In 1879, Auguste Bartholdi received design patent number 11,023 titled "Design for a Statue". It was for the Statue of Liberty.
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| Number | Title | Issue Date |
| 4950310 | Process for the preparation of crystalline sheet sodium silicates X-ray crystalline sodium silicates having a sheet structure and an SiO2 :Na2 O molar ratio of 1.9 to 3.5 are prepared by dissolving an X-ray crystalline sodium silicate having a sheet structure and an SiO2 /Na2 ... | 08/21/1990 |