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Class 568/656 - Halogen bonded directly to the benzene ring


Subclass of Class 568 - Organic compounds -- part of the class 532-570 series
Definition: Compounds wherein the halogen is bonded directly to the
No. of patents: 143
Last issue date: 08/14/2007


1        
NumberTitleIssue Date
7256316Fluorine-containing vinyl ethers, their polymers, and resist compositions using such polymers
A fluorine-containing vinyl ether represented by formula 1, wherein R represents an organic group containing at least one fluorine atom and a cyclic structure is provided. A fluorine-containing copolymer containi...
08/14/2007
7220870Hydrolytic kinetic resolution of cyclic substrates
The present invention relates to a process for stereoselective or regioselective chemical synthesis which generally comprises reacting a nucleophile and a chiral or prochiral cyclic substrate in the presence of a non-racemic, chiral catalyst to produce a stereoisome...
05/22/2007
7131546Product display support systems and methods
A support system for supporting a product for retail display comprises an accessory, a rear portion, a front portion, and a magnetic portion. The accessory is adapted to support the product for retail display. The front portion supports the accessory and is rigidly ...
11/07/2006
7115784Copper-catalyzed formation of carbon-heteroatom and carbon-carbon bonds
The present invention relates to copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of an amide or a...
10/03/2006
7091270Pentabromobenzyl alkyl ethers and their use as fire retardants
The present invention provides novel pentabromobenzyl alkyl ethers serving as highly effective flame retardants in polymers. The invention further provides a fire retarded polymer composition comprising said pentabromobenzyl alkyl ethers. ...
08/15/2006
6881868Process for the preparation of (R)-2-alkyl-3-phenyl-1-propanols
Compounds of formula (I), wherein R1 and R2 are, independently of one another, H,C1-C6alkyl, C1-C6halogenalkyl, C1-C6alkoxyl, C1-C6alkoxy-C1-C
04/19/2005
6770788Process and intermediate compounds for preparation of pesticidal fluoroolefin compounds
A two-step process for the preparation of fluoroolefin compounds of formula I wherein R is hydrogen or alkyl, and R1 is alkyl or cyclopropyl, or R and R1 are taken together with the carbon at...
08/03/2004
6706929Accelerated process for preparing O-methyl phenols, N-methyl heteroaromatic compounds, and methylated aminophenols
An accelerated process for preparing an O-methyl phenol comprising reacting a phenol with dimethyl carbonate in the presence of a catalyst selected from 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-diazabicyclo[2.2.2]octane; and dimethylaminopyridine. According to anothe...
03/16/2004
6677002Phenylcyclohexanes and a liquid-crystalline medium
Novel phenylcyclohexanes of the formula I: ##STR1## in which n is 0 to 7, Q1 and Q2 are H, or one of these radicals is alternatively CH3, r is 0, 1, 2, 3, 4 or 5, A is trans-1,4-cyclohexylene, 1,4-phenylene, 3-fluoro-1,4-p...
01/13/2004
6399837Electron donors
A method of polymerizing at least one olefin comprising contacting the olefin with a catalyst composition comprising: 1) a procatalyst composition comprising a magnesium and titanium-containing component and an electron donor compound of the structure: ##...
06/04/2002
6399835Process for electrophilic aromatic substitution
Processes for the electrophilic substitution of aromatic compounds, such as alkylation, with a desired substituent are disclosed. The processes include contacting the aromatic compound, a precursor of the desired substituent and an aqueous reagent contain...
06/04/2002
6380440Processes for the preparation of 3-bromoanisole and 3-bromonitrobenzene
Process for the preparation of 3-bromoanisole comprising methoxydenitrating 3-bromonitrobenzene in the presence of a phase-transfer catalyst (PTC), and the preparation of 3-bromonirtobenzene by the bromination of nitrobenzene with bromine in oleum. The me...
04/30/2002
6369279Styrene derivatives
Styrene derivatives of formula (1) are novel wherein R1 is hydrogen, C1-20 alkyl, fluoro-substituted C1-20 alkyl, chloro, or trichloromethyl, R2 is a phenol protecting group, p, q and r are integers in the range...
