tovarnye Znaki, vol. 45, No. 29, 1968, p. 25, SU-A-226 629
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