The ice cream cone was invented at the St. Louis Worlds Fair by Ernest Hamwi in 1904. His waffle booth was next to an ice cream vendor who ran short of dishes. Hamwi rolled a waffle to hold ice cream and the cone was born.
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| Number | Title | Issue Date |
| 7256316 | Fluorine-containing vinyl ethers, their polymers, and resist compositions using such polymers A fluorine-containing vinyl ether represented by formula 1, wherein R represents an organic group containing at least one fluorine atom and a cyclic structure is provided. A fluorine-containing copolymer containi... | 08/14/2007 |
| 7220870 | Hydrolytic kinetic resolution of cyclic substrates The present invention relates to a process for stereoselective or regioselective chemical synthesis which generally comprises reacting a nucleophile and a chiral or prochiral cyclic substrate in the presence of a non-racemic, chiral catalyst to produce a stereoisome... | 05/22/2007 |
| 7131546 | Product display support systems and methods A support system for supporting a product for retail display comprises an accessory, a rear portion, a front portion, and a magnetic portion. The accessory is adapted to support the product for retail display. The front portion supports the accessory and is rigidly ... | 11/07/2006 |
| 7115784 | Copper-catalyzed formation of carbon-heteroatom and carbon-carbon bonds The present invention relates to copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of an amide or a... | 10/03/2006 |
| 7091270 | Pentabromobenzyl alkyl ethers and their use as fire retardants The present invention provides novel pentabromobenzyl alkyl ethers serving as highly effective flame retardants in polymers. The invention further provides a fire retarded polymer composition comprising said pentabromobenzyl alkyl ethers. ... | 08/15/2006 |
| 6881868 | Process for the preparation of (R)-2-alkyl-3-phenyl-1-propanols Compounds of formula (I), wherein R1 and R2 are, independently of one another, H,C1-C6alkyl, C1-C6halogenalkyl, C1-C6alkoxyl, C1-C6alkoxy-C1-C | 04/19/2005 |
| 6770788 | Process and intermediate compounds for preparation of pesticidal fluoroolefin compounds A two-step process for the preparation of fluoroolefin compounds of formula I wherein R is hydrogen or alkyl, and R1 is alkyl or cyclopropyl, or R and R1 are taken together with the carbon at... | 08/03/2004 |
| 6706929 | Accelerated process for preparing O-methyl phenols, N-methyl heteroaromatic compounds, and methylated aminophenols An accelerated process for preparing an O-methyl phenol comprising reacting a phenol with dimethyl carbonate in the presence of a catalyst selected from 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-diazabicyclo[2.2.2]octane; and dimethylaminopyridine. According to anothe... | 03/16/2004 |
| 6677002 | Phenylcyclohexanes and a liquid-crystalline medium Novel phenylcyclohexanes of the formula I: ##STR1## in which n is 0 to 7, Q1 and Q2 are H, or one of these radicals is alternatively CH3, r is 0, 1, 2, 3, 4 or 5, A is trans-1,4-cyclohexylene, 1,4-phenylene, 3-fluoro-1,4-p... | 01/13/2004 |
| 6399837 | Electron donors A method of polymerizing at least one olefin comprising contacting the olefin with a catalyst composition comprising: 1) a procatalyst composition comprising a magnesium and titanium-containing component and an electron donor compound of the structure: ##... | 06/04/2002 |
| 6399835 | Process for electrophilic aromatic substitution Processes for the electrophilic substitution of aromatic compounds, such as alkylation, with a desired substituent are disclosed. The processes include contacting the aromatic compound, a precursor of the desired substituent and an aqueous reagent contain... | 06/04/2002 |
| 6380440 | Processes for the preparation of 3-bromoanisole and 3-bromonitrobenzene Process for the preparation of 3-bromoanisole comprising methoxydenitrating 3-bromonitrobenzene in the presence of a phase-transfer catalyst (PTC), and the preparation of 3-bromonirtobenzene by the bromination of nitrobenzene with bromine in oleum. The me... | 04/30/2002 |
| 6369279 | Styrene derivatives Styrene derivatives of formula (1) are novel wherein R1 is hydrogen, C1-20 alkyl, fluoro-substituted C1-20 alkyl, chloro, or trichloromethyl, R2 is a phenol protecting group, p, q and r are integers in the range... | 04/09/2002 |
