Patent References 3100750 3328306 Barium oxide/cresylic acid catalyzed ethoxylation Ethoxylation with strontium bases Inorganic catalyst for alkoxylation of alcohols Patent #: 4302613 InventorsApplicationNo. 06/370204 filed on 04/21/1982US Classes:568/618, Preparing from organic hydroxy containing compound (H of -OH may be replaced by a Group IA or IIA light metal)568/619, From polyhydroxy containing compound568/620, And cyclic ether568/622, Hydroxy containing (H of -OH may be replaced by a Group IA or IIA light metal)568/623, Polyhydroxy containing568/624, Plural diverse oxyalkylene groups containing568/625Plural diverse oxyalkylene groups containingExaminersPrimary: Mars, Howard T.Attorney, Agent or FirmInternational ClassesC07C 41/00 (20060101)C07C 41/03 (20060101) C08G 65/00 (20060101) C08G 65/26 (20060101) AbstractThe process for preparing nonionic surfactants wherein a narrower molecular weight distribution is obtained by the use of a calcium and/or strontium catalyst which comprises reacting a reactive hydrogen compound selected from the group consisting of monohydric alcohols having from about 8 to about 20 carbon atoms and a difunctional polypropylene oxide polymer having an average molecular weight in the range of 1000 to 5000 with an alkylene oxide having 2 to 4 carbon atoms at a temperature at which the reaction proceeds in the presence of at least a catalytic amount of a basic salt of calcium and/or strontium selected from the group consisting of hydroxide, alkoxide and phenoxides and a catalytic amount of an oxyalkylation catalyst promoter. |
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