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| Number | Title | Issue Date |
| 7829748 | Process for the manufacture of 1,3,3,3-tetrafluoropropene The invention provides an economic process for the manufacture of 1,3,3,3-tetrafluoropropene (HFO-1234ze) by a two stage process. A vapor phase hydrofluorination of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) into 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) a... | 11/09/2010 |
| 7781626 | Azeotrope-like compositions of 1,1,1,3,3-pentafluorobutane and hydrogen fluoride The invention relates to azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluorobutane (HFC-365) and hydrogen fluoride and a process for separating the azeotrope-like mixtures. The compositions of the invention are useful as an intermediate in the production... | 08/24/2010 |
| 7629495 | Process for the manufacture of 1,1,1,3,3-pentafluoropropane A process for the manufacture of 1,1,1,3,3-pentafluoropropane which comprises adding hydrogen fluoride to 1,1,1,3-tetrafluoropropene in the substantial absence of metal catalyst. Another embodiment provides for the manufacture of 1,1,1,3,3-pentafluoropropane which c... | 12/08/2009 |
| 7592494 | Process for the manufacture of 1,3,3,3-tetrafluoropropene The invention provides an economic process for the manufacture of 1,3,3,3-tetrafluoropropene (HFC-1234ze) by a two stage process. A hydrofluorination of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) into 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) and 1,1,1,3,3... | 09/22/2009 |
| 7566809 | Process for separation of a mixture comprising at least one hydrofluoroalkane Process for the separation of a mixture comprising at least one hydrofluoroalkane and hydrogen fluoride, according to which a hydrofluoroalkane/hydrogen fluoride mixture is reacted with at least one chlorinated or chlorofluorinated precursor of the hydrofluoroalkane... | 07/28/2009 |
| 7361795 | Azeotrope-like compositions of 1,1,1,3,3-pentafluorobutane and hydrogen fluoride The invention relates to azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluorobutane (HFC-365) and hydrogen fluoride and a process for separating the azeotrope-like mixtures. The compositions of the invention are useful as an intermediate in the production... | 04/22/2008 |
| 7345209 | Processes for synthesis of 1,3,3,3-tetrafluoropropene Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises, in one preferred embodiment, providing a compound of the formula CF3CH2CHFX, wherein X is a selected from the group consisting of chlorine, bromine and iodin... | 03/18/2008 |
| 7317071 | Process for producing fluoromonomer Processes for producing a fluoromonomer from a fluoropolymer, among which one that can be carried out more simply is a process wherein thermal decomposition of a fluoropolymer is preformed by means of a rotary kiln (5) so as to produce a fluoromonomer, the pr... | 01/08/2008 |
| 7312367 | Method of making 1,1,3,3,3-pentafluoropropene The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc ca... | 12/25/2007 |
| 7230146 | Process for producing fluoropropenes Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fl... | 06/12/2007 |
| 7223892 | Process for the separation of a mixture comprising at least one hydrofluoroalkane Process for the separation of a mixture comprising at least one hydrofluoroalkane and hydrogen fluoride, according to which a hydrofluoroalkane/hydrogen fluoride mixture is reacted with at least one chlorinated or chlorofluorinated precursor of the hydrofluoroalkane... | 05/29/2007 |
| 7214839 | Method of making hydrofluorocarbons A manufacturing process for making hydrofluorocarbons (HFCs), by reacting a hydrochlorocarbon and HF in a liquid phase catalytic reactor using a large mole ratio of HF to hydrochlorocarbon to minimize formation of high boiling by-products and improve HF consumption ... | 05/08/2007 |
| 7183448 | Azeotropic composition, comprising 1, 1, 1, 3,3-pentafluoropropane and 1, 1, 1-trifluoro-3-chloro-2-propene, method of separation and purification of the same, and process for producing 1, 1, 1,3,3-pentafloropropane and 1, 1, 1-trifluoro-3-chloro-2-propene A mixture comprising at least 1,1,1,3,3-pentafluoropropane and 1,1,1-trifluoro-3-chloro-2-propene is subjected to a distillation operation, and thereby, a distillate comprising an azeotropic composition consisting substantially of 1,1,1,3,3-pentafluoropropane and 1,... | 02/27/2007 |
