U.S. patents available from 1976 to present.
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Method for production of hydrocarbons from hydrates

Patent 4424866 Issued on January 10, 1984. Estimated Expiration Date: Icon_subject September 8, 2001. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3102548

3103975

3179173

3270816

Methods of water flooding and fracturing using clean, non-damaging fracturing fluids Patent #: 4265311
Issued on: 05/05/1981
Inventor: Ely

Inventor

Assignee

Application

No. 06/300337 filed on 09/08/1981

US Classes:

166/303, Placing preheated fluid into formation166/308.2, Using a chemical (EPO)166/371Including non-expulsive material placed in well

Examiners

Primary: Suchfield, George A.

Attorney, Agent or Firm

International Classes

C09K 8/60 (20060101)
C09K 8/62 (20060101)
E21B 43/25 (20060101)
E21B 43/24 (20060101)
E21B 43/17 (20060101)
E21B 43/26 (20060101)
E21B 43/16 (20060101)

Abstract

A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl2 or CaBr2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl2 /CaBr2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl2 /CaBr2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

Other References

  • N V. Cherskii et al., "Methods of Locating, Opening Up, and Exploiting Productive Horizons Containing Crystal Hydrates of Natural Gas, Physical and Engineering Problems of the North," Institute of Physical and Engineering Problems of the North, Academy of Sciences of the U.S.S.R., Siberian Division, Yakut Branch, Publishing House Nauka Novosibirsk, pp. 112-119, 1972, as translated by Associated Technical Services, Inc
  • S. A. Arshinov et al., "Hydrate-Free Production of Wells in Messoyaksmi Gas Field," Gazovoe Delo, No. 12, 1971 (in Russian), as translated by H. Altmann, Jun. 1972
  • P. A. Kolodeznyi et al., "Engineering the Pumping of Antihydrate Inhibitor into Wells of the Messoyakhskoe Field," Gazov. Delo, No. 11, pp. 9-11, 1970, as translated by Associated Technical Services, Inc
  • Y. P. Korotaev et al., "Particulars of Investigating Gas Wells of the Far North in Relation to the Possibility of Hydrate Formation in the Bottom-Hole Zone of the Reservoir," Gazov. Prom., vol. 14, No. 5, pp. 12-15, 1969, as translated by Associated Technical Services, Inc
  • N. L. Sheshukov et al., Gazovoe Delo, No. 6, pp. 8-10, 1972
  • Gas Research Institute, Gas Hydrate Workshop, Denver, Colorado, pp. 39-44, Feb. 1, 1979
  • W. J. Cieslewicz, "Some Technical Problems and Developments in Soviet Petroleum and Gas Production," The Mines Magazine, pp. 12-16, Nov. 1971
  • C. Bily et al., "Naturally Occurring Gas Hydrates in the Mackenzie Delta, NWT," Bulletin of Canadian Petroleum Geology, vol. 22, No. 3, pp. 340-341 and 349, Sep. 1974
  • "Gas Imprisoned in Permafrost," The Energy Daily, vol. 9, No. 115, p. 4
  • F.Rakowsky et al., "Low-Temperature Electrolytes," Journal of the Electrochemical Society, vol. 10, No. 3, pp. 117-119, Mar. 1954
  • Y. F. Makogon, "Hydrates of Natural Gas," Geoexplorers Associates, Inc., translated from Russian by W. J. Cieslewicz, Denver, Colorado, pp. 89-103, 1978
  • Applied Engineered Stimulation, vol. II, Bryon Jackson, Inc., pp. 106-129, 138-141, and 170-179, 1972
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