U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Glass fiber sizing method

Patent 3936285 Issued on February 3, 1976. Estimated Expiration Date: Icon_subject February 3, 1993. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3414432

3684467

Inventor

Assignee

Application

No. 512646 filed on 10/07/1974

US Classes:

65/448, Organic silicon containing (e.g., coupling agent, etc.)428/378, Coating on discrete and individual rods, strands or filaments65/453With advancing, gathering, or winding continuous fiber or filament

Examiners

Primary: Lindsay, Robert L.

Attorney, Agent or Firm

Abstract

A glass fiber sizing composition for the reinforcement of resin matrices is provided which comprises a homogeneous aqueous composition of two polyester resins. The first polyester resin is a water solubilized condensation cross-linkable, polyester resin, insoluble in aromatic solvents. The second polyester resin is insoluble but dispersible in water but insoluble in the first polyester resin. Thus, when the second polyester is blended with a water solution of the first polyester, a dispersion is produced. In this dispersion the water and the first polyester form the continuous phase and the second polyester forms the dispersed phase. A plasticizer and two silane coupling agents are also incorporated into the sizing composition. The first coupling agent is provided to promote adhesion between the glass fibers and the resin matrix and the second silane coupling agent is employed in the sizing composition to control the wetting of the glass fibers by the first silane coupling agent. A thermoplastic polymer of sufficiently low molecular weight is employed to impart pressure sensitive adhesive characteristics to the sizing composition. Glass fibers sized with the sizing composition of the invention have found particular utility when incorporated into resin matrices which are utilized as molding compounds.

Other References

  • 428 37
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