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Class 570/155 - By dehalogenation or dehydrohalogenation of adjacent carbon atoms in a compound


Subclass of Class 570 - Organic compounds -- part of the class 532-570 series
Definition: Process wherein carbon to carbon unsaturation is obtained
No. of patents: 60
Last issue date: 12/06/2011


1    
NumberTitleIssue Date
8071825Method for producing fluorinated organic compounds
Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). In certain preferred embodiments the processes comprise first exposing a compound of Formula (IA) C(X)...
12/06/2011
8067649Method for producing fluorinated organic compounds
Disclosed is a process for producing tetrafluoropropene comprising: (a) catalytically fluorinating at least one tetrafluoropropene in a first reactor to produce HCFO-1233xf; (b) reacting said HCFO-1233xf with hydrogen fluoride in a second reactor to produce HCFC-244...
11/29/2011
8058486Integrated process to produce 2,3,3,3-tetrafluoropropene
A method for preparing 2,3,3,3-tetrafluoroprop-1-ene comprising (a) providing a starting composition comprising at least one compound having a structure selected from Formulae I, II and III: CX2═CCl—CH2X  (Formula I) ...
11/15/2011
8013194Process for the manufacture of fluorinated olefins
A method for producing 1,1,1,2-tetrafluoropropene and/or 1,1,1,2,3-pentafluoropropene using a single set of four unit operations, the unit operations being (1) hydrogenation of a starting material comprising hexafluoropropene and optionally recycled 1,1,1,2,3-pentaf...
09/06/2011
7994371Process for making chlorotrifluoroethylene from 1,1,2-trichlorotrifluoroethane
Disclosed is a process for the making chlorotrifluoroethylene. The process comprises the step of reacting 1,1,2-trichlorotrifluoroethane with a reducing metal in the presence of a polar aprotic solvent under conditions sufficient to form chlorotrifluoroethylene....
08/09/2011
7964759Method for producing 3,3,3-trifluoropropyne
Disclosed is a method for producing 3,3,3-trifluoropropyne, which is characterized in that a base is reacted with (Z)-1-halogeno-3,3,3-trifluoropropene represented by formula [1]. It is possible by this production method to obtain 3,3,3-trifluoropropyne with high yi...
06/21/2011
7956225Polyfluoro-1-alkene and method for producing the same
A polyfluoro-1-alkene represented by the general formula: CF3(CF2)nCH2(CF2)mCH═CH2 [I], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, is produced by reacting a polyflu...
06/07/2011
7897823Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
Disclosed herein is a process to produce an azeotrope composition comprising a hydrofluoroolefin and hydrogen fluoride, said process comprising, dehydrofluorinating a hydrofluorocarbon containing at least one hydrogen and at least one fluorine on adjacent carbons, t...
03/01/2011
7795481Method of hydrodechlorination to produce dihydrofluorinated olefins
Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also ...
09/14/2010
7795480Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf)
The present invention relates to an improved method for manufacturing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) by reacting 1,1,2,3-tetrachloropropene, 1,1,1,2,3-pentachloropropane, and/or 2,3,3,3-tetrachloropropene with hydrogen fluoride, in a vapor phase reac...
09/14/2010
7723552Process for making chlorotrifluoroethylene from 1,1,2-Trichlorotrifluoroethane
A process for the making chlorotrifluoroethylene. The process has the step of reacting 1,1,2-trichlorotrifluoroethane with a reducing metal in the presence of a polar aprotic solvent under conditions sufficient to form chlorotrifluoroethylene. ...
05/25/2010
7423188Azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
Disclosed herein are azeotrope and near-azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride. These azeotrope and near-azeotrope compositions are useful in processes to produce E-1,3,3,3-tetrafluoropropene and in processes to purify E...
09/09/2008
7396965Method for producing fluorinated organic compounds
A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms. ...
07/08/2008
7388117Azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
Disclosed herein are azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride. The azeotrope compositions are useful in processes to produce and in processes to purify 1,2,3,3,3-pentafluoropropene. ...
06/17/2008
7385094Azeotrope compositions comprising tridecafluoro-3-heptene and hydrogen fluoride and uses thereof
Disclosed herein are azeotrope and near-azeotrope compositions comprising 1,1,1,2,2,4,5,5,6,6,7,7,7-tridecafluoro-3-heptene (HFC-162-13mczy, CF3CF2CH═CFCF2CF2CF3) and 1,1,1,2,2,3,5,5,6,6,7,7,7-tridecafluoro-3-...
06/10/2008
7358405Dehalogenation process
A process for obtaining vinyl compounds by dehalogenation of halofluorinated compounds with aromatic substituents, having formula: T-Ar—(O)y—CFX′—CF2X″  (I) wherein: X′=F, C...
04/15/2008
7348461Processes for halogenating compounds
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
03/25/2008
7329786Processes for producing CFCFHCF
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
02/12/2008
7321071Process for the production of water-soluble fluorine-containing vinyl ethers
The present invention relates to a method for producing a water-soluble fluorine-containing vinyl ether which comprises subjecting a fluorine-containing 2-alkoxypropionic acid derivative represented by the following general formula (I):
01/22/2008
7312367Method of making 1,1,3,3,3-pentafluoropropene
The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc ca...
12/25/2007
7304191Process for the synthesis of fluoroorganic compounds
The present invention relates to a fluorination method for the synthesis of halofluoroorganic compounds which can be used, inter alia, as precursors in the synthesis of 2,3-unsaturated fluoroorganic carbonyl compounds comprising a fluorine substituent in the 2 posit...
