U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Solution mining of trona or nahcolite ore with electrodialytically-produced aqueous sodium hydroxide

Patent 4652054 Issued on March 24, 1987. Estimated Expiration Date: Icon_subject April 16, 2005. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3184287

Process for the solution mining of subterranean sodium bicarbonate bearing ore bodies
Patent #: 3953073
Issued on: 04/27/1976
Inventor: Kube

Method for removal of SO2 from gases
Patent #: 4107015
Issued on: 08/15/1978
Inventor: Chlanda ,   et al.

Bipolar membranes and method of making same
Patent #: 4116889
Issued on: 09/26/1978
Inventor: Chlanda ,   et al.

Electrodialytic process
Patent #: 4219396
Issued on: 08/26/1980
Inventor: Gancy ,   et al.

Electrodialytic process for the conversion of impure soda values to sodium hydroxide and carbon dioxide
Patent #: 4238305
Issued on: 12/09/1980
Inventor: Gancy ,   et al.

Preparing alkali metal hydroxide by water splitting and hydrolysis
Patent #: 4391680
Issued on: 07/05/1983
Inventor: Mani ,   et al.

Solution mining of trona or nahcolite ore with aqueous NaOH and HCl solvents
Patent #: 4498706
Issued on: 02/12/1985
Inventor: Ilardi ,   et al.

Process for recovering sodium carbonate from trona and other mixtures of sodium carbonate and sodium bicarbonate Patent #: 4584077
Issued on: 04/22/1986
Inventor: Chlanda ,   et al.

Inventors

Assignee

Application

No. 06/723679 filed on 04/16/1985

US Classes:

299/5, Dissolving or chemical reaction204/534, And using bipolar membrane423/206.2, Alkali carbonate from trona423/421Alkali metal containing (Li, Na, K, Rb, or Cs)

Examiners

Primary: Kaplan, G. L.

Attorney, Agent or Firm

International Classes

C22B 26/10 (20060101)
C22B 26/00 (20060101)
B01D 61/42 (20060101)
B01D 61/44 (20060101)
E21B 43/34 (20060101)
E21B 43/40 (20060101)
E21B 43/00 (20060101)
E21B 43/28 (20060101)

Abstract

A cyclic solution mining method that uses aqueous sodium hydroxide for recovering valuable alkali values, preferably as soda ash, from subterranean deposits of trona or nahcolite, even when such deposits are NaCl-contaminated. The aqueous sodium hydroxide mining solvent is generated via electrodialysis of a recirculating sodium chloride brine stream. Hydrogen chloride that is also generated in the cell's operation is neutralized with aqueous sodium carbonate, to regenerate sodium chloride brine that is recirculated to the electrodialysis cell as brine feed.

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