04/09/2002
6355813process of making 3-phenyl-1-methylenedioxyphenyl-indane-2-carboxylic acid derivatives
Invented is an improved process for preparing aromatic ring-fused cyclopentane derivatives. Preferred compounds prepared by this invention are indane carboxylates and cyclopentanopyridine derivatives. The most preferred compounds prepared by this inventio...
03/12/2002
6333436Styrene derivatives
Styrene derivatives of formula (1) are novel wherein R1 is H, F, C1-20 alkyl or fluorinated C1-20 alkyl, R2 in cis or trans conformation is F, C1-20 alkyl or fluorinated C1-20 alkyl, R...
12/25/2001
6288242Processes and intermediates for preparing substituted chromanol derivatives
The invention relates to processes for preparing a compound of the formula ##STR1## and the enantiomer of said compound, wherein the benzoic acid moiety is attached at position 6 or 7 of the chroman ring, and R1, R2, and R3
09/11/2001
6239317Process for the production of halogeno-o-hydroxydiphenyl compounds
There is described a four step process for the production of halogeno-o-hydroxydiphenyl compounds having the formula ##STR1## in which X is --O--or --CH2 --; m is 1 to 3; and n is 1 or 2; wherein in the first step, a diphenyl compound is chlorinated...
05/29/2001
6235949Process for the preparation of halogenated derivatives and Lewis acid base catalysts thereof
A process for the preparation of halide compounds, preferably aryl halides, by contacting a gaseous mixture of hydrohalic acid and a compound selected from an aryl halogen formate, an aryl carbonate and equivalents thereof with a Lewis acid catalyst....
05/22/2001
6211399Pressurized chlorination and bromination of aromatic compounds
Disclosed is a method of adding 1 to 4 chlorine or bromine atoms to an aromatic ring of compound that has at least one electron-withdrawing groups on that ring. The aromatic compound is reacted with a chlorinating agent or a brominating agent in the prese...
04/03/2001
6172268Method for producing an optically active 1-substituted 2-propanol
A method for producing an optically active 1-substituted 2-propanol of the following formula 1, which comprises reacting a hydroxy aromatic compound of the following formula 2 with an optically active propylene oxide in the presence of a catalyst: AOH Fo...
01/09/2001
6166273Processes for fluorinating aromatic ring compounds
A process is provided for increasing the fluorine content of benzene or pyridine rings which are optionally substituted with from 1 to 3 inert substituents. The process involves (a) contacting the ring with a metal fluoride composition comprising cupric f...
12/26/2000
6124507Electron donors
Novel compositions of the structure ##STR1## wherein R1 and R2 are each an alkoxy group which may be the same or different and have from one to ten carbon atoms, and R3 -R6 are each individually, hydrogen, ...
09/26/2000
6118018Chlorination and bromination of aromatic compounds at atmospheric pressure
Disclosed is a method of adding 1 to 4 chlorine or bromine atoms to an aromatic ring of compound that has at least one electron-withdrawing groups on that ring. The aromatic compound is reacted with a chlorinating agent or a brominating agent in the prese...
09/12/2000
5981789Preparation of nuclear chlorinated aromatic compounds
Disclosed is a method of preparing an aromatic compound having the general formula ##STR1## where R is CF3, OCF3, OC2 F5, CN, NCO, or COCl, m is 0, 1, or 2, n is 0, 1, or 2, q is 1 or 2, and q+m+n is an int...
11/09/1999
5907063Aromatic bromination process
Activated aromatic compounds are more economically ring brominated by reacting the compounds with a sulfoxide/HBr brominating agent while removing water from the reaction mixture. The water removal provides high conversions and yields when employing stoic...
05/25/1999
5874656Process for preparing o-alkylfluorobenzenes
o-Alkylfluorobenzenes are advantageously prepared by heating the corresponding chloroformates to from 70° to 200° C. in the liquid phase in the presence of hydrogen fluoride and in the presence of an inert diluent other than a halogenated alkane....
02/23/1999
5849959Derivatives of 2, 3, 6-trifluorophenols and a process for their preparation
The present invention relates to compounds of the formula (1) ##STR1## where R is H, a straight-chain or branched alkyl radical with 1 to 6 carbons, a fluorinated straight-chain or branched alkyl radical with 1 to 6 carbons, a benzyl radical, or a be...
