Patent References 3733362 Hydroformylation process using catalyst comprising platinum group metal on support having separate alumina phase Process for hydroformylation of olefin hydrocarbons Hydroformylation process over catalyst having silica alumina support with separate alumina phase and noble metal and cobalt or nickel Patent #: 3989759 InventorsApplicationNo. 05/870582 filed on 01/18/1978US Classes:568/454, Group VA element (N, P, As, Sb, or Bi) containing material utilized (e.g., arsenic containing ligand utilized, etc.)502/162, Organic phosphorus or nitrogen, except the ammonium ion502/166Rhodium containingExaminersPrimary: Lone, Werren B.Attorney, Agent or FirmInternational ClassesC07C 45/00 (20060101)C07C 45/50 (20060101) B01J 31/16 (20060101) B01J 31/24 (20060101) Foreign Application Priority Data1977-01-20 NLAbstractOlefinically unsaturated compounds are subjected to hydroformylation to produce the corresponding aldehyde having an additional carbon atom by reacting the compound with hydrogen and carbon monoxide under appropriate conditions of temperature and pressure in the presence of a catalytically active metallo-organic complex in the pores of a solid porous carrier in the form of a solution in a ligand-forming electron-donating phosphorous compound, such as triethyl phosphine, that has a vapor pressure of less than 15 mbar under reaction conditions. The central atom of the metallo-organic complex is preferably rhodium, cobalt, ruthenium or irridium. |
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