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AbstractA cyclic method for recovering alkali values from subterranean trona deposits. The ore is contacted via solution mining with an aqueous mining solvent containing sodium hydroxide, the resulting Na2 CO3 -containing solution is withdrawn and carbonated, and sodium sesquicarbonate and/or sodium bicarbonate is crystallized and separated from the solution. The crystallized solids are calcined in a direct coal-fired calciner, and the resultant anhydrous soda ash is recrystallized in water to form sodium carbonate monohydrate or anhydrous sodium carbonate, which is recovered as a dense alkali product. Aqueous mining solvent is regenerated by causticization of one or more of the various liquor streams, and the recovery cycle is repeated. | InventorsAssigneeApplicationNo. 06/216096 filed on 12/15/1980US Classes:299/4, Input and output wells423/206.2Alkali carbonate from tronaField of Search299/4Input and output wellsExaminersPrimary: Purser, Ernest R.Attorney, Agent or FirmUS Patent References3119655, 3184287, 3498744, 3780160, 3953073, Process for the solution mining of subterranean sodium bicarbonate bearing ore bodiesIssued on: 04/27/1976 Inventor: Kube4039618, Treatment of sodium carbonate crystallizer mother liquors Issued on: 08/02/1977 Inventor: Gancy , et al.4285915, Recovery of alkali values from trona ore Issued on: 08/25/1981 Inventor: Saldick , et al.4288419Enhanced recovery of sodium carbonate from NaCl-containing sodium carbonate solutions Issued on: 09/08/1981 Inventor: Copenhafer , et al. International ClassesE21B 43/40 (20060101)E21B 43/00 (20060101) E21B 43/34 (20060101) E21B 43/28 (20060101) C22B 3/14 (20060101) C22B 3/00 (20060101) |