U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Production of 1,1,1,3-tetrachloropropane

Patent 4605802 Issued on August 12, 1986. Estimated Expiration Date: Icon_subject August 12, 2003. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2658930

3471579

3641170

Process for the preparation of tetrachloroalkanes Patent #: 4243607
Issued on: 01/06/1981
Inventor: Takamizawa ,   et al.

Inventor

Assignee

Application

No. 06/364175 filed on 04/01/1982

US Classes:

570/257Preparing by increasing the number of carbons in the compound

Examiners

Primary: Warren, Charles F.
Assistant: Boska, Joseph A.

Attorney, Agent or Firm

International Classes

C07C 17/275 (20060101)
C07C 17/00 (20060101)

Abstract

In the reaction of carbon tetrachloride with ethylene in the presence of a catalyst comprising a phosphite ester and an iron-containing material to produce 1,1,1,3-tetrachloropropane, the improvement which comprises employing powdered iron as the iron-containing material. Thereby the carbon tetrachloride is converted in large amount and with high selectivity to the desired product. The reaction proceeds well even under milder conditions than with the catalysts of the prior art.

Other References

  • T Asahara, M. Seno, and T. Sato, Kogyo Kagaku Zasshi, 74 (11), 2288 (1971)
  • T. Asahara and T. Sato, Kogyo Kagaku Zasshi, 74, 703 (1971)
  • Starks, "Free Radical Telomerization", Academic Press 1974, Chapter 5
  • Starks', "Free Radical Telomerization" (1974), pp. 108-119
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