U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Recovery of alkali values from trona ore

Patent 4285915 Issued on August 25, 1981. Estimated Expiration Date: Icon_subject April 23, 2000. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2376433

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3119655

3184287

3211519

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Inventors

Assignee

Application

No. 06/142918 filed on 04/23/1980

US Classes:

423/206.2, Alkali carbonate from trona23/302T, Sodium compounds299/5, Dissolving or chemical reaction423/421Alkali metal containing (Li, Na, K, Rb, or Cs)

Examiners

Primary: Straub, Gary P.

Attorney, Agent or Firm

International Classes

C01B 17/16 (20060101)
C01B 17/22 (20060101)
C01B 17/00 (20060101)
C01D 7/00 (20060101)
C22B 26/00 (20060101)
C22B 26/10 (20060101)

Abstract

Alkali values are recovered in a cyclic method from mechanically mined trona ore or from trona deposits by a solution mining technique utilizing a solvent comprising an aqueous solution of sodium sulfide. The ore is solubilized as sodium carbonate which is precipitated as sodium sesquicarbonate and/or sodium bicarbonate by treating the solution with hydrogen sulfide and the precipitated salt separated from the mother liquor. In the process, sodium sulfide and hydrogen sulfide become converted into sodium hydrosulfide which is contained in the mother liquor. Heat treatment of the mother liquor converts the sodium hydrosulfide into sodium sulfide thereby regenerating a solution of sodium sulfide which is recycled to the trona ore and into hydrogen sulfide which is evolved and recycled to the sodium carbonate solution.

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