12/15/1998
5817888Bromination process
A bromination process for organic compounds employs stabilized bromine chloride solutions as the brominating agent. Activated aromatic compounds such as anisole can be selectively monobrominated in the para-position in high purity and yield....
10/06/1998
5773668Method of making trichloromethoxybenzene
Disclosed is a method of making trichloromethoxybenzene. A mixture is prepared of anisole and a source of chlorine free radicals, such as chlorine or sulfuryl chloride. The reaction is performed in a solvent, which can be either benzotrifluoride, orthochl...
06/30/1998
5654493Process for preparing 4-bromophenyl alkyl ethers
The present invention relates to a process for preparing 4-bromophenyl alkyl ethers by reacting phenyl alkyl ethers with bromine in a water-miscible solvent in the presence of an oxidizing agent which is able to oxidize hydrogen bromide to bromine....
08/05/1997
5606084Process of fluorinating organic compounds with 1-substituted-4-fluoro-1,4-diazoniabicyclo octane salts
The present invention relates to the preparation and uses of 1-substituted-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts, specifically 1-hydroxyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts as reagents for the introduction of fluorine in organic com...
02/25/1997
5484932Halogenation processes in advantageous solvents, and novel bistrifluoromethyl-polyfluoroalkoxybenzenes
Compounds such as ##STR1## wherein R is F, CF3, CF2 H, CHF CF3 or CF2 CF3, as well as related compounds containing chlorine, are used as solvents in halogenation processes....
01/16/1996
5478964N-fluorosulfonimides and their application as fluorinating agents
The invention describes N-fluorosulfonimides which are useful as fluorinating agents. The N-fluorosulfonimides are stable, easily synthesized, and allow the introduction of fluorine into organic compounds under mild conditions....
12/26/1995
5476646X-ray contrast compositions containing iodophenoxyalkanes and pharmaceutically acceptable clays
Disclosed are x-ray contrast compositions for oral or retrograde examination of the gastrointestinal tract comprising a nonionic x-ray producing agent in combination with a pharmaceutically acceptable clay in a pharmaceutically acceptable carrier; and met...
12/19/1995
5463138Process for preparing difluoromethoxyarenes and difluoromethylthioarenes
Difluoromethoxyarenes and difluoromethylthioarenes of the general formula (I), Ar--Q--CHF2 (I) in which Ar represents optionally substituted aryl, and Q represents oxygen or sulphur, (which can be used as interme...
10/31/1995
5463088Process for preparing perfluoroalkoxy (alkylthio) benzenes
A process for preparing perfluoroalkoxy(alkylthio)benzenes from perfluorochloroalkoxy(alkylthio)-benzenes by reaction with hydrogen fluoride in the gas phase and in the presence of a catalyst....
10/31/1995
5446186Structure and synthesis of nitrophenyl-EGTA, a caged calcium, intermediates thereof and a method of producing a high photochemical yield of liberated calcium
The synthesis and compound of a new caged calcium which is an ortho-nitrophenyl derivative of EGTA and various intermediates. It is synthesized in ten steps and 24% overall yield. The photosensitive chelator, nitrophenyl-EGTA, has a Kd for Ca
08/29/1995
5443814X-ray contrast compositions containing iodophenoxyalkanes and cellulose derivatives
Disclosed are x-ray contrast compositions for oral or retrograde examination of the gastrointestinal tract comprising a nonionic x-ray producing agent in combination with a cellulose derivative in a pharmaceutically acceptable carrier; and methods for the...
08/22/1995
5440051Process for the ଱-chlorination of aryl ethers
Aryl ethers are chlorinated in the ଱-position by a process in which they are metered into a reaction vessel at the same time as chlorine, the reaction being carried out at temperatures in the range from 60° to 150° C....
08/08/1995
5422035Benzene derivatives, and liquid-crystalline medium
A liquid-crystalline medium based on a mixture of polar compounds having positive dielectric anisotropy, comprising one or more compounds of the formula I ##STR1## in which R, A1,. A2, Z1, Z2, m, n, L1...
06/06/1995
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