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US Patent 4522971 - Polymers containing resorcinol monobenzoate

US Patent Issued on June 11, 1985
Estimated Patent Expiration Date: Icon_subject February 25, 2003Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

Resorcinol monobenzoate is reacted through the hydroxyl group preferably with an acrylic prepolymer containing glycidyl methacrylate. The product can be used in coating compositions and films to give highly ultraviolet absorbent properties.

Other References

  • "Ultraviolet Stabilizing Monomers and Polymers. II. Synthesis and Polymerization of Acrylate and Methacrylate Derivatives of 2,4-Dihydroxybenzophenone", J. Fertig, et al., Journal of Applied Polymer Science 10, 663-672, (1966)
  • "Transparent Ultraviolet-Barrier Coatings", S. M. Cohen et al., Journal of Polymer Science, Part A1, 9, 3263-3299 (1971)
  • "Polymeric Ultraviolet Absorbers", by D. A. Tirrell, Polymer News, 7, 104-110 (1981)
  • Prof. Dr. H. Batzer, "Polymere 2,2,6,6-Tetraalkylpiperidin-Derivate, 1 . . . ", Makromol Chem. 181, 595-633 (1980)
  • D. R. Olson, "UV Absorber Progenitors: Photo-Fries Rearrangements of Sulfonate Esters of Hydroxyphenylbenzotriazoles", J. App. Pol. Scie. 28, 1159-1165 (1983)

Inventor

Assignee

Application

No. 06/469689 filed on 02/25/1983

US Classes:

524/547, From reactant-containing atom other than O, N, C, halogen, or hydrogen524/548, From heterocyclic monomer524/555, From nitrogen-containing monomer other than acrylonitrile or methacrylonitrile524/556, From carboxylic acid or ester thereof monomer524/558, Acid or ester contains an oxygen atom which is other than part of a free carboxyl group or carboxylic acid ester group524/559, Ester contains two or more ester groups or at least one carboxylic ester group and at least one free acid group; or carboxylic acid contains two or more free carboxyl groups524/560, From ester derived from at least one unsaturated carboxylic acid and a saturated alcohol, e.g., methyl methacrylate, etc.525/132, With saturated phenolic reactant or polymer thereof; or with solid copolymer derived from at least one phenolic reactant wherein at least one of the reactants forming the solid copolymer is saturated; or with SPFI wherein at least one of the necessary ingredients is a phenolic reactant or with a reaction product thereof; or with a SICP containing a phenolic group Si-H or Si-C bond525/327.3, Three membered chalcogen ring monomer, e.g., oxirane, etc.525/328.2, Polymer derived from monomer containing nitrogen other than: unsubstituted ammonium, acrylonitrile, acrylamide, methylolacrylamide and the corresponding methacryl materials525/328.9, Polymer derived from ether monomer525/384, Oxygen compound contains at least one alcohol group526/321Monomer containing at least two carboxylic acid ester groups

Field of Search

524/547, From reactant-containing atom other than O, N, C, halogen, or hydrogen524/548, From heterocyclic monomer524/555, From nitrogen-containing monomer other than acrylonitrile or methacrylonitrile524/556, From carboxylic acid or ester thereof monomer524/558, Acid or ester contains an oxygen atom which is other than part of a free carboxyl group or carboxylic acid ester group524/559Ester contains two or more ester groups or at least one carboxylic ester group and at least one free acid group; or carboxylic acid contains two or more free carboxyl groups

Examiners

Primary: Lipman, Bernard

US Patent References

2970066, 3113907, 3288880, 3328491, 3340231, 3341493, 3365421, 3418397, 3429852, 3441545, 3444129, 3445423, 3445566, 3595602, 3652492, 3849373, 3956269, Azo free radical initiators containing ultraviolet light stabilizing groups
Issued on: 05/11/1976
Inventor: Sheppard ,   et al.
4208465, Clear coat/color coat finish containing an antioxidant and an ultraviolet light stabilizer
Issued on: 06/17/1980
Inventor: Chang
4210612, Novel polymeric N-heterocyclic compounds
Issued on: 07/01/1980
Inventor: Karrer
4278804, Ultraviolet light absorbing agents and compositions and articles containing same
Issued on: 07/14/1981
Inventor: Ashby ,   et al.
4294949, Novel polymeric compounds
Issued on: 10/13/1981
Inventor: Karrer
4308362, Copolymers of substituted piperidines, their manufacture and use
Issued on: 12/29/1981
Inventor: Wiezer ,   et al.
4310650, Ultraviolet absorbing copolymers
Issued on: 01/12/1982
Inventor: Gupta ,   et al.
4328346, Silane-functionalized ultraviolet screen precursors
Issued on: 05/04/1982
Inventor: Chung ,   et al.
4355071, Clear coat/color coat finish containing ultraviolet light stabilizer
Issued on: 10/19/1982
Inventor: Chang
4362895, Ultraviolet absorbing copolymers
Issued on: 12/07/1982
Inventor: Gupta ,   et al.
4372835Silane-functionalized ultraviolet screen precursors
Issued on: 02/08/1983
Inventor: Chung ,   et al.

International Classes

C08G 85/00 (20060101)
C09D 7/12 (20060101)
C08F 20/00 (20060101)
C08F 20/30 (20060101)
C08F 8/00 (20060101)

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