Patent ReferencesCrystalline silicates and method of preparing the same ZSM-5 containing aluminum-free shells on its surface Patent #: 4088605 InventorAssigneeApplicationNo. 05/965656 filed on 12/01/1978US Classes:502/69, Heterogeneous arrangement423/700, ZEOLITE423/713, Isomorphic metal substitution502/71ZSM TypeExaminersPrimary: Dees, Carl F.Attorney, Agent or FirmInternational ClassesB01J 29/00 (20060101)B01J 29/40 (20060101) C07C 6/08 (20060101) C07C 6/00 (20060101) B01J 29/65 (20060101) B01J 29/70 (20060101) AbstractAluminosilicate zeolites are prepared containing an outer aluminum-free shell. The outer shell is essentially SiO2 that has crystallized on the zeolite surface in the ZSM-5 type configuration, leading to a more selective catalyst. |
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