| 7176338 | Process for preparing 1,1,1-trifluoro-2, 2-dichloroethane The invention relates to a process for preparing 1,1,1-trifluoro-2,2-dichloroethane (F123). This process consists in placing 1,1,1-trifluoro-2-chloroethane (F133a) in contact with chlorine in the presence of hydrogen fluoride and a fluorination catalys... | 02/13/2007 |
| 7145046 | Production of fluorine compounds Inorganic and organic compounds containing fluorine can be produced, for example, from corresponding chlorine-containing compounds by chlorine/fluorine exchange using fluorinating agents. Monocyclic or bicyclic compounds containing at least two nitrogen atoms, at le... | 12/05/2006 |
| 7138553 | Method for purifying tetrachloroethylene and process for producing hydrofluorocarbons Tetrachloroethylene containing a stabilizer is contacted with a zeolite having an average pore size of 3.4 to 11 Å and/or a carbonaceous adsorbent having an average pore size of 3.4 to 11 Å in a liquid phase to obtain a high purity tetrachloroethylene. A halogen... | 11/21/2006 |
| 7112708 | Method of making difluoromethane, 1,1,1-trifluoroethane and 1,1-difluoroethane A process for the production of difluoromethane (HFC-32), 1,1,1-trifluoroethane (HFC-143a) and 1,1-difluoroethane (HFC-152a). In the process the following steps are employed: (a) providing a reaction vessel, (b) pr... | 09/26/2006 |
| 7109386 | Method for preparing a halogenated olefin Process for the preparation of a halogenated olefin by reaction of an alkyne and/or of an allene compound with a hydrogen halide in a liquid medium comprising at least one hydrohalogenation catalyst comprising at least one palladium compound. ... | 09/19/2006 |
| 7102041 | Continuous process for preparing halogenated compounds A process for preparing a haloalkane comprising: (a) contacting a haloalkane starting material with an alkene in the presence of an effective amount of a catalyst complex under conditions effective to facilitate an addition reaction and to form a product stream comp... | 09/05/2006 |
| 7102040 | Fluoropolymer lined metallic vessel design The invention provides an apparatus useful in fluorinating organic compounds, or more particularly to a reactor system suitable for the fluorination of organic compounds on a commercial scale. The apparatus is also useful in chemical reactions including heating or c... | 09/05/2006 |
| 7094934 | Production process of hydrofluorocarbons In a process for producing a hydrogen-containing fluorinated hydrocarbon in which a halogenated hydrocarbon reaction raw material, which includes a chlorinated alkene and/or a hydrogen-containing chlorinated alkane, is subjected to a fluorination reaction with hydro... | 08/22/2006 |
| 7091388 | Method of making 1,1,3,3,3-pentafluoropropene The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc ca... | 08/15/2006 |
| 7084316 | Process for purifying pentafluoroethane, process for producing the same, and use thereof A process comprising bringing crude pentafluoroethane containing at least one compound selected from the group consisting of hydrofluorocarbons containing one carbon atom, hydrochlorofluorocarbons containing one carbon atom and hydrochlorocarbons containing one carb... | 08/01/2006 |
| 7074434 | Process for the separation of a mixture comprising at least one hydrofluoroalkane and hydrogen fluoride, processes for the preparation of a hydrofluoroalkane and azeotropic compositions Process for the separation of a mixture comprising at least one hydrofluoroalkane and hydrogen fluoride, according to which a hydrofluoroalkane/hydrogen fluoride mixture is reacted with at least one chlorinated or chlorofluorinated precursor of the hydrofluoroalkane... | 07/11/2006 |
| 7071368 | Method of making 1,1,1-trifluoroethane A process for producing 1,1,1-trifluoroethane (HFC-143a) which process comprises reacting hydrogen fluoride with vinylidene chloride along with one or more of 1,1,-dichloro-1-fluoroethane (HCFC-141b), 1-chloro-1,1-difluoroethane (HCFC-142b) and 1,1,1-trichloroethane... | 07/04/2006 |
| 7067705 | Process for the preparation of 1,1-dichloro-3,3,3-trifluoropropane A convenient and economical process for the preparation of 1,1-dichloro-3,3,3-trifluoropropane (HCFC-243) by the reaction of 1,1,1,3,3-pentachloropropane (HCC-240) with hydrogen fluoride in the presence of an activated hydrofluorination catalyst. Also, the selective... | 06/27/2006 |
| 7067706 | Method for preparing a hydro(chloro)fluoroalkane and catalyst Process for the preparation of a hydro(chloro)fluoroalkane according to which a halogenated precursor of the hydro(chloro)fluoroalkane is reacted with hydrogen fluoride in the presence of a catalyst comprising chromium (Cr) and at least one other metal selected from... | 06/27/2006 |
