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Class 568/741 - Preparing from peroxide or preparing by oxidation


Subclass of Class 568 - Organic compounds -- part of the class 532-570 series
Definition: Processes which include preparing the compound from a peroxide
No. of patents: 80
Last issue date: 12/01/2009


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NumberTitleIssue Date
7626060Process for the preparation of phenolic compounds, for separating phenol from cleavage product mixtures, and an apparatus
To improve energy efficiency of prior art processes while preserving the standards of quality and total yield of desired end products, a process for the preparation of phenolic compounds is proposed. The process of the invention comprises working-up of the cleavage ...
12/01/2009
6900358Process for catalytic hydroxylation of benzene
A process for hydroxylating benzene under catalytic distillation conditions to produce hydroxylated products such as phenol is provided. The process provides for direct hydroxylation of liquid phase benzene with an oxidant and a zeolite catalyst under conditions eff...
05/31/2005
6576798Method and system for purifying cumene hydroperoxide cleavage products
A system for purifying a cumene hydroperoxide cleavage product mixture comprises a cumene hydroperoxide cleavage product mixture feed containing impurities in fluid communication with an aqueous alkaline solution feed; the cumene hydroperoxide cleavage pr...
06/10/2003
6573408System and method for purifying cumene hydroperoxide cleavage products
A system for purifying a cumene hydroperoxide cleavage product mixture comprises a cumene hydroperoxide cleavage product mixture feed containing impurities in fluid communication with an aqueous alkaline solution feed; the cumene hydroperoxide cleavage pr...
06/03/2003
6482989Method for oxidizing alkanes and cycloalkanes with aldehydes in the presence of copper-based catalysts and nitrogen-containing compounds
A method for oxidizing an alkane, comprising the step of oxidizing said alkane with oxygen in the presence of an aldehyde, a copper-based catalyst and a nitrogen-containing compound. This method may be used to convert alkanes to corresponding alcohols and...
11/19/2002
6479711Process for producing aromatic hydroxy compound
A process for producing an aromatic hydroxy compound having hydroxyl group at the para-position with respect to a hydroxy or an alkoxy substituent group present in the aromatic ring at a high yield and at a high selectivity, using a novel and useful hydro...
11/12/2002
6441252Apparatus for producing phenol using reactive distillation
An apparatus for producing phenol and acetone from cumene hydroperoxide comprises a reactive distillation column comprising at its upper portion a distillation column and at its lower portion a catalyst bed....
08/27/2002
6441251Production of phenol
A process for producing phenol and acetone from cumene hydroperoxide is described in which the cumene hydroperoxide is contacted with a solid-acid catalyst comprising an inorganic, porous, crystalline material, designated as M41S, exhibiting, after calcin...
08/27/2002
6410804Production of phenol using reactive distillation
A process for producing phenol and acetone from cumene hydroperoxide comprises: i) introducing a cumene hydroperoxide feed into a reactive distillation column comprising at its upper portion a distillation column and at its lower portion a catalyst bed, a...
06/25/2002
6365762Method for catalytic and selective oxidation of aromatic compounds
The invention relates to the use of compounds of the formula R1a Reb Oc.L.sub.d (I), in which ##STR1## and the total of a, b and c is such as to comply with the pentavalency or heptavalency of rhenium, with the prov...
04/02/2002
6350921Process for the production of a dihydroxybenzene and dicarbinol from diisopropylbenzene
Improved methods for the simultaneous production of dihydroxybenzene and dicarbinol from diisopropylbenzene are provided. These methods provide for continuous and simultaneous production of diisopropylbenzene dihydroperoxide (DHP) and diisopropylbenzene h...
02/26/2002
6297406Production of phenol
A process for producing phenol and acetone from cumene hydroperoxide is described in which the cumene hydroperoxide is contacted with a solid-acid catalyst comprising a mixed oxide of cerium and a Group IVB metal....
