Patent References 2866720 3900630 Three layer anti-reflection film Patent #: 3934961 InventorsAssigneeApplicationNo. 05/766749 filed on 02/08/1977US Classes:428/155, Crackled, crazed or slit427/190, Metallic compound particles427/257, Wrinkled or crackled coating427/269, Glass or ceramic base427/279, Vitreous coating427/398.1, Cooling428/426, Of quartz or glass428/428, Next to another silicon containing layer428/432Next to metal or compound thereofExaminersPrimary: Herbert, Thomas J. Jr.Assistant: Varndell, R. Eugene Jr. Attorney, Agent or FirmInternational ClassesA61L 27/00 (20060101)C04B 41/45 (20060101) C04B 41/86 (20060101) C04B 41/50 (20060101) C03C 4/00 (20060101) A61L 27/32 (20060101) A61F 2/00 (20060101) AbstractA method of coating a Al2 O3 ceramic surface with a biologically active glass comprising contacting a glass and ceramic having different thermal coefficients of expansion at a temperature sufficient to bond the glass to the ceramic surface by ion diffusion, cooling the coated substrate to a temperature sufficient to produce thermo-mechanical stress induced interconnected micro-cracks in the glass coating and overcoating said micro-cracked glass coating with at least one additional coating of biologically active glass. The invention includes a product of manufacture comprising a compacted Al2 O3 ceramic surface coated with at least two layers of biologically active glass characterized in that the first layer of glass has interconnected thermo-mechanical stress induced micro-cracks therein. | |