| 6355813 | process of making 3-phenyl-1-methylenedioxyphenyl-indane-2-carboxylic acid derivatives Invented is an improved process for preparing aromatic ring-fused cyclopentane derivatives. Preferred compounds prepared by this invention are indane carboxylates and cyclopentanopyridine derivatives. The most preferred compounds prepared by this inventio... | 03/12/2002 |
| 6333436 | Styrene derivatives Styrene derivatives of formula (1) are novel wherein R1 is H, F, C1-20 alkyl or fluorinated C1-20 alkyl, R2 in cis or trans conformation is F, C1-20 alkyl or fluorinated C1-20 alkyl, R... | 12/25/2001 |
| 6288242 | Processes and intermediates for preparing substituted chromanol derivatives The invention relates to processes for preparing a compound of the formula ##STR1## and the enantiomer of said compound, wherein the benzoic acid moiety is attached at position 6 or 7 of the chroman ring, and R1, R2, and R3 | 09/11/2001 |
| 6239317 | Process for the production of halogeno-o-hydroxydiphenyl compounds There is described a four step process for the production of halogeno-o-hydroxydiphenyl compounds having the formula ##STR1## in which X is --O--or --CH2 --; m is 1 to 3; and n is 1 or 2; wherein in the first step, a diphenyl compound is chlorinated... | 05/29/2001 |
| 6235949 | Process for the preparation of halogenated derivatives and Lewis acid base catalysts thereof A process for the preparation of halide compounds, preferably aryl halides, by contacting a gaseous mixture of hydrohalic acid and a compound selected from an aryl halogen formate, an aryl carbonate and equivalents thereof with a Lewis acid catalyst.... | 05/22/2001 |
| 6211399 | Pressurized chlorination and bromination of aromatic compounds Disclosed is a method of adding 1 to 4 chlorine or bromine atoms to an aromatic ring of compound that has at least one electron-withdrawing groups on that ring. The aromatic compound is reacted with a chlorinating agent or a brominating agent in the prese... | 04/03/2001 |
| 6172268 | Method for producing an optically active 1-substituted 2-propanol A method for producing an optically active 1-substituted 2-propanol of the following formula 1, which comprises reacting a hydroxy aromatic compound of the following formula 2 with an optically active propylene oxide in the presence of a catalyst: AOH Fo... | 01/09/2001 |
| 6166273 | Processes for fluorinating aromatic ring compounds A process is provided for increasing the fluorine content of benzene or pyridine rings which are optionally substituted with from 1 to 3 inert substituents. The process involves (a) contacting the ring with a metal fluoride composition comprising cupric f... | 12/26/2000 |
| 6124507 | Electron donors Novel compositions of the structure ##STR1## wherein R1 and R2 are each an alkoxy group which may be the same or different and have from one to ten carbon atoms, and R3 -R6 are each individually, hydrogen, ... | 09/26/2000 |
| 6118018 | Chlorination and bromination of aromatic compounds at atmospheric pressure Disclosed is a method of adding 1 to 4 chlorine or bromine atoms to an aromatic ring of compound that has at least one electron-withdrawing groups on that ring. The aromatic compound is reacted with a chlorinating agent or a brominating agent in the prese... | 09/12/2000 |
| 5981789 | Preparation of nuclear chlorinated aromatic compounds Disclosed is a method of preparing an aromatic compound having the general formula ##STR1## where R is CF3, OCF3, OC2 F5, CN, NCO, or COCl, m is 0, 1, or 2, n is 0, 1, or 2, q is 1 or 2, and q+m+n is an int... | 11/09/1999 |
| 5907063 | Aromatic bromination process Activated aromatic compounds are more economically ring brominated by reacting the compounds with a sulfoxide/HBr brominating agent while removing water from the reaction mixture. The water removal provides high conversions and yields when employing stoic... | 05/25/1999 |
| 5874656 | Process for preparing o-alkylfluorobenzenes o-Alkylfluorobenzenes are advantageously prepared by heating the corresponding chloroformates to from 70° to 200° C. in the liquid phase in the presence of hydrogen fluoride and in the presence of an inert diluent other than a halogenated alkane.... | 02/23/1999 |
| 5849959 | Derivatives of 2, 3, 6-trifluorophenols and a process for their preparation The present invention relates to compounds of the formula (1) ##STR1## where R is H, a straight-chain or branched alkyl radical with 1 to 6 carbons, a fluorinated straight-chain or branched alkyl radical with 1 to 6 carbons, a benzyl radical, or a be... | 12/15/1998 |