10/02/2001
6169215Production of phenol
A process for producing phenol and acetone from cumene hydroperoxide is described in which the cumene hydroperoxide is contacted with a solid-acid catalyst produced by calcining a source of a Group IVB metal oxide with a source of an oxyanion of a Group V...
01/02/2001
6169216Production of phenol
A process for producing phenol and acetone from cumene hydroperoxide is described in which the cumene hydroperoxide is contacted with a solid-acid catalyst comprising a sulfated transition metal oxide, preferably sulfated zirconia....
01/02/2001
6107527Process for the production of hydroxy-aromatic substances
The process for the production of hydroxy aromatic substances by means of catalytic oxidation of isoalkyl aromatic substance with oxygen, and decomposition of the hydroperoxide thus formed, is based on the concept that isoalkylaromatic substances are emul...
08/22/2000
5962752Leached alumina vanadyl catalysts for hydroxylation of aromatics using molecular oxygen as the terminal oxidant without coreductant
A process is disclosed for the catalytic hydroxylation of aromatic hydrocarbons which comprises contacting aromatic feedstock with oxidant comprising molecular oxygen, under suitable reaction conditions, in the presence of a catalyst comprising vanadyl (V...
10/05/1999
5932773Process for the preparation of ଱ and ଲ napthol by hydroxylation of naphthalene using organotransition metal complex
This invention relates to a process for the hydroxylation of napthalene to .varies. and ଲ naphthols which comprises reacting napthalene with hydrogen peroxide in the presence of a solid catalyst containing an organotransition metal complex wherein s...
08/03/1999
5811599Process for the selective oxidation of hydrocarbons and their derivatives
A process for the oxidation of hydrocarbons and their derivatives having the general formula RX, wherein R is from n-alkyl, iso-alkyl, benzyl, cyclohexyl, mono, di or tricyclic aryl, or alkenic groups and X is selected from H, OH or Cl to compounds having...
09/22/1998
5670465Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom
p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enoli...
09/23/1997
5510543Removal and neutralization of acid catalyst from products of cumene hydroperoxide cleavage
The present invention is an improved method for the recovery of phenol from a cleavage mass resulting from the sulfuric acid cleavage of cumene hydroperoxide comprising neutralizing the cleavage mass, forming an aqueous phase and an organic phase, separat...
04/23/1996
5504260Catalytic oxidation
Organic compounds are selectively oxidized by means of a particularly advantageous process, using elemental oxygen and a catalyst containing palladium and copper and carrying out the process in the presence of carbon monoxide....
04/02/1996
5475157Process for producing aromatic hydroxylic compound
There is disclosed a process for producing an aromatic hydroxylic compound by acid decomposition of a hydroperoxide having the general formula (I) ##STR1## wherein Ar represents an aromatic hydrocarbon group having a valence of n; and n represents an...
12/12/1995
5430200Process for producing phenol from cumene
The present invention provides in a particular embodiment an improvement in the process for producing phenol by the acid-catalyzed cleavage of cumene hydroperoxide (CHP). The reactant stream fed to the cleavage reactor also includes the contaminant by-pro...
07/04/1995
5426244Method for preparing dihydric phenols
Phenols are reacted with a hydrogen peroxide in the presence of a crystalline titanosilicate catalyst and a cyclic ether, such as dioxane, as a solvent. The method provides especially high para-selectivity compared with conventional methods, and, at the s...
06/20/1995
5414155Preparation of o-dihydroxylated aromatic compounds via oxidation of o-fuchsones
o-Dihydroxylated aromatic compounds, for example pyrocatechol, are selectively prepared by reacting an o-fuchsone with an oxidizing agent, for example hydrogen peroxide, optionally in the presence of a catalytically effective amount of an acid catalyst....
05/09/1995
5414154Phenol with low levels of methylbenzofuran
A process for the reduction of methylbenzofuran (MBF) impurities in phenol obtained from the decomposition product of cumene hydroperoxide requires treating the phenol to reduce the level of acetol, contacting the phenol containing a low level of acetol w...
