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Class 585/470 - By alkyl or aryl transfer between molecules, e.g., disproportionation, etc.


Subclass of Class 585 - Chemistry of hydrocarbon compounds
Definition: Subject matter wherein an alkyl or aryl moiety of a molecule
No. of patents: 193
Last issue date: 05/01/2012


1          
NumberTitleIssue Date
8168843Reformate benzene reduction via transalkylation
A process for reducing benzene content in a reformate stream, including: fractionating a full range reformate comprising benzene, C7 to C9 monoalkyl aromatics, and C10+ polyalkyl aromatics into at least three fractions including a li...
05/01/2012
8030533Method for combined production of paraxylene and benzene with improved productivity
A process for the combined production of para-xylene and benzene comprises: separating a first feed, by adsorption in a simulated moving bed SMB, to produce an extract E rich in para-xylene and at least one raffinate R which is dep...
10/04/2011
7638669Integrated process for producing xylenes and high purity benzene
Processes and apparatus are provided that provide high yields of xylenes per unit of aromatic-containing feed while enabling a high purity benzene co-product to be obtained without the need for an extraction or distillation to remove C6 naphthenes. The pr...
12/29/2009
7632975Process for the synthesis of arylfluorenes and analogs thereof
A process is provided for the synthesis of a compound of formula (I): wherein: M=0 or 1; N and p are 0 or 1 to 4; X is a single bond, O, S or NH; ...
12/15/2009
7544848Integrated process for producing xylenes and high purity benzene
Processes and apparatus are provided that provide high yields of xylenes per unit of aromatic-containing feed while enabling a high purity benzene co-product to be obtained without the need for an extraction or distillation to remove C6 naphthenes. The pr...
06/09/2009
7405335Integrated process for producing xylenes and high purity benzene
Processes and apparatus are provided that provide high yields of xylenes per unit of aromatic-containing feed while enabling a high purity benzene co-product to be obtained without the need for an extraction or distillation to remove C6 naphthenes. The pr...
07/29/2008
7387978Selective para-xylene production via methylation of toluene with methanol in the presence of modified HZSM-5 catalyst
We disclose a method for converting toluene to xylenes, comprising contacting toluene with methanol in the presence of a silica-bound HZSM-5 catalyst. As an example, in one embodiment the method can include: (i) first silylating HZSM-5, to form silylated HZSM-5; (ii...
06/17/2008
7361798Production of dialkylbenzenes
The invention relates to a process for producing a desired dialkylbenzene isomer having a formula R2C6H4, where R is an alkyl substituent, by contacting a polyalkylbenzene compound of formula RnC6H6-n...
04/22/2008
7358414Para-xylene process using perm-selective separations
Processes and apparatus are disclosed for recovery of purified products from a fluid mixture by means of integrated perm-selective separations with purified product recovery operations. More particularly, integrated processes of the invention comprise separations by...
04/15/2008
7326819High-activity isomerization catalyst and process
A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of...
02/05/2008
7314601Processes for producing xylenes using isomerization and transalkylation reactions and apparatus therefor
Processes for making xylene isomer use integrated transalkylation and isomerization reaction zones to enhance xylene recovery and enable reduction in capital costs and energy consumption. ...
01/01/2008
7304193Integrated process for aromatics production
An aromatics complex flow scheme has been developed. The isomerized xylenes effluent from a xylene recovery zone is recycled to a transalkylation stripper without requiring C8 aromatic hydrocarbons to be separated. This improvement results in an aromatics...
12/04/2007
7288687Integrated process for aromatics production
An aromatics complex flow scheme has been developed in which C7-C8 aliphatic hydrocarbons are recycled to an isomerization unit of a xylene recovery zone to increase the efficiency of the isomerization unit. This improvement results in an aroma...
10/30/2007
7276636Styrene process with recycle from dehydrogenation zone
A styrene process is disclosed that uses a dehydrogenation reactor and a transalkylation reactor and in which a significant portion of the benzene, the inhibitors, or both, recovered from the dehydrogenation reactor passes to the transalkylation reactor. The process...
10/02/2007
7271303Multi-zone process for the production of diesel and aromatic compounds
A multi-zone process for the production of low sulfur diesel and aromatic compounds wherein C9+ hydrocarbons are hydrocracked to produce low sulfur diesel and a naphtha boiling range stream which is reformed and transalkylated within reforming ...
09/18/2007
7271123Molecular sieve catalyst composition, its making and use in conversion process
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a molecular sieve cata...
09/18/2007
7268263Integrated process for aromatics production
An aromatics complex flow scheme has been developed. C7-C8 aliphatic hydrocarbons are recycled to an isomerization unit of a xylene recovery zone to increase the efficiency of the isomerization unit. This improvement results in an aromatics com...
09/11/2007
7249469Method for separating a multicomponent stream
This invention relates to a method for separating a stream having benzene, toluene and alkyl benzene, said method comprising: feeding the stream into a first distillation column, wherein the stream comprises between about 60 mole percent to about 85 mole percent tol...
07/31/2007
7230152Process for selective aromatics disproportionation with increased conversion
An improved process is disclosed for the selective disproportionation of toluene. The process preferably uses a disproportionation catalyst comprising a pentasil type zeolite such as MFI that is bound with aluminum-phosphate. Running the process at a toluene convers...
