Patent References 3120563 3826815 3876696 3922222 Method of recovering unreacted ammonium carbamate in urea synthesis Integrated urea-ammonia process Process for preparing urea Method of recovering unreacted materials and heat in urea synthesis Method for the condensation of carbammate in urea-synthesis installations Treatment of water vapor generated in concentrating an aqueous urea solution Patent #: 4207256 InventorsAssigneeApplicationNo. 06/216303 filed on 12/15/1980US Classes:564/70, With decomposition of by-product ammonium carbamate (i.e., decomposition of HNH-COO-HHNHH)564/72In plural stagesExaminersPrimary: Hearn, Brian E.Attorney, Agent or FirmInternational ClassesC07C 273/00 (20060101)C07C 273/04 (20060101) C02F 1/02 (20060101) C02F 11/08 (20060101) C02F 9/00 (20060101) C02F 11/06 (20060101) Foreign Application Priority Data1976-09-09 ITAbstractIn a urea producing method by synthesis, the improvement which consists in feeding liquid ammonia in excess to the reactor so that a urea solution which contains ammonium carbamate is produced, the carbamate is decomposed in a high-pressure decomposer and the stripping agent is an inert, oxygen-containing gaseous stream, the carbamate decomposition products are sent to a high pressure condenser and ammonium carbamate is formed, whereafter the carbamate is separated from the inerts and the solution of urea coming from the high-pressure decomposer is fed to a medium-pressure decomposer which is fed through its bottom with inerts. The heat for operating the medium-pressure decomposer is a hot condensate from the high-pressure-decomposer-heating steam, and the products of decomposition of the carbamate coming from the medium-pressure decomposer are sent to a medium-pressure condenser together with a solution of ammonium carbonate coming from the low-pressure sections of the installation. Virtually pure, nonpolluting waters can be discharged from the installation. |
| ||||||||||||||