U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Aqueous sizing composition and glass fibers made therewith for reinforcing thermosetting polymers

Patent 4394418 Issued on July 19, 1983. Estimated Expiration Date: Icon_subject December 24, 2001. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3556754

3655353

3814715

3817898

3882068

Sizing composition and glass fibers treated therewith
Patent #: 3935344
Issued on: 01/27/1976
Inventor: Haggerty ,   et al.

Oxidized polyolefin-high molecular weight elastomeric mixture
Patent #: 3936415
Issued on: 02/03/1976
Inventor: Coakley

Tire cord containing glass fibers sized with a starch based size
Patent #: 3946132
Issued on: 03/23/1976
Inventor: Hedden

Size composition for treating glass fibers for reinforcement of paper comprising starch, a polyolefin emulsion and lubricant
Patent #: 4143006
Issued on: 03/06/1979
Inventor: Workman

Emulsion composition and method for use in treating glass fibers Patent #: 4240944
Issued on: 12/23/1980
Inventor: Temple

Inventor

Assignee

Application

No. 06/334349 filed on 12/24/1981

US Classes:

428/391, Silane, silicone or siloxane in coating523/404, With organic nitrogen or organic sulfur reactant523/414, Polymer contains more than one 1,2-epoxy group or one derived from reactant containing more than one 1,2-epoxy group is further derived from or reacted with organic nitrogen or sulfur523/421, Organic nitrogen compound contains element other than C, H, O, or N523/427, Composition wherein two or more polymers or a polymer and a reactant all contain more than one 1,2-epoxy group, or product thereof523/437, Two or more polymers derived from ethylenic reactants only523/438, Polymer derived from ethylenic reactants only derived from plural unsaturated reactant523/443, Silicon523/466, Inorganic SI-O bond DNRM523/467, Polymer derived from ethylenic reactants only524/188, Silicon atom524/230, N-(C=O)alkyl wherein alkyl group contains eight or more carbon atoms524/315, Carboxylic acid ester524/322, Acyl group of the carboxylic acid or derivative has at least fifteen carbon atoms, e.g., stearic acid, etc.524/366, C-O-C compound DNRM524/375, Phenoxy group524/487, Hydrocarbon wax524/488Microcrystalline wax

Examiners

Primary: Marquis, Melvyn I.

Attorney, Agent or Firm

International Classes

C03C 25/26 (20060101)
C03C 25/24 (20060101)

Abstract

An aqueous sizing composition for glass fibers and the resultant sized glass fiber strands are provided, where the sized glass fiber strands have an improved slip/flow property and resultant thermosetting articles reinforced with the sized glass fiber strands have improved impact properties. The aqueous sizing composition has a poly(vinyl acetate) silane copolymer, epoxy polymer, one or more lubricants, an organo silane coupling agent, which may be an amino-silane coupling agent, lubricant modified-amino-organo silane coupling agent, epoxy-containing silane coupling agent or a mixture of one or more of these coupling agents, one or more nonionic surfactants, a polyethylene-containing polymer, a wax, a hydrocarbon acid and water. The aqueous sizing composition is applied to glass fibers which are then produced into wet chopped glass fiber strands or continuous sized glass fiber strands. The continuous sized glass fiber strands may be subsequently dried under drying conditions sufficient to remove a substantial amount of the moisture of the strands for subsequent chopping to produce dry chopped glass fiber strands. The sized glass fiber strands have good choppability in that there is not a high amount of fly or fuzz produced during the chopping operation. The sized glass fiber strands in any form may be used for reinforcing thermosetting polymeric material.

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