U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Catalytic conversion of phenol to cyclohexanol and/or cyclohexanone

Patent 3998884 Issued on December 21, 1976. Estimated Expiration Date: Icon_subject December 21, 1993. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2087691

2328719

2574078

2829166

2857432

2873296

3076810

3305586

Inventor

Assignee

Application

No. 565086 filed on 04/04/1975

US Classes:

568/362, Phenol containing reactant568/835Cyclohexanol per se

Examiners

Primary: Morgenstern, Norman

Attorney, Agent or Firm

International Class

C07C 45/00 (20060101)

Abstract

Phenol is reacted with hydrogen in contact with a nickel catalyst, wherein the concentration of hydrogen is controlled, and/or wherein controlled amounts of water are included in the reaction mixture, to produce cyclohexanol, or preferably cyclohexanol plus cyclohexanone. Optionally, the product stream from this reaction is used as the feed stream for a dehydrogenation reaction to produce cyclohexanone.

Other References

  • Adkins, "Reactions of Hydrogen" pp. 56-62 (1937)
  • Mallinckrodt, "Lab. Chemicals," (1960) pp. 171-172
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