| 7067707 | Pentafluoroethane production method Process for the manufacture of pentafluoroethane, according to which tetrafluoroethylene is subjected to reaction with an organic nitrogenous base hydrofluoride at a temperature of greater than 100° C. and not exceeding 160° C. ... | 06/27/2006 |
| 7064240 | Process for producing perfluorocarbons and use thereof The process for producing perfluorocarbons according to the present invention is characterized in that in the production of a perfluorocarbon by contacting an organic compound with a fluorine gas, the organic compound is contacted with the fluorine gas at a temperat... | 06/20/2006 |
| 7053252 | Process for preparing 1,1,1-trifluoro-2,2-dichloroethane The invention relates to a process for preparing 1,1,1-trifluoro-2,2-dichloroethane (F123). This process consists in placing 1,1,1-trifluoro-2-chloroethane (F133a) in contact with chlorine in the presence of hydrogen fluoride and a fluorination catalys... | 05/30/2006 |
| 7009083 | Process for the preparation of 1-chloro-1-fluoroethane and/or 1,1-difluoroethane The invention relates to a process for the preparation of 1-chloro-1-fluoroethane and 1,1-difluoroethane by reaction of vinyl chloride with hydrogen fluoride, in an organic solvent consisting of at least one saturated halogen-containing hydrocarbon. ... | 03/07/2006 |
| 6967260 | Method for purification of tetrafluoromethane and use thereof Tetrafluoromethane containing ethylene compound, hydrocarbon compounds, carbon monoxide and/or carbon dioxide is contacted with zeolite having an average pore size of 3.4 to 11 Å and an Si/Al ratio of 1.5 or less and/or a carbonaceous adsorbent having an average p... | 11/22/2005 |
| 6939521 | Fluoropolymer reactor with heat exchange jacket A reactor for fluorinating an organic compound comprising (a) an outer vessel; (b) a reactor vessel being disposed within said outer vessel to define an annular space, said reactor vessel at least partially comprising a fluoropolymer, said annular space being adapte... | 09/06/2005 |
| 6930215 | Process for the preparation of 1.1.1.3.3-pentafluoropropane 1,1,1,3,3-pentafluoropropane is produced by reaction between 1,1,1,3,3-pentachloropropane and hydrogen fluoride in the presence of a hydrofluorination catalyst. The 1,1,1,3,3-pentachloropropane may advantageously be obtained by reaction between vinyl chloride and te... | 08/16/2005 |
| 6927312 | Method of removing water from hydrofluorocarbon manufacturing processes Disclosed are improved fluorination processes and fluorine-containing compositions which involve introducing to one or more fluorination process compositions a water reactive agent in an amount and under conditions effective to decrease the amount of water in that c... | 08/09/2005 |
| 6891074 | Production of hydrofluoroalkanes A process for the production of a hydrofluoroalkane, which process comprises contacting a hydrochlorofluoroethane of formula CClXYCFHZ, wherein X and Y are each independently chlorine or fluorine and Z is chlorine, fluorine or hydrogen, in the liquid phase with hydr... | 05/10/2005 |
| 6858762 | Process for the manufacture of halocarbons and selected compounds and azeotropes with HF A liquid phase process is disclosed for producing halogenated alkane adducts of the formula CAR1R2CBR3R4 (where A, B, R1, R2, R3, and R4 are as defined in the specification) whic... | 02/22/2005 |
| 6849772 | Process for producing and purifying 1,1-difluoroethane, and product thus obtained 1,1-Difluoroethane containing less than 10 mg/kg of vinyl chloride is obtained by treatment, with hydrogen fluoride, of a crude 1,1-difluoroethane containing less than 1 mol of hydrogen chloride per mole of 1,1-difluoroethane. ... | 02/01/2005 |
| 6846963 | Process for producing 1,1,1,3,3-pentafluoropropane In a process for producing 1,1,1,3,3-pentafluoropropane which has a liquid-phase reaction step for fluorination of 1,1,1,3,3-pentahalopropane (wherein at least one of halogen atoms is not fluorine) with HF in the presence of antimony pentahalide catalyst in a reacto... | 01/25/2005 |
| 6844475 | Low temperature production of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) A process for producing 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) from 1,1,1-3,3-pentachloropropane (HCC-240fa) by its reaction with hydrogen fluoride, the reactants are reacted in a liquid phase reaction at a temperature of less than 150° C. in the presence of... | 01/18/2005 |
