U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

ZSM-5 Containing aluminum-free shells on its surface

Patent 4203869 Issued on May 20, 1980. Estimated Expiration Date: Icon_subject December 1, 1998. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Crystalline silicates and method of preparing the same
Patent #: 3941871
Issued on: 03/02/1976
Inventor: Dwyer ,   et al.

ZSM-5 containing aluminum-free shells on its surface Patent #: 4088605
Issued on: 05/09/1978
Inventor: Rollmann

Inventor

Assignee

Application

No. 05/965656 filed on 12/01/1978

US Classes:

502/69, Heterogeneous arrangement423/700, ZEOLITE423/713, Isomorphic metal substitution502/71ZSM Type

Examiners

Primary: Dees, Carl F.

Attorney, Agent or Firm

International Classes

B01J 29/00 (20060101)
B01J 29/40 (20060101)
C07C 6/08 (20060101)
C07C 6/00 (20060101)
B01J 29/65 (20060101)
B01J 29/70 (20060101)

Abstract

Aluminosilicate zeolites are prepared containing an outer aluminum-free shell. The outer shell is essentially SiO2 that has crystallized on the zeolite surface in the ZSM-5 type configuration, leading to a more selective catalyst.

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