05/09/1995
5387724Selective hydroxylation of phenol or phenolic ethers
Phenols, and related aromatic compounds, phenolic ethers, can be hydroxylated selectively using hydrogen peroxide in the presence of an amorphous or microcrystalline zirconium phosphate catalyst in a solvent containing an aliphatic carboxylic acid. The pr...
02/07/1995
5371305Process for producing phenol from cumene
The present invention provides in a particular embodiment an improvement in the process for producing phenol by the acid-catalyzed cleavage of cumene hydroperoxide (CHP). The reactant stream fed to the cleavage reactor also includes the contaminant by-pro...
12/06/1994
5364983Process for the preparation of aromatic polyhydroxy compounds
The present invention relates to a process for the preparation of aromatic polyhydroxy compounds, by reacting an aromatic hydroxyaldehyde with hydrogen peroxide, with or without the addition of a base, in the presence of a nitrile R--CN, in which R is an ...
11/15/1994
5364982Catalytic hydroxylation of phenol
Hydroxylation of phenol is prone to the production of tarry by-products. Selective hydroxylation of phenol can be obtained by reacting a limited amount of hydrogen peroxide with phenol in solution in a compatible organic solvent and in the presence of a c...
11/15/1994
5331103Process for monohydroxylation of phenolic compounds
The present invention relates to a process for monohydroxylation of phenolic compounds which allows an increase in the amount of para isomer. The invention relates to a process for monohydroxylation of a phenolic compound having a hydrogen atom in the para pos...
07/19/1994
52929594,4-dinitroadamantange-2,6-dione
4,4-Dinitroadamantane-2,6-dione,6, and a method of making the same....
03/08/1994
5276216Process for oxidizing aromatic and aliphatic compounds
Process for oxidizing aromatic and aliphatic compounds, by using, in aqueous solution, an enzymatic system constituted by hydrogen, peroxide as the oxidizer compound, peroxidase and activated oxygen, or an enzyme which releases activated oxygen from H
01/04/1994
5233097Oxidation of aromatics to hydroxyaromatics using aluminosilicates containing framework titanium
Certain crystalline titanoaluminosilicate molecular sieve compositions having titanium, aluminum, and silicon present as framework tetrahedral oxide units are particularly effective in hydroxylating the aromatic nucleus of aromatic compounds using hydroge...
08/03/1993
5160497Phenol production process
Phenol production process wherein: 1) benzene is reacted with propene and isopropylic alcohol by contacting a catalyst based on a dealuminized Y zeolite with a SiO2 /Al2 O3 molar ratio ranging from 8 to 70, then the obtained pr...
11/03/1992
5110995Preparation of phenol or phenol derivatives
The invention relates to a process for the production of phenol or phenol derivatives by oxidation of the aromatic nucleus of benzene or benzene derivatives with nitrous oxide over a zeolite catalyst....
05/05/1992
5097078Catalytic hydroxylation of phenols/phenol ethers
The phenols and phenol ethers are hydroxylated by reacting such phenols/phenol ethers with hydrogen peroxide, in the presence of (a) a catalytically effective amount of an alkali metal or alkaline earth metal salt of at least one protonic acid having a pK...
03/17/1992
5017729Phenol preparation process and propylene recovery therefrom
Phenol is produced in a recycle manner by (a) reacting benzene with propylene to synthesize cumene, (b) oxidizing the cumene of step (a) into cumene hydroperoxide, (c) acid cleaving cumene hydroperoxide into phenol and acetone, (d) hydrogenating the aceto...
05/21/1991
5003114Hydroxylation of phenols/phenol ethers
Phenols/phenol ethers are hydroxylated by reaction with hydrogen peroxide in the presence of a catalytically effective amount of a calcined germanozeosilite MFI zeolite....
03/26/1991
4992600Process for the oxidation of benzene to phenol
The instant invention relates to a process for the oxidation of benzene to phenol which comprises contacting benzene and molecular oxygen with a dihydrodihydroxyanthracene-sulfonate salt dissolved in water, optionally in the presence of an oxidation catal...
02/12/1991
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