U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for forming high performance titanium trichloride olefin polymerization catalyst components

Patent 4111836 Issued on September 5, 1978. Estimated Expiration Date: Icon_subject November 3, 1996. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3206448

3660519

3919180

3926928

Catalyst component comprising brown titanium trichloride
Patent #: 3984350
Issued on: 10/05/1976
Inventor: Karayannis ,   et al.

Process for the manufacture of a catalyst Patent #: 4008177
Issued on: 02/15/1977
Inventor: Rust ,   et al.

Inventors

Assignee

Application

No. 05/738390 filed on 11/03/1976

US Classes:

502/107, Including heating to higher temperature526/136, Contains non-transition elemental metal, hydride thereof, or carbon to non transition metal atom bond526/141, Non-metal material is organic nitrogen-containing compound526/142Non-metal material is organic oxygen-containing compound

Examiners

Primary: Garvin, Patrick P.

Attorney, Agent or Firm

International Class

C08F 10/00 (20060101)

Abstract

A process is described herein for improving the soluble polymer production of, while maintaining substantially the same crystalline polymer yield of, a high surface area, large porosity, brown catalyst component comprising beta titanium trichloride and some of at least one organic electron pair donor compound, which component is prepared by (a) organoaluminum compound reduction of titanium tetrachloride followed by (b) incorporation of the reduced solid with said donor compound and thereafter (c) treatment with titanium tetrachloride. The improved process comprises treatment at ambient temperature or somewhat above with an additional organic electron pair donor compound such as an ester, an amine, an organic borate or a coordinating, cyclic hydrocarbon containing at least one double bond, etc., after (b) or (c) above and prior to use of said component in polymerization.

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