12/04/2007
7271301Synthesis of perfluoroolefins
A gold-lined pyrolysis reactor is used to pyrolyze compounds to form fluoroolefins like tetrafluoroethylene and hexafluoropropylene in high yield, with minimum to no formation of perfluoroisobutylene, chlorotrifluoroethylene, coke, salts, or polymer. ...
09/18/2007
7268261Production processes
Methods and materials are disclosed for the recovery of valuable hydrofluorocarbons and subsequent conversion to environmentally inert compounds. More specifically methods and materials are provided for recovering hydrofluorocarbons such as HFC-227, HFC-236, HFC-245...
09/11/2007
7250540Process for manufacturing fluoroolefins
A process for manufacturing fluoroolefins comprising perfluorinating a starting material comprising at least one carbon-bonded hydrogen by electrochemical fluorination, dissociating this separated effluent in a pyrolysis, quenching and separating the effluent to yie...
07/31/2007
7250539Materials and methods for the conversion of hydrofluorocarbons
Methods and materials are disclosed for the recovery of valuable hydrofluorocarbons and subsequent conversion to environmentally inert compounds. More specifically methods and materials are provided for recovering hydrofluorocarbons such as HFC-227, HFC-236, HFC-245...
07/31/2007
7230146Process for producing fluoropropenes
Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fl...
06/12/2007
7164050Preparation of halo-olefin
A process for preparing a halo-olefin to minimize one or more side reactions which form at least one impurity, said process comprising contacting a halogenated hydrocarbon with a metal dehalogenating agent dissolved in a solvent under conditions sufficient to dehalo...
01/16/2007
7132577Method of inhibiting coke formation in ethylene dichloride pyrolysis cracker
Provided is a method of inhibiting the formation of coke in an ethylene dichloride to vinyl chloride monomer pyrolysis cracker. The coke formation, which occurs during an ethylene dichloride pyrolysis reaction, is inhibited by contacting a heat-transfer surface of t...
11/07/2006
7091388Method of making 1,1,3,3,3-pentafluoropropene
The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc ca...
08/15/2006
7033952Apparatus and method using a remote RF energized plasma for processing semiconductor wafers
Chemical generator and method for generating a chemical species at a point of use such as the chamber of a reactor in which a workpiece such as a semiconductor wafer is to be processed. The species is generated by creating free radicals, and combining the free radic...
04/25/2006
7030283Process for producing 1,1-difluorovinyl cycloaliphatic compounds
This invention relates to a process for the preparation of 1,1-difluoroolefins, e.g., difluorovinyl cycloaliphatic compounds such as difluorovinylcyclohexane and derivatives by the dehydrofluorination of a trifluoromethyl-substituted cycloaliphatic compound and the ...
04/18/2006
6963016Process for the synthesis of highly active modified carbon supported palladium catalyst
The present invention relates to a process for the synthesis of highly active modified carbon supported palladium catalyst by simultaneously impregnating activated carbon with a palladium precursor and an aluminium precursor. The carbon supported palladium catalyst ...
11/08/2005
6689923Perfluoroolefin-hydrocarbon hybrid compound, method of producing the same and method of producing perfluoroalkyl radical
The present invention provides a perfluoroolefin-hydrocarbon hybrid compound represented by the following general formula (1): [(CF3)2 CX][(CF3)2 CY]C.dbd.C(CF3)Z (1) wherein X, Y and Z may be the same or dif...
02/10/2004
6683226Process for the production of hexafluoropropylene from CClF2CClFCF3 and azeotropes of CClF2CClFCF3 with HF
A process for the manufacture of CF3 CF.dbd.CF2 is disclosed. The process involves contacting 2,3-dichloro-1,1,1,2,3,3-hexafluoropropane with at least 0.1 mole of hydrogen in a reaction vessel of titanium, nickel or iron or their all...
01/27/2004
6380446Process for dehydrohalogenation of halogenated compounds
Halogenated compounds are dehydrohalogenated in a multi-stage bubble reactor wherein agitation of the reactor contents is provided by in situ generation and vaporization of reaction product having a boiling point lower than that of the reactants....
04/30/2002
6297205Monohydric alcohol-free transparent moisturizing bar soap
A monohydric alcohol-free, transparent, moisturizing bar soap having a high humectant solvent content. The formulation includes: (i) from about 38% to about 96% of one or more humectant solvents and (ii) from about 3% to about 20% of insoluble and/or solu...
10/02/2001
6166156Method for making photocurable halofluorinated acrylates
Halofluorinated alkylene monomers are made by a method comprising the steps of: (a) subjecting a first polymer which is the reaction product of a fluorinated vinyl monomer and a vinyl comonomer to dehydrohalogenation to form a second polymer; (b) treating...
12/26/2000
6031141Fluoroolefin manufacturing process
This invention provides a process for the manufacture of a fluoroolefin of the formula (R1)2 C.dbd.C(R1)2 wherein each R1 is independently selected from the group consisting of --H, --F, --CF3, ...
02/29/2000
5763703Manufacturing method for hexafluorocylobutene and hexafluorocyclobutane
Manufacturing method for hexafluorocyclobutene in which 1,2-dichlorohexafluorocyclobutane is dechlorinated using hydrogen in the presence of a metal oxide and/or silicon oxide catalyst. Manufacturing method for (Z)-1,2,3,3,4,4-hexafluorocyclobutane which ...
06/09/1998
5728903Method for producing flourine-containing silicone compound
A method for producing a fluorine-containing silicone compound, which comprises subjecting a compound of the following formula (I) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation to obtain a fluor...
03/17/1998
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