06/12/2007
7220888Method for producing hydrocarbons having a modified carbon skeleton
The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal...
05/22/2007
7179434Integrated apparatus for aromatics production
Enabling a transalkylation process to handle both C10 alkylaromatics and unextracted toluene permits the following improvements to be realized. No longer extracting toluene allows a reformate-splitter column to be eliminated. The extraction unit can be mo...
02/20/2007
7169730Modified carbide and oxycarbide containing catalysts and methods of making and using thereof
Compositions including modified carbide-containing nanorods and/or modified oxycarbide-containing nanorods and/or modified carbon nanotubes bearing carbides and oxycarbides and methods of making the same are provided. Rigid porous structures including modified oxyca...
01/30/2007
7169368Integrated apparatus for aromatics production
Enabling a transalkylation process to handle both C10 alkylaromatics and unextracted toluene permits the following improvements to be realized. No longer extracting toluene allows a reformate-splitter column to be eliminated. The extraction unit can be mo...
01/30/2007
7160831Molecular sieve catalyst composition, its making and use in conversion processes
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated mo...
01/09/2007
7151199Hydrocarbon conversion processes using non-zeolitic molecular sieve catalysts
Hydrocarbon or oxygenate conversion process in which a feedstock is contacted with a non zeolitic molecular sieve which has been treated to remove most, if not all, of the halogen contained in the catalyst. The halogen may be removed by one of several methods. One m...
12/19/2006
7128883Process and apparatus for ethylbenzene production and transalkylation to xylene
The use of two transalkylation catalysts to react aromatic compounds of carbon number nine (and heavier carbon numbers) with benzene to form carbon number eight aromatics is disclosed. The two catalyst system preserves ethyl-group species on the heavier aromatics th...
10/31/2006
7109389Process for the disproportionation and transalkylation of toluene and heavy aromatics
A process for the disproportionation and transalkylation of toluene and the heavy aromatics comprises: subjecting a first stream of toluene, and a stream enriched in aromatics of nine carbon atoms to toluene disproportionation and transalkylation reactions in the pr...
09/19/2006
7094941Selectivated metallosilicate catalyst composite for alkyl aromatic conversion, process for the preparation thereof, use thereof in hydrocarbon conversion
A repeated “soak and dry” selectivation process for preparing a modified metallosilicate catalyst composite is disclosed comprising of a mixture of amorphous silica, alumina and a pore size controlled metallosilicate useful for alkylaromatic conversion. The proc...
08/22/2006
7094939Styrene process with recycle from dehydrogenation zone
A styrene process is disclosed that uses a dehydrogenation reactor and a transalkylation reactor and in which a significant portion of the benzene, the inhibitors, or both, recovered from the dehydrogenation reactor passes to the transalkylation reactor. The process...
08/22/2006
7041866Solid-acid isomerization catalyst and process
A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component co...
05/09/2006
7022889Isomerization process using novel catalyst
A process for the isomerization of a feedstream comprising C5–C6 hydrocarbons where the process involves charging hydrogen and a feedstream comprising at least normal C5–C6 hydrocarbons into an isomerization zone and c...
04/04/2006
7019184Non-oxidative conversion of gas to liquids
The present invention provides a process for natural gas in the form, e.g., of stranded gas or associated gas to transportable liquids. More particularly, the present invention provides a process in which the gas is non-oxidatively converted to aromatic liquid, pref...
03/28/2006
7015175High-activity isomerization catalyst and process
A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of...
03/21/2006
6979396Combination reforming and isomerization process
A reforming and isomerization process has been developed. A reforming feedstream is charged to a reforming zone containing a reforming catalyst and operating at reforming conditions to generate a reforming zone effluent. Hydrogen and an isomerization feedstream is c...
12/27/2005
6977322Isomerization catalyst and processes
A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a tungstated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component ...
12/20/2005
6972347Method for converting aromatic hydrocarbons
A method for converting aromatic hydrocarbons by contacting an aromatic hydrocarbon starting material including benzene and having a non-aromatic compound content of 1% by weight or less, with a catalystto generate useful C7 and C8 aromatic hydrocarbons while reduci...
12/06/2005
6958425Aromatics transalkylation to ethylbenzene and xylenes
The use of transalkylation catalysts to react heavy aromatic compounds of carbon number nine (and heavier carbon numbers) with benzene to form carbon number eight aromatics is disclosed. The catalyst system preserves ethyl-group species on the heavier aromatics that...
10/25/2005
6936744Alkylaromatics production
The present invention provides a process for producing a monoalkylated aromatic compound, particularly cumene, comprising the step of contacting a polyalkylated aromatic compound with an alkylatable aromatic compound under at least partial liquid phase conditions an...
08/30/2005
6927188High-activity isomerization catalyst and process
A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of...
08/09/2005
6924407Pressure-tuned solid catalyzed heterogeneous chemical reactions
Improved methods for conducting solid acid-catalyzed, near- or supercritical heterogeneous chemical reactions (e.g., alkylation reactions) are provided which give enhanced product yields and permit longer processing runs. The preferred reactions of the invention are...
08/02/2005
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