U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for recovering lithium from salt brines

Patent 4723962 Issued on February 9, 1988. Estimated Expiration Date: Icon_subject June 5, 2006. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

876851

1623513

3268289

3306700

3537813

Process for the production of high purity lithium hydroxide
Patent #: 4036713
Issued on: 07/19/1977
Inventor: Brown

Process for solar concentration of lithium chloride brine
Patent #: 4243392
Issued on: 01/06/1981
Inventor: Brown ,   et al.

Production of highly pure lithium chloride from impure brines
Patent #: 4271131
Issued on: 06/02/1981
Inventor: Brown ,   et al.

Process for purification of lithium chloride
Patent #: 4274834
Issued on: 06/23/1981
Inventor: Brown ,   et al.

Process for recovering lithium from brine by salting out lithium sulfate monohydrate Patent #: 4287163
Issued on: 09/01/1981
Inventor: Garrett ,   et al.

Inventor

Assignee

Application

No. 06/873099 filed on 06/05/1986

US Classes:

23/302R, Alkali metal and ammonium compounds23/295R, Crystallization23/295S, Solar23/296, Selective23/298, From natural sources23/300, With added material23/304, Alkaline earth metal and magnesium compounds423/179.5, Lithium423/551Alkali metal containing (Li, Na, K, Rb, or Cs)

Examiners

Primary: Metz, Andrew H.
Assistant: Pak, Chung K.

Attorney, Agent or Firm

International Classes

C01D 15/00 (20060101)
C01D 15/06 (20060101)
C22B 26/00 (20060101)
C22B 26/12 (20060101)

Abstract

An improved process is described for recovering lithium from evaporatively concentrated brines. Epsom salt recovered from the brine at about 0° C. is added to the concentrated lithium-containing brine, so as to precipitate lithium sulfate monohydrate, the brine having previously been subjected to the sequential steps of two stage chilling, evaporative concentration, further chilling and vacuum evaporation.

Other References

  • Garrett and Laborde (1980), Salting Out Process for Lithium Recovery
  • Badilla et al. (1981), Obtaining Sulfate from Brines from the Atcama Salt Deposit-Final Study Report
  • Ramirez, R. S., Process for Recovering Lithium Sulfate, Variation A and Variation B
  • "Process for Precipitation (Salting Out) to Retrieve Lithium", Martin Laborde E., Corporacion de Fomento de la Produccion, Santiago, Chile
  • Ramirez, R. S., "Process for Obtaining Magnesium Sulfate", Variation B, (1979) (English translation)
  • D. Kaplan, Process for the Extraction of Lithium from Dead Sea Solutions, Israel J. Chem., vol. 1, 1963
  • R. L. Nielsen and M. G. Herre: Lithium and its Compounds, Ind. and Engineering Chemistry, vol. 43, No. 12, Dec. 1951
  • Anon., "Silver Peak Gives Bright Look to Foote Mineral's Lithium Picture", E/MJ, Apr. 1970, pp. 71-73
  • Anon., "Utah Company Gets Set Up to Tap Mineral Wealth of Great Salt Lake", E/MJ, Apr. 1970, pp. 67-70
  • J. A. Epstein, E. M. Fesit, and J. Zmora: Extraction of Lithium from Dead Sea, Hydrometallurgy, vol. 6, pp. 269-275, 1981, Elsevier Scientific Publishing Co., Amsterdam
  • W. A. Averill and David L. Olson: A Review of Extractive Processes for Lithium from Ores and Brines, Energy, vol. 3, pp. 305--313, 1975, Pergamon Press Ltd
  • G. G. Gabra and A. E. Torma: Lithium Chloride Extraction by N-Butanol, Hydrometallurgy, pp. 23-33, 1978, Elsevier Publishing Co., Amsterdam
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