| 5817888 | Bromination process A bromination process for organic compounds employs stabilized bromine chloride solutions as the brominating agent. Activated aromatic compounds such as anisole can be selectively monobrominated in the para-position in high purity and yield.... | 10/06/1998 |
| 5773668 | Method of making trichloromethoxybenzene Disclosed is a method of making trichloromethoxybenzene. A mixture is prepared of anisole and a source of chlorine free radicals, such as chlorine or sulfuryl chloride. The reaction is performed in a solvent, which can be either benzotrifluoride, orthochl... | 06/30/1998 |
| 5654493 | Process for preparing 4-bromophenyl alkyl ethers The present invention relates to a process for preparing 4-bromophenyl alkyl ethers by reacting phenyl alkyl ethers with bromine in a water-miscible solvent in the presence of an oxidizing agent which is able to oxidize hydrogen bromide to bromine.... | 08/05/1997 |
| 5606084 | Process of fluorinating organic compounds with 1-substituted-4-fluoro-1,4-diazoniabicyclo octane salts The present invention relates to the preparation and uses of 1-substituted-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts, specifically 1-hydroxyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts as reagents for the introduction of fluorine in organic com... | 02/25/1997 |
| 5484932 | Halogenation processes in advantageous solvents, and novel bistrifluoromethyl-polyfluoroalkoxybenzenes Compounds such as ##STR1## wherein R is F, CF3, CF2 H, CHF CF3 or CF2 CF3, as well as related compounds containing chlorine, are used as solvents in halogenation processes.... | 01/16/1996 |
| 5478964 | N-fluorosulfonimides and their application as fluorinating agents The invention describes N-fluorosulfonimides which are useful as fluorinating agents. The N-fluorosulfonimides are stable, easily synthesized, and allow the introduction of fluorine into organic compounds under mild conditions.... | 12/26/1995 |
| 5476646 | X-ray contrast compositions containing iodophenoxyalkanes and pharmaceutically acceptable clays Disclosed are x-ray contrast compositions for oral or retrograde examination of the gastrointestinal tract comprising a nonionic x-ray producing agent in combination with a pharmaceutically acceptable clay in a pharmaceutically acceptable carrier; and met... | 12/19/1995 |
| 5463138 | Process for preparing difluoromethoxyarenes and difluoromethylthioarenes Difluoromethoxyarenes and difluoromethylthioarenes of the general formula (I), Ar--Q--CHF2 (I) in which Ar represents optionally substituted aryl, and Q represents oxygen or sulphur, (which can be used as interme... | 10/31/1995 |
| 5463088 | Process for preparing perfluoroalkoxy (alkylthio) benzenes A process for preparing perfluoroalkoxy(alkylthio)benzenes from perfluorochloroalkoxy(alkylthio)-benzenes by reaction with hydrogen fluoride in the gas phase and in the presence of a catalyst.... | 10/31/1995 |
| 5446186 | Structure and synthesis of nitrophenyl-EGTA, a caged calcium, intermediates thereof and a method of producing a high photochemical yield of liberated calcium The synthesis and compound of a new caged calcium which is an ortho-nitrophenyl derivative of EGTA and various intermediates. It is synthesized in ten steps and 24% overall yield. The photosensitive chelator, nitrophenyl-EGTA, has a Kd for Ca | 08/29/1995 |
| 5443814 | X-ray contrast compositions containing iodophenoxyalkanes and cellulose derivatives Disclosed are x-ray contrast compositions for oral or retrograde examination of the gastrointestinal tract comprising a nonionic x-ray producing agent in combination with a cellulose derivative in a pharmaceutically acceptable carrier; and methods for the... | 08/22/1995 |
| 5440051 | Process for the -chlorination of aryl ethers Aryl ethers are chlorinated in the -position by a process in which they are metered into a reaction vessel at the same time as chlorine, the reaction being carried out at temperatures in the range from 60° to 150° C.... | 08/08/1995 |
| 5422035 | Benzene derivatives, and liquid-crystalline medium A liquid-crystalline medium based on a mixture of polar compounds having positive dielectric anisotropy, comprising one or more compounds of the formula I ##STR1## in which R, A1,. A2, Z1, Z2, m, n, L1... | 06/06/1995 |