U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Method of removing impurity metals from semiconductor devices

Patent 4231809 Issued on November 4, 1980. Estimated Expiration Date: Icon_subject May 25, 1999. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3320103

3556879

3929529

Elimination of stacking faults in silicon devices: a gettering process
Patent #: 3997368
Issued on: 12/14/1976
Inventor: Petroff ,   et al.

Process for the removal of specific crystal structure defects from semiconductor discs and the product thereof
Patent #: 4042419
Issued on: 08/16/1977
Inventor: Heinke ,   et al.

Semiconductor fabrication method for improved device yield by minimizing pipes between common conductivity type regions
Patent #: 4069068
Issued on: 01/17/1978
Inventor: Beyer ,   et al.

Method of making semiconductor device with PN junction in stacking-fault free zone
Patent #: 4116719
Issued on: 09/26/1978
Inventor: Shimizu ,   et al.

Gettering semiconductor wafers with a high energy laser beam
Patent #: 4131487
Issued on: 12/26/1978
Inventor: Pearce ,   et al.

Method of limiting stacking faults in oxidized silicon wafers Patent #: 4149905
Issued on: 04/17/1979
Inventor: Levinstein ,   et al.

Inventor

Assignee

Application

No. 06/042401 filed on 05/25/1979

US Classes:

438/477, By vapor phase surface reaction257/E21.318, Of silicon body, e.g., for gettering (EPO)438/473, By implanting or irradiating438/774In atmosphere containing halogen

Examiners

Primary: Rutledge, L. Dewayne
Assistant: Roy, Upendra

Attorney, Agent or Firm

International Classes

H01L 21/02 (20060101)
H01L 21/322 (20060101)

Abstract

A process is disclosed for gettering deleterious metal impurities, particularly the transition metals such as Cu, Fe, Co, Ni and Cr from silicon wafers by high temperature treatment for a comparatively short time in a hydrogen chloride vapor at low oxygen pressure. The low oxygen pressure inhibits the oxide growth on the silicon surfaces to thicknesses of not more than about 150 Angstroms, sufficient to protect the silicon surface but not so thick as to constitute a barrier to outdiffusion of the gettered impurities. This particular process may be preceded and followed by other previously known gettering techniques.

Other References

  • Rijks et al., J. Appl. Phys., 50 (Mar. 1979), 1370-1380
  • Seidel et al., "Transistors . . . Annealed in . . . Oxygen . . . ", IEEE, vol. ED-24, (1977), 717
  • Beyer et al., "Ion Implantation Gettering . . . ", IBM-TDB, 20 (1978), 3122
  • Shiraki, "S. F. Generation Suppression . . . HCl Oxidation", Jap. J. Appl. Phys., 15 (1976), 1
  • Poponiak et al., "Gettering . . . Epitaxial Layer", IBM-TDB, 19 (1976), 2052
  • Rozgonyi et al., "Interstitial Oxygen Gettering . . . ", Appl. Phys. Letts., 31 (1977), 343
  • Hu, ". . . Oxidation S. F. in Si", Appl. Phys. Letts., 27 (1975), 165
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